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A magnetic metal/polymer nanocomposite material based on poly(diphenylamine) and Fe3O4 nanoparticles

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Abstract

It was discovered that IR heating of poly(diphenylamine) in the presence of FeCl3•6H2O in an inert atmosphere at 300–700 °C produces a metal polymer nanocomposite with Fe3O4 nanoparticles dispersed in polymer matrix. This is achieved by condensation of crystalline diphenylamine oligomers with evolution of hydrogen that promotes iron reduction. The formation of Fe3O4 nanoparticles was confirmed by X-ray powder diffraction. The magnetic and thermal properties of the Fe3O4—poly(diphenylamine) nanocomposite were examined. This nanocomposite material shows superparamagnetism and thermal stability.

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp., 119991, Moscow, Russian Federation

    S. Zh. Ozkan, G. P. Karpacheva, M. N. Efimov & G. N. Bondarenko

  2. National University of Science and Technology “MISiS”, 4 Leninsky prosp., 119049, Moscow, Russian Federation

    E. L. Dzidziguri

  3. Department of Chemistry, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    P. A. Chernavskii

Authors
  1. S. Zh. Ozkan
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  2. E. L. Dzidziguri
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  3. G. P. Karpacheva
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  4. P. A. Chernavskii
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  5. M. N. Efimov
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  6. G. N. Bondarenko
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Corresponding author

Correspondence to S. Zh. Ozkan.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0196–0201, January, 2015.

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Ozkan, S.Z., Dzidziguri, E.L., Karpacheva, G.P. et al. A magnetic metal/polymer nanocomposite material based on poly(diphenylamine) and Fe3O4 nanoparticles. Russ Chem Bull 64, 196–201 (2015). https://doi.org/10.1007/s11172-015-0842-5

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  • DOI: https://doi.org/10.1007/s11172-015-0842-5

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