Skip to main content
SpringerLink
Log in

Crystal Structure of the Azido-Bridged Copper(II) Complex [Cu2L2(μ1,1-N3)2] Based on the 2-[(3-Amino-2,2-Dimethylpropylimino)-Methyl]-4-Bromophenol Schiff Base Ligand

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

New end-on azido-bridged dinuclear copper(II) complex [Cu2L2(μ1,1-N3)2] (I) (HL = 2-[(3-amino-2,2-dimethylpropylimino)-methyl]-4-bromophenol) is synthesized and characterized by the elemental analysis and FT-IR spectroscopy. The crystal structure of I is determined by X-ray diffraction. The crystal of I is monoclinic, space group P21/c, a = 10.7926(4) Å, b = 12.4222(4) Å, c = 11.0894(4) Å, β = 100.085(2)°, V = 1463.76(9) Å3, Z = 2. The crystal structure shows that the structure contains [Cu2L2(μ1,1-N3)2] units joined together by intermolecular H-bonding interactions to form a 2D rectangular grid.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. Escuer, J. Esteban, S. P. Perlepes, and T. C. Stamatatos. Coord. Chem. Rev., 2014, 275, 87–129.

    Article  CAS  Google Scholar 

  2. C. Adhikary and S. Koner. Coord. Chem. Rev., 2010, 254, 2933–2958.

    Article  CAS  Google Scholar 

  3. J. Ribas, A. Escuer, M. Monfort, R. Vicente, R. Cortés, L. Lezama, and T. Rojo. Coord. Chem. Rev., 1999, 193, 1027–1068.

    Article  Google Scholar 

  4. S. Naiya, C. Biswas, M. G. B. Drew, C. J. Gómez–García, J. M. Clemente–Juan, and A. Ghosh. Inorg. Chem., 2010, 49, 6616–6627.

    Article  CAS  PubMed  Google Scholar 

  5. P. Bhowmik, L. KantDas, S. Chattopadhyay, and A. Ghosh. Inorg. Chim. Acta, 2015, 430, 24–29.

    Article  CAS  Google Scholar 

  6. Karahan, S. Karabulut, H. Dal, R. Kurtaran, and J. Leszczynski. J. Mol. Struct., 2015, 1093, 1–7.

    Article  CAS  Google Scholar 

  7. F. Niu, K.–X. Yan, L. Pang, D. Qu, X. Zhao, and Z. You. Inorg. Chim. Acta, 2015, 435, 299–304.

    Article  CAS  Google Scholar 

  8. M. Nandy, S. Shit, E. Garribba, C. J. Gómez–García, and S. Mitra. Polyhedron, 2015, 102, 137–146.

    Article  CAS  Google Scholar 

  9. F. Z. Chibou. Fellah, J.–P. Costes, C. Duhayon, and L. Vendier. Polyhedron, 2016, 111, 101–108.

    Article  CAS  Google Scholar 

  10. P. Adak, C. Das, B. Ghosh, S. Mondal, B. Pakhira, E. Sinn, A. J. Blake, A. E. O′Connor, and S. K. Chattopadhyay. Polyhedron, 2016, 119, 39–48.

    Article  CAS  Google Scholar 

  11. W.–B. Shi, A.–L. Cui, and H.–Z. Kou. Cryst. Growth Des., 2012, 12, 3436–3443.

    Article  CAS  Google Scholar 

  12. N. Aiswarya, M. Sithambaresan, S. S. Sreejith, S. W. Ng, and M. R. Prathapachandr. Kurup. Inorg. Chim. Acta, 2016, 443, 251–266.

    Article  CAS  Google Scholar 

  13. S. Koner, S. Saha, T. Mallah, and K.–I. Okamoto. Inorg. Chem., 2004, 43, 840–842.

    Article  CAS  PubMed  Google Scholar 

  14. S. Koner, S. Saha, K.–I. Okamoto, and J.–P. Tuchagues. Inorg. Chem., 2003, 42, 4668–4672.

    Article  CAS  PubMed  Google Scholar 

  15. S. Sen, S. Mitra, D. L. Hughes, G. Rosair, and C. Desplanches. Polyhedron, 2007, 26, 1740–1744.

    Article  CAS  Google Scholar 

  16. M. Zbiri, S. Saha, C. Adhikary, S. Chaudhuri, C. Dauland, and S. Koner. Inorg. Chim. Acta, 2006, 359, 1193–1199.

    Article  CAS  Google Scholar 

  17. C. Adhikary, D. Mal, R. Sen, A. Bhattacharjee, P. Gütlich, S. Chaudhuri, and S. Koner. Polyhedron, 2007, 26, 1658–1662.

    Article  CAS  Google Scholar 

  18. M. S. Ray, A. Ghosh, R. Bhattacharya, G. Mukhopadhyay, M. G. B. Drew, and J. Ribas Dalton Trans., 252–259 2004,.

    Google Scholar 

  19. L. H. Wang. Russ. J. Coord. Chem., 2011, 37, 40–44.

    Article  CAS  Google Scholar 

  20. (a) COSMO, version 1.60. Bruker AXS Inc.: Madison, Wisconsin, 2005.

    Google Scholar 

  21. SAINT, version 7.06A. Bruker AXS Inc.: Madison, Wisconsin, 2005.

  22. SADABS, version 2.10. Bruker AXS Inc.: Madison, Wisconsin, 2005.

  23. M. C. Burla R. Caliandro, M. Camalli, B. Carrozzini, G. L. Cascarano, L. DCaro, C. Giacovazzo, G. Polidori, and R. Spagna. SIR2004, J. Appl. Crystallogr., 2005, 38, 381–388.

    Article  CAS  Google Scholar 

  24. G. M. Sheldrick. SHELXL97. University of Göttingen, Göttingen, Germany, 1997.

    Google Scholar 

  25. A. W. Addison, T. N. Rao, J. Reedijk, J. Van Rijn, and G. C. Verschoor. J. Chem. Soc. Dalton Trans., 1984, 1349–1356.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Saveh Branch, Islamic Azad University, Saveh, Iran

    A. Ghaemi, B. Keyvani & K. Fayyazi

  2. Department of Chemistry, University of Isfahan, Isfahan, Iran

    H. A. Rudbari

Authors
  1. A. Ghaemi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. Keyvani
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. K. Fayyazi
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. H. A. Rudbari
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. Ghaemi.

Additional information

Original Russian Text © 2018 A. Ghaemi, B. Keyvani, K. Fayyazi, H. A. Rudbari.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 59, No. 5, pp. 1216–1220, June-July, 2018.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ghaemi, A., Keyvani, B., Fayyazi, K. et al. Crystal Structure of the Azido-Bridged Copper(II) Complex [Cu2L2(μ1,1-N3)2] Based on the 2-[(3-Amino-2,2-Dimethylpropylimino)-Methyl]-4-Bromophenol Schiff Base Ligand. J Struct Chem 59, 1176–1180 (2018). https://doi.org/10.1134/S0022476618050219

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476618050219

Keywords

Search

Navigation