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Functionalization of sterically hindered catechol and o-benzoquinone with 2,2,6,6-tetramethylpiperidine 1-oxyl

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Abstract

Sterically hindered 4,6-di-tert-butyl-3-formylcatechol and 3,6-di-tert-butyl-o-benzoquinone react with 4-amino-2,2,6,6-tetramethylpiperidine 1-oxyl to give new chelate ligands of the o-quinone type bearing a 2,2,6,6-tetramethylpiperidine 1-oxyl neutral radical moiety. Structures of the synthesized compounds were established by ESR spectroscopy, IR spectroscopy, mass spectrometry, and X-ray diffraction analysis.

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603137, Nizhny Novgorod, Russian Federation

    N. O. Druzhkov, E. N. Egorova, M. V. Arsen’ev, E. V. Baranov & V. K. Cherkasov

Authors
  1. N. O. Druzhkov
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  2. E. N. Egorova
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  3. M. V. Arsen’ev
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  4. E. V. Baranov
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  5. V. K. Cherkasov
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Corresponding author

Correspondence to V. K. Cherkasov.

Additional information

Dedicated to Academician of the Russian Academy of Sciences R. Z. Sagdeev on the occasion of his 75th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2855–2860, December, 2016.

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Druzhkov, N.O., Egorova, E.N., Arsen’ev, M.V. et al. Functionalization of sterically hindered catechol and o-benzoquinone with 2,2,6,6-tetramethylpiperidine 1-oxyl. Russ Chem Bull 65, 2855–2860 (2016). https://doi.org/10.1007/s11172-016-1668-5

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  • DOI: https://doi.org/10.1007/s11172-016-1668-5

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