Abstract
Many steel components are needed to be reinforced on their surface to have a high abrasive resistance and corrosion resistance. Based on self-propagating high-temperature synthesis, a process to making Al2O3 composite coatings on mild steel substrate in atmospheric environment with the help of simple auxiliary facilities was developed successfully. A pre-coated bilayer coating was employed. The effects of Fe content in pre-coated transition layer on phase composition, porosity and interfacial bonding were studied using scanning electron microscopy (SEM), energy-dispersive spectrum (EDS) and X-ray diffraction (XRD). The thermal shock resistance and abrasive resistance were investigated. When Fe content changes from 0 wt% to 50 wt%, the bond quality at first becomes better and then worse gradually. When Fe content is less 20 wt%, there is a small gap between the transition layer and the substrate; when Fe contents are 30 wt% and 40 wt%, working layer, the transition layer and the substrate bond together well. The working layer is mainly composed of Al2O3, Fe–Cr and Al(Cr)2O3 phases and has a dense structure with porosity of less than 1%. The coating has a good thermal shock resistance and abrasive resistance. The abrasive resistance of the working layer is about ten times that of the substrate.
Similar content being viewed by others
References
Kubota A, Tsubota Y, Nakano H. Electrodeposition behavior and wear resistance of Co–Ni alloys from sulfamate baths for continuous steel casting mold. Tetsu to Hagane. 1999;85(10):728.
Allcock BW, Lavin PA. Novel composite coating technology in primary and conversion industry applications. Surf Coat Technol. 2003;163(2):62.
Yang Y, Yan DR, Dong YC. Nanostructured ceramic composite coating prepared by reactive plasma spraying micro-sized Al–Fe2O3 composite powders. J Alloys Compd. 2011;509(5):L90.
Hou QY. Microstructure and wear resistance of steel matrix composite coating reinforced by multiple ceramic particulates using SHS reaction of Al–TiO2–B2O3, system during plasma transferred arc overlay welding. Surf Coat Technol. 2013;226(8):113.
Sharifitabar M, Khaki JV, Sabzevar MH. Microstructure and wear resistance of in situ TiC–Al2O3, particles reinforced Fe-based coatings produced by gas tungsten arc cladding. Surf Coat Technol. 2016;285:47.
Duan XX, Gao SY, Dong Q. Reinforcement mechanism and wear resistance of Al2O3/Fe–Cr–Mo steel composite coating produced by laser cladding. Surf Coat Technol. 2016;291:230.
Li J, Yu ZH, Wang HP, Li MP. Microstructural characterization of titanium matrix composite coatings reinforced by in situ synthesized TiB + TiC fabricated on Ti6Al4V by laser cladding. Rare Metals. 2010;29(5):465.
Yang K, Rong J, Feng JW. In-situ fabrication of amorphous/eutectic Al2O3–YAG ceramic composite coating via atmospheric plasma spraying. J Eur Ceram Soc. 2016;36(16):4261.
Xu JY, Zou BL, Tao SY. Fabrication and properties of Al2O3–TiB2–TiC/Al metal matrix composite coatings by atmospheric plasma spraying of SHS powders. J Alloys Compd. 2016;672:251.
Peng YD, Yi Y, Li LY. Iron-based soft magnetic composites with Al2O3, insulation coating produced using sol–gel method. Mater Des. 2016;109:390.
Tiwari SK, Sahu RK, Pramanick AK. Development of conversion coating on mild steel prior to sol gel nanostructured Al2O3, coating for enhancement of corrosion resistance. Surf Coat Technol. 2011;205(21–22):4960.
La PQ, Bai MW, Xue QJ. A study of Ni3Al coating on carbon steel surface via the SHS casting route. Surf Coat Technol. 1999;113(1–2):44.
Morsi K. The diversity of combustion synthesis processing: a review. J Mater Sci. 2012;47(1):68.
Zaitsev AA, Sentyurina ZA, Levashov EA. Structure and properties of NiAl–Cr(Co, Hf) alloys prepared by centrifugal SHS casting. Part 1—room temperature investigations. Mater Sci Eng A. 2017;690:463.
Wang YF, Yang ZG. Finite element analysis of residual thermal stress in ceramic-lined composite pipe prepared by centrifugal-SHS. Mater Sci Eng A. 2007;460(1):130.
Du ZZ, Fu HG, Fu HF. A study of ceramic-lined compound copper pipe produced by SHS-centrifugal casting. Mater Lett. 2005;59(14):1853.
Yuan XY, Liu GH, Jin HB. In situ synthesis of TiC reinforced metal matrix composite (MMC) coating by self propagating high temperature synthesis (SHS). J Alloys Compd. 2011;509(30):L301.
Wang CH, Wang ZH, Zhou ZH, Jiang SQ, Xue XF, Yao JJ. Fabrication and characterization of Al2O3–metal composite coating on steel plate with non-pressure combustion synthesis. Rare Metals. 2013;32(4):390.
Xue XF, Wang ZH, Zhou ZH. Bonding characteristics of the Al2O3–metal composite coating fabricated onto carbon steel by combustion synthesis. Int J Miner Metal Mater. 2014;44(9):886.
Masanta M, Shariff SM, Choudhury AR. Microstructure and properties of TiB2–TiC–Al2O3, coating prepared by laser assisted SHS and subsequent cladding with micro-/nano-TiO2, as precursor constituent. Mater Des. 2015;90:307.
Masanta M, Shariff SM, Choudhury AR. Tribological behavior of TiB2–TiC–Al2O3 composite coating synthesized by combined SHS and laser technology. Surf Coat Technol. 2010;204(16):2527.
Zang CC, Wang YZ, Zhang YD, Zhang YD, Li JH, Zeng H, Zhang DQ. Microstructure and wear-resistant properties of NiCr–Cr3C2 coating with Ni45 transition layer produced by laser cladding. Rare Metals. 2015;34(7):491.
Almangour B, Grzesiak D, Jen MY. Selective laser melting of TiC reinforced 316L stainless steel matrix nanocomposites: Influence of starting TiC particle size and volume content. Mater Des. 2016;104:141.
Qian J, Zhang J, Li S. Study on laser cladding NiAl/Al2O3 coating on magnesium alloy. Rare Metal Mater Eng. 2013;42(3):466.
Si TZ, Liu N, Zhang QA. Thermal shock fatigue behavior of TiC/Al2O3 composite ceramics. Rare Metals. 2008;27(3):308.
Mahmoodian R, Hassan MA, Hamdi M. In-situ TiC–Fe–Al2O3–TiAl/Ti3Al composite coating processing using centrifugal assisted combustion synthesis. Compos Part B Eng. 2014;59(3):279.
Sierra C, Vázquez AJ. NiAl coating on carbon steel with an intermediate Ni gradient layer. Surf Coat Technol. 2006;200(14–15):4383.
Jones M, Horlock AJ, Shipway PH. Microstructure and abrasive wear behavior of FeCr–TiC coatings deposited by HVOF spraying of SHS powders. Wear. 2001;249(s3–4):246.
Tan YF, Long HE, Wang XL. Tribological properties and wear prediction model of TiC particles reinforced Ni–base alloy composite coatings. Trans Nonferrous Met Soc China. 2014;24(8):2566.
Akhtar F, Guo SJ, Feng PZ. TiC-Maraging stainless steel composite: microstructure, mechanical and wear properties. Rare Metals. 2006;25(6):630.
Acknowledgements
This study was financially supported by the National Natural Science Foundation of China (No. 51379070) and the Fundamental Research Funds for the Central Universities (No. 2017B40314).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Gao, HD., Wang, ZH. & Shao, J. Manufacture and characteristics of Al2O3 composite coating on steel substrate by SHS process. Rare Met. 38, 704–712 (2019). https://doi.org/10.1007/s12598-017-0974-x
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12598-017-0974-x