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Pyrolysis mechanism of a β-O-4 type lignin dimer model compound

A joint theoretical and experimental study

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Abstract

To help understand the pyrolysis mechanism of lignin, a non-phenolic lignin dimer model compound with β-O-4 linkage, namely 1-methoxy-2-(4-methoxyphenethoxy)benzene, was prepared. Its pyrolysis mechanism was investigated by density functional theory calculations and confirmed by the analytical pyrolysis–gas chromatography/mass spectrometry experiments. Possible pyrolytic pathways were proposed and analyzed based on three initial pyrolysis mechanisms of the model compound, including the C β –O homolytic mechanism, the C α –C β homolytic mechanism and the C β –O concerted decomposition mechanism. The results indicate that the lignin dimer model compound is thermally stable at low pyrolysis temperature (300 °C), whereas at moderate pyrolysis temperature (500 °C), four major pyrolytic products will be generated via the initial C β –O concerted decomposition and C β –O homolysis, including the 1-methoxy-4-vinylbenzene, 2-hydroxybenzaldehyde, 1-ethyl-4-methoxybenzene and 2-methoxyphenol. Products from the C α –C β homolysis can hardly be formed, due to the high-energy barriers and limitation of the available free hydrogen atoms. Secondary cracking of the primary pyrolytic products will take place to form some light compounds, which will be enhanced with the increase in pyrolysis temperature.

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Acknowledgements

The authors thank the National Natural Science Foundation of China (51276062), National Torch Plan (2013GH561645), 111 Project (B12034), Foundation of State Key Laboratory of Coal Combustion (FSKLCC1413), and Fundamental Research Funds for the Central Universities (2014ZD17) for financial support.

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Authors and Affiliations

  1. National Engineering Laboratory for Biomass Power Generation Equipment, North China Electric Power University, Beijing, 102206, China

    Jun-jiao Zhang, Xiao-yan Jiang, Xiao-ning Ye, Qiang Lu & Chang-qing Dong

  2. State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan, 430074, Hubei, China

    Lei Chen & Xian-hua Wang

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  1. Jun-jiao Zhang
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  2. Xiao-yan Jiang
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  7. Chang-qing Dong
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Correspondence to Qiang Lu or Chang-qing Dong.

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Zhang, Jj., Jiang, Xy., Ye, Xn. et al. Pyrolysis mechanism of a β-O-4 type lignin dimer model compound. J Therm Anal Calorim 123, 501–510 (2016). https://doi.org/10.1007/s10973-015-4944-y

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  • DOI: https://doi.org/10.1007/s10973-015-4944-y

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