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Functionalization of sterically hindered o-benzoquinones: amino-substituted 3,6-di(tert-butyl)-o-benzoquinones

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Abstract

New sterically hindered functionalized o-quinones were synthesized by the 1,4-nucleophilic addition of secondary cyclic amines to 3,6-di(tert-butyl)-o-benzoquinone. The ability of these o-quinones to form o-semiquinone complexes with transition and main-group metals was studied by ESR spectroscopy in solution.

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhny Novgorod, Russian Federation

    G. A. Abakumov, V. K. Cherkasov, T. N. Kocherova, N. O. Druzhkov, Yu. A. Kurskii, M. P. Bubnov, G. K. Fukin & L. G. Abakumova

Authors
  1. G. A. Abakumov
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  2. V. K. Cherkasov
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  3. T. N. Kocherova
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  4. N. O. Druzhkov
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  5. Yu. A. Kurskii
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  6. M. P. Bubnov
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  7. G. K. Fukin
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  8. L. G. Abakumova
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Corresponding author

Correspondence to T. N. Kocherova.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1786–1793, September, 2007.

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Abakumov, G.A., Cherkasov, V.K., Kocherova, T.N. et al. Functionalization of sterically hindered o-benzoquinones: amino-substituted 3,6-di(tert-butyl)-o-benzoquinones. Russ Chem Bull 56, 1849–1856 (2007). https://doi.org/10.1007/s11172-007-0287-6

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  • DOI: https://doi.org/10.1007/s11172-007-0287-6

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