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The enhanced surface properties of geopolymer inorganic coatings by adding with MgO

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Abstract

This paper mainly studies an inorganic coating based on geopolymer technology. Metakaolin is used as raw material, and water glass solution is used as alkali activator to prepare geopolymer. The surface properties including crack resistance and scrub resistance of the obtained coating were improved by adding certain amount of resin and fillers such as silicone acrylic emulsion, mica powder, and MgO powder. The results show that when the contents of silicone acrylic emulsion, mica powder, and MgO powder are 19.00%, 3.20%, and 2.16–2.86%, respectively, the surface properties of the coating are optimal. Especially noteworthy is that adding MgO can enhance the surface properties of the prepared coating, the mechanism of which can be rationalized by the inhibited shrinkage of the coating via microcrack deformation, the enhanced compactness and the filled pores of the coating upon adding MgO. In addition, the flame retardancy of the samples was explored through thermal analysis and cone calorimeter.

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References

  1. Habert, G, D’Espinose de Lacaillerie, JB, Roussel, N, “An Environmental Evaluation of Geopolymer Based Concrete Production: Reviewing Current Research Trends.” J. Clean. Prod., 19 1229–1238 (2011)

    Article  CAS  Google Scholar 

  2. Gaikwad, MS, Kusumkar, VV, Yemul, OS, Hundiwale, DG, “Eco-Friendly Waterborne Coating from Bio-Based Polyester Amide Resin.” Polym. Bull., 76 743–2763 (2019)

    Article  CAS  Google Scholar 

  3. Zhang, SH, You, JP, Kennes, C, Cheng, ZW, Ye, JX, Chen, DZ, Chen, JM, Wang, LD, “Current Advances of VOCs Degradation by Bioelectrochemical System: A Review.” Chem. Eng. J., 334 2625–2637 (2018)

    Article  CAS  Google Scholar 

  4. Zhang, CM, Huo, R, Wang, XD, Zhang, JY, Cheng, J, Shi, L, “In-Situ Encapsulation of Flaky Aluminum Pigment with Poly (Methylhydrosiloxane) Anti-corrosion Film for High-Performance Waterborne Coatings.” J. Ind. Eng. Chem., 89 239–249 (2020)

    Article  CAS  Google Scholar 

  5. Qi, YQ, Shen, LM, Zhang, JL, Yao, J, Lu, R, Miyakoshi, T, “Species and Release Characteristics of VOCs in Furniture Coating Process.” Environ. Pollut., 245 810–819 (2019)

    Article  CAS  Google Scholar 

  6. Singh, AP, Gunasekaran, G, Suryanarayana, C, Naik, RB, “Fatty Acid Based Waterborne Air Drying Epoxy Ester Resin for Coating Applications.” Prog. Org. Coat., 87 95–105 (2015)

    Article  CAS  Google Scholar 

  7. Weiss, KD, “Paint and Coatings: A Mature Industry in Transition.” Prog. Polym. Sci., 22 203–245 (1997)

    Article  CAS  Google Scholar 

  8. Biondi, L, Perry, M, Vlachakis, C, Wu, Z, Hamilton, A, McAlorum, J, “Ambient Cured Fly Ash Geopolymer Coatings for Concrete.” Materials, 12 923 (2019)

    Article  CAS  Google Scholar 

  9. Kakaei, MN, Danaee, I, Zaarei, D, “Investigation of Corrosion Protection Afforded by Inorganic Anticorrosive Coatings Comprising Micaceous Iron Oxide and Zinc Dust.” Corros. Eng. Sci. Technol., 48 194–198 (2013)

    Article  CAS  Google Scholar 

  10. McLellan, BC, Williams, RP, Lay, J, Riessen, AV, Corder, GD, “Costs and Carbon Emissions for Geopolymer Pastes in Comparison to Ordinary Portland Cement.” J. Clean. Prod., 19 1080–1090 (2011)

    Article  CAS  Google Scholar 

  11. Mellado, A, Catalan, C, Bouzon, N, Borrachero, MV, Monzo, JM, Paya, J, “Carbon Footprint of Geopolymeric Mortar: Study of the Contribution of the Alkaline Activating Solution and Assessment of an Alternative Route.” RSC Adv., 4 23846–23852 (2014)

    Article  CAS  Google Scholar 

  12. Wu, YG, Lu, BW, Bai, W, Du, TH, Zhang, YF, Cai, L, Jiang, C, Wang, WJ, “Geopolymer, Green Alkali Activated Cementitious Material: Synthesis, Applications and Challenges.” Constr. Build. Mater., 224 930–949 (2019)

    Article  CAS  Google Scholar 

  13. Lahoti, M, Tan, KH, Yang, EH, “A Critical Review of Geopolymer Properties for Structural Fire-Resistance Applications.” Constr. Build. Mater., 221 514–526 (2019)

    Article  CAS  Google Scholar 

  14. Lv, XS, Wang, KT, He, Y, Cui, XM, “A Green Drying Powder Inorganic Coating Based on Geopolymer Technology.” Constr. Build. Mater., 214 441–448 (2019)

    Article  CAS  Google Scholar 

  15. Alshaaer, M, “Synthesis and Characterization of Self-healing Geopolymer Composite.” Constr. Build. Mater., 45 118432 (2020)

    Article  CAS  Google Scholar 

  16. Chen, YX, Shui, ZH, Chen, W, Duan, P, Chen, GW, “Effect of lDHs Modified Mk-Based Geopolymer Coating on Durability of Concrete.” B. Chin. Ceram. Soc., 34 1968–1973 (In Chinese) (2015)

    CAS  Google Scholar 

  17. Mu, S, Liu, JP, Lin, W, Wang, YC, Liu, JZ, Shi, L, Jiang, Q, “Property and Microstructure of Aluminosilicate Inorganic Coating for Concrete: Role of Water to Solid Ratio.” Constr. Build. Mater., 148 846–856 (2017)

    Article  CAS  Google Scholar 

  18. Myers, RJ, Bernal, SA, San Nicolas, R, Provis, JL, “Generalized Structural Description of Calcium-Sodium Aluminosilicate Hydrate Gels: The Cross-Linked Substituted Tobermorite Model.” Langmuir, 29 5294–5306 (2013)

    Article  CAS  Google Scholar 

  19. Villaquiran-Caicedo, MA, de Gutierrez, RM, “Mechanical and Microstructural Analysis of Geopolymer Composites Based on Metakaolin and Recycled Silica.” J. Am. Ceram. Soc., 102 3653–3662 (2019)

    Article  CAS  Google Scholar 

  20. Siti Salwa, MS, Mustafa Al Bakri, AM, Kamarudin, H, Ruzaidi, CM, Binhussain, M, Sharifah Zaliha, SZ, “Review on Current Geopolymer as a Coating Material.” AJBAS, 7 (5) 246–257 (2013)

    CAS  Google Scholar 

  21. Amran, YHM, Alyousef, R, Alabduljabbar, H, El-Zeadani, M, “Clean Production and Properties of Geopolymer Concrete: A Review.” J. Clean. Prod., 251 119679 (2020)

    Article  CAS  Google Scholar 

  22. Bai, CY, Colombo, P, “Processing, Properties and Applications of Highly porous Geopolymers: A Review.” Ceram. Int., 44 16103–16118 (2018)

    Article  CAS  Google Scholar 

  23. Aguirre-Guerrero, AM, Robayo-Salazar, RA, de Gutierrez, RM, “A Novel Geopolymer Application: Coatings to Protect Reinforced Concrete Against Corrosion.” Appl. Clay. Sci., 135 437–446 (2017)

    Article  CAS  Google Scholar 

  24. Jiang, CH, Wang, AY, Bao, XF, Ni, TY, Ling, J, “A Review on Geopolymer in Potential Coating Application: Materials, Preparation and Basic Properties.” J. Build. Eng., 32 101734 (2020)

    Article  Google Scholar 

  25. Kan, LL, Lv, JW, Duan, BB, Wu, M, “Self-healing of Engineered Geopolymer Composites Prepared by Fly Ash and Metakaolin.” Cem. Concr. Res., 125 105895 (2019)

    Article  CAS  Google Scholar 

  26. Shi, HS, Wu, M, “Geo-Polymerization Research Status of Geopolymeric Cement.” Mater Rev., 08 88–91 (In Chinese) (2007)

    Google Scholar 

  27. Mao, YW, Biasetto, L, Colombo, P, “Metakaolin-Based Geopolymer Coatings on Metals by Airbrush Spray Deposition.” J. Coat. Technol. Res., 17 991–1002 (2020)

    Article  CAS  Google Scholar 

  28. Jamil, NH, Al Bakri Abdullah, MM, Pa, FC, Mohamad, HW, Ibrahim, WMA, Chaiprapa, J, “Influences of SiO2, Al2O3, CaO and MgO in Phase Transformation of Sintered Kaolin-Ground Granulated Blast Furnace Slag Geopolymer.” J. Mater. Res. Technol., 9 14922–14932 (2020)

    Article  CAS  Google Scholar 

  29. Foster, D, Thompson, PD, “The Use of MgO as a Densification Aid for α-SiC.” J. Eur. Ceram. Soc., 19 2823–2831 (1999)

    Article  CAS  Google Scholar 

  30. Badogiannis, E, Kakali, G, Tsivilis, S, “Metakaolin as Supplementary Cementitious Material: Optimization of Kaolin to Metakaolin Conversion.” J. Therm. Anal. Calorim., 81 457–462 (2005)

    Article  CAS  Google Scholar 

  31. ISO5660, “Reaction to Fire Tests—Heat Release, Smoke Production and Mass Loss Rate (Cone Calorimeter Method).”

  32. Xie, HY, Yang, W, Yuen, ACY, Xie, C, Xie, JS, Lu, HD, Yeoh, GH, “Study on Flame Retarded Flexible Polyurethane Foam/Alumina Aerogel Composites with Improved Fire Safety.” Chem. Eng. J., 311 310–317 (2017)

    Article  CAS  Google Scholar 

  33. Wang, YC, Zhao, JP, “Facile Preparation of Slag or Fly Ash Geopolymer Composite Coatings with Flame Resistance.” Constr. Build. Mater., 203 655–661 (2019)

    Article  CAS  Google Scholar 

  34. Kim, DH, Lee, YH, Park, CC, Kim, HD, “Synthesis and Surface Properties of Self-crosslinking Core–Shell Acrylic Copolymer Emulsions Containing Fluorine/Silicone in the Shell.” Colloid. Polym. Sci., 292 173–183 (2014)

    Article  CAS  Google Scholar 

  35. Zhou, M, Zhai, SX, Song, TT, Zhao, H, Fan, ZZ, Ge, FY, Zhao, YP, Xu, B, Cai, ZS, “Chemically and Physically Modified Flame-Retardant Silicone-Acrylic Emulsion Adhesive for Electrostatic Flocking.” J. Inorg. Organomet. Polym. Mater., 30 4342–4349 (2020)

    Article  CAS  Google Scholar 

  36. Gong, YL, Shao, TT, Chen, XL, Cao, SS, Chen, LJ, “Silicone Acrylate Dispersion Based on Semi-continuous Seed Emulsion Polymerization Using Polymerizable Emulsifiers.” Chem. Pap., 74 2875–2882 (2020)

    Article  CAS  Google Scholar 

  37. Tian, QB, Li, CZ, Li, HW, Wang, Y, Lv, ZJ, “An Overview on Study of the Mica-Based Glass-Ceramic Composites.” Mater. Rev., 13 2191–2196 (In Chinese) (2019)

    Google Scholar 

  38. Au, PI, Siow, SY, Avadiar, L, Lee, EM, Leong, YK, “Muscovite Mica and Koalin Slurries: Yield Stress–Volume Fraction and Deflocculation Point Zeta Potential Comparison.” Powder Technol., 262 124–130 (2014)

    Article  CAS  Google Scholar 

  39. Lv, XS, Qin, Y, Lin, ZX, Tian, ZK, Cui, XM, “Inhibition of Efflorescence in Na-Based Geopolymer Inorganic Coating.” ACS. Omega, 5 14822–14880 (2020)

    Article  CAS  Google Scholar 

  40. Li, CC, Shi, H, Zhou, WL, Zha, J, Huang, JY, Shen, WG, “Influence of the Thermal Treatment Process of MgO on Alkali-Activated Cement.” B. Chin. Ceram. Soc., 35 632–637 (In Chinese) (2016)

    Google Scholar 

  41. Shen, WG, Wang, YH, Zhang, T, Zhou, MK, Li, JS, Cui, XY, “Magnesia Modification of Alkali-Activated Slag Fly Ash Cement.” J. Wuhan Univ. Technol., 26 121–125 (2011)

    Article  CAS  Google Scholar 

  42. Li, ZH, Yang, YM, Chen, XW, Yu, QJ, “Effects of Collocation of MgO on the Volumetric Deformation and Microstructure of Hardened Geopolymer Pastes.” Concrete, 6 47–51 (In Chinese) (2018)

    Google Scholar 

  43. Wei, YJ, Gu, SJ, Fang, HL, “Properties of MgO Transparent Ceramics Prepared at Low Temperature Using High Sintering Activity MgO Powders.” J. Am. Ceram. Soc., 9 5382–5391 (2020)

    Article  CAS  Google Scholar 

  44. Long, Y, Huang, LJ, Che, JT, “Role of MgO on Densification and Mechanical Properties in Spark Plasma Sintered Os0.9Re0.1B2 Ceramic.” Ceram. Int., 46 2612–2617 (2020)

    Article  CAS  Google Scholar 

  45. Li, ZH, Zhang, W, Wang, RL, Chen, FZ, Jia, XC, Cong, PT, “Effects of Reactive MgO on the Reaction Process of Geopolymer.” Materials, 12 526 (2019)

    Article  CAS  Google Scholar 

  46. Kumar, M, Kumar, M, Arora, S, “Thermal Degradation and Flammability Studies of Wood Coated with Fly Ash Intumescent Composites.” J. Indian Acad. Wood Sci., 10 125–133 (2013)

    Article  Google Scholar 

  47. Temuujin, J, Minjigmaa, A, Rickard, W, Lee, M, Williams, I, Riessen, AV, “Preparation of Metakaolin Based Geopolymer Coatings on Metal Substrates as Thermal Barriers.” Appl. Clay Sci., 46 265–270 (2009)

    Article  CAS  Google Scholar 

  48. Wang, YC, Zhao, JP, “Comparative Study on Flame Retardancy of Silica Fume-Based Geopolymer Activated by Different Activators.” J. Alloys Compd., 743 108–114 (2018)

    Article  CAS  Google Scholar 

  49. Zhang, ZT, Wang, KT, Mo, BH, Li, XF, Cui, XM, “Preparation and Characterization of a Reflective and Heat Insulative Coating Based on Geopolymers.” Energy Build., 87 220–225 (2015)

    Article  Google Scholar 

  50. Lizcano, M, Kim, HS, Basu, S, Radovic, M, “Mechanical Properties of Sodium And Potassium Activated Metakaolin-Based Geopolymers.” J. Mater. Sci., 47 2607–2616 (2012)

    Article  CAS  Google Scholar 

  51. Khan, MI, Azizlin, K, Sufifian, S, Man, Z, “Sodium Silicate-free Geopolymers as Coating Materials: Effects of Na/Al and Water/Solid Ratios on Adhesion Strength.” Ceram. Int., 41 2794–2805 (2015)

    Article  CAS  Google Scholar 

  52. Liu, N, Huo, K, McDowell, MT, Zhao, J, Cui, Y, “Rice Husks as a Sustainable Source of Nanostructured Silicon for High Performance Li-ion Battery Anodes.” Sci. Rep., 3 1919 (2013)

    Article  Google Scholar 

  53. Temuujin, J, Rickard, W, Lee, M, Riessen, AV, “Preparation and Thermal Properties of Fire Resistant Metakaolin-Based Geopolymer-Type Coatings.” J. Non-Cryst. Solids, 357 1399–1404 (2011)

    Article  CAS  Google Scholar 

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Acknowledgments

The authors would like to thank the financial supports from the Anhui Provincial key R & D projects (No. 201904a05020033) and the Anhui Provincial Natural Science Foundation (No. 1908085MB42).

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X.L., Y.F., and Y.L. contributed to the conception and design of the experiments, analysis of the data and the writing of the manuscript. W.L., J.W., C.L., B.Y., and Z.P. assisted Y.L. for the synthesis of materials and the data collection and analysis. All authors contributed to the discussion and manuscript preparation.

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Correspondence to Xueting Liu.

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Liu, X., Fan, Y., Li, Y. et al. The enhanced surface properties of geopolymer inorganic coatings by adding with MgO. J Coat Technol Res 19, 947–957 (2022). https://doi.org/10.1007/s11998-021-00572-z

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  • DOI: https://doi.org/10.1007/s11998-021-00572-z

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