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Copper(I) Chloride π-Complexes with 2,5-Bis(Allylthio)-1,3,4-Thiadiazole: Synthesis and Structural Features

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Abstract

Three new Cu(I) π-complexes with 2,5-bis(allylthio)-1,3,4-thiadizole (Bialtia) ([Cu3Cl3(Bialtia)2] (1), [Cu3Cl3(Bialtia)] (2), and [Cu2Cl2(Bialtia)] (3)) are obtained by the alternating current electrochemical synthesis and studied by single crystal X-ray diffraction. A distinctive feature of Bialtia is its ability to coordinate to Cu(I) atoms by nitrogen atoms of the thiadiazole core and two allyl groups. The formation of island inorganic {Cu3Cl3} moieties occurs in 1 through π coordination of two independent Bialtia molecules by three metal atoms. Due to the absence of one Bialtia molecule in 2, inorganic {–Cu3Cl3–} subunits join into infinite chains {[Cu3Cl3(Bialtia)]}n}. The structure of [Cu2Cl2(Bialtia)] (3) contains two Cu(I) atoms with different coordination environments: distorted tetrahedral and trigonal.

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Authors and Affiliations

  1. Franko National University Lviv, Lviv, Ukraine

    Yu. I. Slyvka, B. R. Ardan & M. G. Mys’kiv

Authors
  1. Yu. I. Slyvka
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  2. B. R. Ardan
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  3. M. G. Mys’kiv
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Correspondence to Yu. I. Slyvka.

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Original Russian Text © 2018 Yu. I. Slyvka1, B. R. Ardan, M. G. Mys kiv.

Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 2, pp. 402–408, March–April, 2018.

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Slyvka, Y.I., Ardan, B.R. & Mys’kiv, M.G. Copper(I) Chloride π-Complexes with 2,5-Bis(Allylthio)-1,3,4-Thiadiazole: Synthesis and Structural Features. J Struct Chem 59, 388–394 (2018). https://doi.org/10.1134/S0022476618020191

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  • DOI: https://doi.org/10.1134/S0022476618020191

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