Abstract
In this paper, a new La(III) ion-imprinted polymer La(III)-IIP was prepared by imprinting polymerization method, using methacrylic acid as the functional monomer and alkylated mesoporous silica as the carrier. La(III)-IIP was characterized by FTIR and SEM techniques. The material was also used to capture La3+ in low concentration wastewater, and the structural morphology as well as the elemental composition of the material were characterized and analyzed. In addition, based on the characterization and experimental data, the adsorption type of La(III) and the possible adsorption mechanism of the material were further analyzed, and finally, the selective adsorption of lanthanum and the regeneration performance of the material were investigated.
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A. Tk, C. Akb, C. Alb et al., Adsorption of rare earth metals from wastewater by nanomaterials: a review. J. Hazard. Mater. 386, 121632 (2020)
F.H. Robert, C. Thibault, E.C. Bren et al., Magnetic Field Directed Rare-Earth Separations. Angew. Chem. Int. Ed. 132(5), 1867–1872 (2019)
M.J. Simon, T.W. Timothy, W. Zhehan et al., Recycling of the rare earth elements. Curr. Opin. Green Sustain. Chem. 13, 1–7 (2018)
A. Ioannis, B. Amit, C.L. Eder, Adsorption of rare earth metals: a review of recent literature. J. Mol. Liq. 221, 954–962 (2016)
T. Yue, S. Lu, F. Chong et al., Distribution of rare earth elements (REEs) and their roles in plants growth: a review. Environ. Pollut. 298, 118540 (2021)
H. Minowa, M. Ebihara, Separation of rare earth elements from scandium by extraction chromatography. Anal. Chim. Acta 498(1–2), 25–37 (2003)
F. Nicolas, B. Germain, B. Dominique et al., Determination of rare earth elements and other trace elements (Y, Mn Co, Cr) in seawater using Tm addition and Mg(OH)2 co-precipitation. Talanta 85(1), 582–587 (2011)
A. Tsuyoshi, W. Yuezhou, K. Mikio et al., Separation of rare earths in nitric acid medium by a novel silica-based pyridinium anion exchange resin. J. Alloys Compd. 408, 1008–1012 (2006)
D. İlayda, E. Duygu, R.K. Ali, Graphene oxides for removal of heavy and precious metals from wastewater. J. Mater. Sci. 51, 6097–6116 (2016)
Z. Yongfeng, Z. Yian, W. Aiqin, A simple approach to fabricate granular adsorbent for adsorption of rare elements. Int. J. Biol. Macromol. 72, 410–420 (2014)
M. Shamsipur, J. Fasihi, A. Khanchi et al., A stoichiometric imprinted chelating resin for selective recognition of copper (II) ions in aqueous media. Anal. Chim. Acta 599(2), 294–301 (2007)
A. Koohpaei, S. Shahtaheri, M. Ganjali et al., Application of multivariate analysis to the screening of molecularly imprinted polymers (MIPs) for ametryn. Talanta 75(4), 978–986 (2008)
B. Ooa, Macroporous copolymer networks. Prog. Polym. Sci. 25(6), 711–779 (2000)
J. Fu, L. Chen, J. Li et al., Current status and challenges of ion imprinting. J. Mater. Chem. A 2015(3), 13598–13627 (2015)
Y. Huang, R. Wang et al., Review on Fundamentals, preparations and applications of imprinted polymers. Curr. Org. Chem. 22(16), 1600–1618 (2018)
O.Y. Kim, Preparation of mesoporous silica by the rapid gelation of Na2SiO3 and H2SiF6 in aqueous surfactant solution. Microporous Mesoporous Mater. 285, 137–141 (2019)
M.H. Mostafa, S.E. Rizk, A.A. Nayl, Adsorption kinetics and modeling of gadolinium and cobalt ions sorption by an ion-exchange resin. Part. Sci. Technol. 34(6), 716–724 (2015)
H. Azhar-Abdul, A. Hamidi-Abdul, M.J. Megat-Azmi et al., Comparison study of ammonia and COD adsorption on zeolite, activated carbon and composite materials in landfill leachate treatment. Desalination 262(1–3), 31–35 (2010)
L. Sheng-Yu, G. Jin, Q. Bin et al., Kinetic models for the adsorption of lead ions by steel slag. Waste Manage. Res. 262(1–3), 31–35 (2009)
S. Qianqian, F. Yi, L. Zhenya et al., The performance of porous hexagonal BN in high adsorption capacity towards antibiotics pollutants from aqueous solution. Chem. Eng. J. 325, 71–79 (2017)
L. Xing, C. Ya-Shuo, Z. Qian et al., Removal of iodine from aqueous solution by PVDF/ZIF-8 nanocomposite membranes. Sep. Purif. Technol. 238, 116488 (2019)
J.S. Piccin, T. Cadaval, L. Pinto et al., Adsorption Isotherms in Liquid Phase: Experimental, Modeling, and Interpretations (Springer International Publishing, New York, 2017)
M.A. Al-Anber, Adsorption of ferric ions onto natural feldspar: kinetic modeling and adsorption isotherm. Int. J. Environ. Sci. Technol. 12, 139–150 (2013)
S. Gaurav, N. Mu, Adsorptive removal of noxious cadmium ions from aqueous medium using activated carbon/zirconium oxide composite: Isotherm and kinetic modelling. J. Mol. Liq. 310, 113025 (2020)
P.S. Neetu, Synthesis, characterization and sorption behavior of zirconium(IV) antimonotungstate: an inorganic ion exchanger. Desalination 267(2–3), 277–285 (2011)
F. Mojtaba, A. Asghar, L. Milad Jamal et al., Adsorption of lead(II) and chromium(VI) from aqueous environment onto metal-organic framework MIL-100(Fe): synthesis, kinetics, equilibrium and thermodynamics. J. Solid State Chem. 291, 121636 (2020)
G. Ahmet, Y. Mehmet, S. Mustafa et al., The investigation of adsorption thermodynamics and mechanism of a cationic surfactant, CTAB, onto powdered active carbon. Fuel Process. Technol. 81(1), 57–66 (2003)
S. Fabiano Bisinella, M. Aparecido Nivaldo, B. Carlos Eduardo et al., Monolayer–multilayer adsorption phenomenological model: Kinetics, equilibrium and thermodynamics. Chem. Eng. J. 284, 1328–1341 (2015)
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The work was supported by the Nature Science Foundation of China (51664042).
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Project supported by the Nature Science Foundation of China (51664042).
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Author Contribution Statement: YH, First author: Designed the study, conducted the study, analyzed most of the data, and wrote the paper. The remaining authors contributed to refining the idea, performing additional analysis, and finalizing the paper.
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Huang, Y., Li, X., Qin, Y. et al. Preparation of Lanthanide Ion Surface Imprinted Polymers Based on Mesoporous Silica and Their Adsorption Properties. J Inorg Organomet Polym 33, 3638–3650 (2023). https://doi.org/10.1007/s10904-023-02769-8
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DOI: https://doi.org/10.1007/s10904-023-02769-8