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Improvement of adherence and anticorrosion properties of an epoxy-polyamide coating on steel by incorporation of an indole-3 butyric acid-modified nanomagnetite

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Abstract

In this study, synthesized magnetite (Fe3O4) nanoparticles were treated with a corrosion inhibitor, indole-3 butyric acid (IBA) and incorporated in an epoxy-polyamide coating. The coating was applied on a carbon steel substrate. For comparison, coatings without particles or with nontreated Fe3O4 particles were also prepared. The IBA-modified nanomagnetite (IBA–Fe3O4) was characterized by infrared spectroscopy and Zeta potential measurements. The inhibitive action of IBA was shown by electrochemical measurements (polarization curves) performed for a bare carbon steel in 0.1 M NaCl solution containing Fe3O4 or IBA–Fe3O4 nanoparticles. Adherence and anticorrosion properties of the epoxy-based coatings containing Fe3O4 or IBA–Fe3O4 were compared to those of the pure epoxy-polyamide resin by dry and wet adherence measurements and by salt spray test. The results showed significant improvement of the film adherence and higher corrosion protection of the carbon steel in the presence of IBA–Fe3O4. It was concluded that the IBA effect was restricted to the metal/coating interface.

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Acknowledgments

This work was carried out with financial support from National Foundation for Science and Technology Development of Vietnam (NAFOSTED, Project 104.01-2011.01), Vietnamese Academy of Science and Technology (VAST, Project VAST.HTQT.Phap.02/13-14), Vietnamese National University of Hanoi (Project QG.12.05), and from CNRS, France (LIA-FOCOMAT Project).

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Authors and Affiliations

  1. Laboratory for Protective Coatings, Institute for Tropical Technology, VAST, 18, Hoang Quoc Viet, Hanoi, Vietnam

    Anh Truc Trinh, Thu Trang Nguyen, Thu Thuy Thai & Thi Xuan Hang To

  2. Faculty of Chemistry, VNU University of Science, 19, Le Thanh Tong, Hanoi, Vietnam

    Xuan Hoan Nguyen

  3. Université de Toulouse, CIRIMAT, UPS/INPT/CNRS, 4, allée Emile Monso, CS 44362, 31030, Toulouse Cedex 4, France

    Anh Son Nguyen, Maëlenn Aufray & Nadine Pébère

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  1. Anh Truc Trinh
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Correspondence to Anh Truc Trinh or Thi Xuan Hang To.

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Trinh, A.T., Nguyen, T.T., Thai, T.T. et al. Improvement of adherence and anticorrosion properties of an epoxy-polyamide coating on steel by incorporation of an indole-3 butyric acid-modified nanomagnetite. J Coat Technol Res 13, 489–499 (2016). https://doi.org/10.1007/s11998-015-9768-y

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  • DOI: https://doi.org/10.1007/s11998-015-9768-y

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