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Platinum(II) and platinum(IV) chloro complexes with (RS)-1-(4-chlorophenyl)-4,4-dimethyl-3-(1Н-1,2,4-triazol-1-ylmethyl)pentan-3-ol

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Abstract

Platinum(II) and platinum(IV) chloro complexes with (RS)-1-(4-chlorophenyl)-4,4-dimethyl-3-(1Н-1,2,4-triazol-1-ylmethyl)pentan-3-ol (L), namely, cis-[PtCl2L2], trans-[PtCl2L2], and trans-[PtCl4L2], were synthesized. The structures of their coordination cores and the coordination mode of the reagent to the metal ions via the N(4) atom of the triazole ring were determined by electronic, IR, and NMR 1H and 13C spectroscopy. The ratio between treo and erythro diastereomers and the conformation of reagent L in the complexes were established from the complete assignment of signals in their NMR spectra.

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Authors and Affiliations

  1. Ufa Institute of Chemistry, Russian Academy of Sciences, pr. Oktyabrya 71, Ufa, 450054, Russia

    R. A. Khisamutdinov, G. R. Anpilogova, O. V. Shitikova & Yu. I. Murinov

Authors
  1. R. A. Khisamutdinov
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  2. G. R. Anpilogova
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  3. O. V. Shitikova
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  4. Yu. I. Murinov
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Corresponding author

Correspondence to R. A. Khisamutdinov.

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Original Russian Text © R.A. Khisamutdinov, G.R. Anpilogova, O.V. Shitikova, Yu.I. Murinov, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 12, pp. 1591–1598.

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Khisamutdinov, R.A., Anpilogova, G.R., Shitikova, O.V. et al. Platinum(II) and platinum(IV) chloro complexes with (RS)-1-(4-chlorophenyl)-4,4-dimethyl-3-(1Н-1,2,4-triazol-1-ylmethyl)pentan-3-ol. Russ. J. Inorg. Chem. 61, 1530–1537 (2016). https://doi.org/10.1134/S0036023616120068

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  • DOI: https://doi.org/10.1134/S0036023616120068

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