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Structure of Two New Compounds of Copper(I) Iodide with N-Donor and P-Donor Ligands

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Abstract

The copper(I) halides complexes present a large structural variety and have numerous technological applications. In this work we have prepared two new copper(I) complexes with N-donor and P-donor ligands [CuI(2-(diphenylphosphino)benzaldehyde)2] (1), [CuI(2-(diphenylphosphino)benzaldehyde) (acetonitrile)]2 (2) from CuI as starting material. The complexes were characterized by elemental analysis, IR spectroscopy and crystallographic studies. Compound 1 crystallizes in a monoclinic C2/c space group. It is a monomer with a P-donor ligand bound with copper(I) in a distorted triangular planar geometry. Compound 2 crystallizes in monoclinic P21/c space group. It has two molecules of the P-donor ligand and two molecules of the N-donor ligand in trans configuration, forming a dimer with two bridging iodides. The Cu(I) atom is four coordinated in trigonal pyramidal geometry with τ4 value of 0.85. The bond distances are 2.5050(6)-2.7090(6) Å for Cu–I, 2.044(4) Å for Cu–N and 2.2489(8)-2.2528(8) Å for Cu–P.

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Authors and Affiliations

  1. Departamento de Física, Universidad de La Laguna, Avd. Astrofísico Fco Sánchez s/n, La Laguna, Tenerife, E-38204, Spain

    A. Aguirrechu-Comerón & J. González-Platas

  2. Departamento de Química (Unidad Departamental de Química Inorgánica), Facultad de Química, Universidad de La Laguna, Tenerife, E-38280, Spain

    R. Hernández-Molina

  3. Instituto de Química Biorgánica Antonio González, Avda. Astrofísico Fco. Sánchez s/n, La Laguna, Tenerife, E-38280, Spain

    R. Hernández-Molina

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  1. A. Aguirrechu-Comerón
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  2. R. Hernández-Molina
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Correspondence to A. Aguirrechu-Comerón.

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Original Russian Text © 2018 A. Aguirrechu-Comerón, R. Hernández-Molina, J. González-Platas.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 59, No. 4, pp. 981–986, May-June, 2018.

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Aguirrechu-Comerón, A., Hernández-Molina, R. & González-Platas, J. Structure of Two New Compounds of Copper(I) Iodide with N-Donor and P-Donor Ligands. J Struct Chem 59, 943–948 (2018). https://doi.org/10.1134/S0022476618040285

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