Abstract
Lanthanum oxide compounds are of great interest because of their wide range of applications (e.g., heterogeneous catalysis). It is well known that lanthanum oxide compounds, like lanthanum oxide, have to be handled carefully in a humid atmosphere due to their hydration affinity. Furthermore, lanthanum hydroxide has a high CO2 affinity and partially forms basic carbonates. The amount of carbonate impurities that are formed in air remains nearly constant over a long time. To investigate the carbonation process in more detail, lanthanum hydroxide and lanthanum oxide were stored in a controlled humid CO2 atmosphere. The results of thermal analysis (TA) and X-ray diffraction (XRD) prove a transformation of lanthanum hydroxide as well as lanthanum oxide to lanthanum carbonate via lanthanum hydroxide carbonate.
Similar content being viewed by others
References
Valange S, Beauchaud A, Barrault J, Gabelica Z, Daturi Z, Can F. Lanthanum oxides for the selective synthesis of phytosterol esters: correlation between catalytic and acid-base properties. J Catal. 2007;251:113–22.
Zhou Q, Zhang H, Chang F, Li H, Pan H, Xue W, Hu DY, Yang S. Nano La2O3 as a heterogeneous catalyst for biodiesel synthesis by transesterification of Jatropha curcas L. oil. J Ind Eng Chem. 2015;31:385–92.
Lin CH, Campbell D, Wang JX, Lunsford H. Oxidative dimerization of methane over lanthanum oxide. J Phys Chem. 1986;90:534–7.
Campbell KD, Zhang H, Lunsford JH. Methane activation by the lanthanide oxides. J Phys Chem. 1988;92:750–3.
Bernal S, Martin GA, Moral O, Perricho V. Oxidative dehydrogenation of ethane over lanthana: actual nature of the active phase. Catal Lett. 1990;6:231–8.
Chen H, Yu H, Peng F, Wang H, Yang J, Pan M. Efficient and stable oxidative stream reforming of ethanol for hydrogen production: effect of in situ dispersion of Ir over Ir/La2O3. J Catal. 2010;269:281–90.
Wang F, Ta N, Li Y, Shen W. La(OH)3 and La2O2CO3 nanorod catalysts for Claisen-Schmidt condensation. Chin J Catal. 2014;35:437–43.
Gao J, Hou Z, Guo J, Zhu Y, Zheng X. Catalytic conversion of methane and CO2 to synthesis gas over a La2O3-modified SiO2 supported Ni catalyst in fluidized-bed reactor. Catal Today. 2008;131:278–84.
Huang SJ, Walters AB, Vannice MA. Adsorption and decomposition of NO on lanthanum oxide. J Catal. 2000;192:29–47.
Wang F, Lu G. High performance rare earth oxides LnOx (Ln = La, Ce, Nd, Sm and Dy)-modified Pf/SiO2 catalysts for CO oxidation in the presence of H2. J Powder Sour. 2008;181:120–6.
Haensch A, Borowski D, Barsan N, Koziej D, Niederberger M, Weimer U. Faster response times of rare-earth oxycarbonate based CO2 sensors and another readout strategy for real-world applications. Proc Eng. 2011;25:1429–32.
Tang L, Li Y, Xu K, Hou X, Lv Y. Sensitive and selective acetone sensor based in its cataluminescence from nano-La2O3 surface. Sens Actuator B. 2008;132:243–9.
Koyabu K, Masui T, Tamura S, Imanaka N. Synthesis of new phosphor based on rare earth oxycarbonate. J Alloys Compd. 2006;408–412:867–70.
Wang S, Wang W, Qian Y. Preparation of La2O3 thin films by pulse ultrasonic spray pyrolysis method. Thin Solid Films. 2000;372:50–3.
Laiho R, Lähderanta E, Säisä L, Kovács G, Zsolt G, Kirscher I, Halász I. Optically induced changes in the magnetic properties of the ceramic superconductor La1.8Ba0.2CuO4. Phys Rev B. 1990;42:347–53.
Normand B, Rice TM. Dynamical properties of an antiferromagnet near the quantum critical point: application to LaCuO2.5. Phys Rev B. 1997;56:8760–73.
Béchade E, Julien I, Iwata T, Masson O, Thomas P, Champion E, Fukuda K. Synthesis of lanthanum silicate oxyapatite materials as a solid oxide fuel cell electrolyte. J Eur Ceram Soc. 2008;28:2717–24.
Imanaka N, Okamoto K, Adachi G. Water-insoluble lanthanum oxychloride-based solid electrolytes with ultra-high chloride ion conductivity. Angew Chem Int Ed. 2002;41:3890–2.
Xu Y, Peng Y, Zheng X, Dearn KD, Xu H. Synthesis and tribological studies of nanoparticle additives for pyrolysis bio-oil formulated as a diesel fuel. Energy. 2015;83:80–8.
Mazloumi M, Zanganeh S, Kajbafvala A, Shayegh MR, Sadrnezhaad SK. Formation of lanthanum hydroxide nanostructures: effect of NaOH and KOH solvents. Int J Eng Trans B. 2008;21:169–76.
Wang X, Li Y. Synthesis and characterization of lanthanide hydroxide single-crystal nanowires. Angew Chem Int Ed. 2002;4:4790–3.
Méndez M, Carvajal JJ, Marsal LF, Salagre P, Aguiló M, Díaz F, Formentín P, Pallarès J, Cesteros Y. Effect of the La(OH)3 preparation method on the surface and rehydroxylation properties of resulting La2O3. J Nanopart Res. 2013;15:1479.
Li SCH, Du N, Fan JN, Xu LJ, Xu J. Low-temperature chemical solution synthesis of dendrite-like La(OH)3 nanostructures and their thermal conversion to La2O3 nanostructures. Rare Met. 2015;34:395–9.
Salavati-Niasari M, Hosseinzadeh G, Davar F. Synthesis of lanthanum carbonate nanoparticles via sonochemical method for preparation of lanthanum hydroxide and lanthanum oxide nanoparticles. J Alloys Compd. 2011;509:134–40.
Zhu J, Gui Z, Ding Y. A simple rout to lanthanum hydroxide nanorods. Mater Lett. 2008;62:2373–6.
Ozawa M, Onoe R, Kato H. Formation and decomposition of some rare earth (RE = La, Ce, Pr) hydroxides and oxides by homogeneous precipitation. J Alloys Compd. 2006;408–412:556–9.
Mu Q, Chen T, Wang Y. Synthesis, characterization and photoluminescence of lanthanum hydroxide nanorods by a simple route at room temperature. Nanotechnology. 2009;20:345602.
Leidinger P, Popescu R, Gerthsen D, Feldmann C. Nanoscale La(OH)3 hallow spheres and fine-tuning of its outer diameter and cavity size. Small. 2010;6:1886–91.
Zheng D, Shi J, Lu X, Wang C, Liu Z, Liang C, Liu P, Tong Y. Controllable growth of La(OH)3 nanorod and nanotube arrays. Cryst Eng Comm. 2010;12:4066–70.
Füglein E, Walter D. Thermal analysis of lanthanum hydroxide. J Therm Anal Calorim. 2012;110:199–202.
Neumann A, Walter D. The thermal transformation from lanthanum hydroxide to lanthanum hydroxide oxide. Thermochim Acta. 2006;445:200–4.
Bernal S, Díaz JA, García R, Rodríguez-Izquierdo JM. Study of some aspects of the reactivity of La2O3 with CO2 and H2O. J Mat Sci. 1985;20:537–41.
Bernal S, Botana FJ, García R, Ramírez F, Rodríguez-Izquierdo JM. Solid state chemistry of the preparation of lanthana-supported metal catalyst—study of the impregnation step. J Mat Sci. 1987;22:3793–800.
Hubbard CR, Evans EH, Smith DK. The reference intensity ratio, I/Ic, for computer simulated powder patterns. J Apll Cryst. 1976;9:169–74.
Alvero R, Odriozola JA, Trillo JM, Bernal S. Lanthanide oxides: preparation and ageing. J Chem Soc Dalton Trans. 1984(1);87–91.
Bernal S, Blanco G, Calvino JJ, Pérez Omil JA, Pintado JM. Some major aspects of the chemical behavior of rare earth oxides: an overview. J Alloys Compd. 2006;408–412:496–502.
Nikulshina V, Gálvez ME, Steinfeld A. Kinetic analysis of the carbonation reactions for the capture of CO2 from air via the Ca(OH)2-CaCO3-CaO solar thermochemical cycle. Chem Eng J. 2007;129:75–83.
Shih SM, Ho CS, Song YS, Lin JP. Kinetics of the reaction of Ca(OH)2 with CO2 at low temperature. Ind Eng Chem Res. 1999;38:1316–22.
Acknowledgements
We would like to thank Dr. Carolin Fischer, NETZSCH-Gerätebau, for the TG–FTIR analysis.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Haibel, E., Berendts, S. & Walter, D. Thermogravimetric and X-ray diffraction investigation on carbonated lanthanum oxide and lanthanum hydroxide formed in humid CO2 atmosphere. J Therm Anal Calorim 134, 261–267 (2018). https://doi.org/10.1007/s10973-018-7256-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10973-018-7256-1