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Synthesis, Surface Morphology, Gas Sensor, DSC Technique and Third-Order Behavior of Conducting Polymer

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Abstract

The compound polyaniline (Poly-ANI) with different concentrations of (H2SO4) sulfuric acid has been synthesized by the chemical polymerization method. The prepared compounds have been characterized using number of techniques including FTIR, FE-SEM, EDS and DSC. Additionally, UV–Vis spectroscopy employed for studying the linear optical properties of polymer with different acid concentrations. Third order optical nonlinearity was characterized using Z-scan at 532 nm. The results showed that the nonlinear refractive index has a negative sign. It was observed that the nonlinear refractive index changes in different ratios of H2SO4. The high value of nonlinear refractive index (\(n_{2}\)) obtained along Z-axis is \(74.62 \times 10^{ - 7}\) cm2/W, and the corresponding \(\chi^{3}\) is 21.5 × 10−5 esu. Also, the Poly-ANI film shows the response to NH3 gas sensing in the range 20 ppm-250 ppm and can be used for NH3 sensing application.

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Authors and Affiliations

  1. Department of Physics, College of Education for Pure Sciences, University of Basrah, Basrah, Iraq

    Fadhil A. Tuma & Hussain A. Badran

  2. Ministry of Education, Directorate of Education, Al-Basma Preparatory School for Girls, Basrah, Iraq

    Alyaa A. Jari

  3. Department of Material Science, Polymer Research Centre, University of Basrah, Basrah, Iraq

    Harith A. Hasan

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The present submissions represent original work. The current work is not considered for publication elsewhere in any other form. Also, all of the co-authors aware of this submission and they contributed to this work. Fadhil A. Tuma: Analyzed the results, wrote the original draft and Participated in the study of the Poly-ANI structure. Alyaa A. Jari: Interpreted the data, revised the manuscript and Data curation. Harith A. Hasan: Data analysis and revised manuscript. Hussain Ali Badran: designed the study and conducted most of the experiments.

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Tuma, F.A., Jari, A.A., Hasan, H.A. et al. Synthesis, Surface Morphology, Gas Sensor, DSC Technique and Third-Order Behavior of Conducting Polymer. J Fluoresc (2023). https://doi.org/10.1007/s10895-023-03448-0

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