Abstract
Sb2Se3 thin films which prepared using thermal evaporation were irradiated using LASER beam with different times of exposure (texpos). X-ray diffraction (XRD) results showed that the structure of these samples had changed from amorphous structure to polycrystalline structure with (texpos). The surface topography of these samples were studied using scanning electron microscopy (SEM). The measured optical parameters such as transmission (T) and reflection (R) were effected by these radiations. The determined optical energy gap (Eg) increases with (texpos). The values of oscillating energy (Eo) and dispersion energy (Ed) increased with (texpos). The dielectrical results such as dielectric loss (ε\) and dielectric tangent loss (ε\\) were affected and increase with (texpos). The determined values for both real part of optical conductivity (σ1) and imaginary part of optical conductivity (σ2) increase also with (texpos). The nonlinear optical parameters such as, nonlinear refractive index (n2) and third-order nonlinear optical susceptibility (χ(3)). The nonlinear results affected with (texpos). Finally, the density of states and Fermi level position for these samples were determined optically.
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J.J. Carey, J.P. Allen, D.O. Scanlon, G.W. Watson, The electronic structure of the antimony chalcogenide series: prospects for optoelectronic applications. J. Solid State Chem. 213, 116–125 (2014)
P. Kumar, T.S. Sathiaraj, R. Thangaraj, Optical properties of amorphous Sb2Se3: Sn films. Philos. Mag. Lett. 90(3), 183–192 (2011)
A. Bera, K. Pal, D.V.S. Muthu, S. Sen, P. Guptasarma, U.V. Waghmare, A.K. Sood, Sharp Raman anomalies and broken adiabaticity at a pressure induced transition from band to topological insulator in Sb2Se3. Phys. Rev. Lett. 110, 107401 (2013)
L. Dai, K. Liu, H. Li, L. Wu, H. Hu, Y. Zhuang, L. Yang, C. Pu, P. Liu, Pressure-induced irreversible metallization accompanying the phase transitions in Sb2S3. Phys. Rev. B 97, 024103 (2018)
M. Muralikrishna, A.S. Kiran, B. Ravikanth, P. Sowmendran, V. SaiMuthukumar, K. Venkataramaniah, Optical nonlinear absorption characteristics of Sb2Se3 nanoparticles. AIP Conf. Proc. 1591, 411–414 (2014)
Y. Lai, Z. Chen, C. Han, L. Jiang, F. Liu, J. Li, Y. Liu, Preparation and characterization of Sb2Se3 thin films by electrodeposition and annealing treatment. Appl. Surf. Sci. 261, 510–514 (2012)
T.M. Razykov, A.X. Shukurov, O.K. Atabayev, K.M. Kuchkarov, B. Ergashev, A.A. Mavlonov, Growth and characterization of Sb2Se3 thin films for solar cells. Sol. Energy 173, 225–228 (2018)
Y.R. Lazcano, Y. Pena, M.T.S. Nair, P.K. Nair, Polycrystalline thin films of antimony selenide via chemical bath deposition and post deposition treatments. Thin Solid Films 493, 77–82 (2005)
H. Sakai, K. Shimakawa, Y. Inagaki, T. Arizumi, Electrical properties of chalcogenide glasses of Te-Se-Ge and Te-Se-Sb systems. Jpn. J. Appl. Phys. 13, 500–504 (1974)
E. Černošková, R. Todorov, Z. Černošek, J. Holubová, L. Beneš, Thermal properties and the structure of amorphous SbSe thin film. J. Therm. Anal. Calorim. 118, 105–110 (2014)
C. Kaito, T. Fujita, T. Kimura, K. Hanamoto, N. Suzuki, S. Kimura, Y. Saito, Structure and crystallization of Sb Se films prepared by vacuum evaporation method. Thin Solid Films 312, 93–98 (1998)
K.Y. Rajpure, C.D. Lokhande, C.H. Bhosale, Effect of the substrate temperature on the properties of spray deposited Sb–Se thin films from non-aqueous medium. Thin Solid Films 311, 114–118 (1997)
P. Kumar, R. Thangaraj, Glassy state and structure of Sn–Sb–Se chalcogenide alloy. J. Non-Cryst. Solids 352, 2288–2291 (2006)
J.M. Yoon, E.T. Kim, J.Y. Lee, Y.T. Kim, Transmission electron microscopy study on the crystallization of Sb–Se–Te ternary alloys. Jpn. J. Appl. Phys. 48, 105501–105502 (2009)
I. Efthimiopoulos, J. Zhang, M. Kucway, C. Park, R.C. Ewing, Y. Wang, Sb2Se3 under pressure. Sci. Rep. 3, 2665–2672 (2013)
K.A. Chandrasekharani, A.G. Kunjomana, Growth and micro indentation analysis of pure and doped Sb2Se3 crystals. Turk. J. Phys. 33, 209–217 (2009)
R. Browning, N. Kuperman, B. Moon, R. Solanki, Atomic layer growth of InSe and Sb2Se3 layered semiconductors and their heterostructure. Electronics 6, 27–36 (2017)
Z. Li, H. Zhu, Y. Guo, X. Niu, X. Chen, C. Zhang, W. Zhang, X. Liang, D. Zhou, J. Chen, Efficiency enhancement of Sb2Se3 thin-film solar cells by the co-evaporation of Se and Sb2Se3. Appl. Phys. Express 9(5), 052302–052303 (2016)
K. Zeng, D.J. Xue, J. Tang, Antimony selenide thin-film solar cells. Semicond. Sci. Technol. 31, 063001–063002 (2016)
G.P. Voutsas, A.G. Papazoglou, P.J. Rentzeperis, D. Siapkas, The crystal structure of antimony selenide, Sb2Se3. Z. Kristallogr. Cryst. Mater. 171, 261–268 (1985)
N.W. Tideswell, F.H. Kruse, J.D. McCullough, The crystal structure of antimony selenide Sb2Se3. Acta Crystallogr. 10, 99–102 (1957)
H. Koc, A.M. Mamedov, E. Deligoz, H. Ozisik, First principles prediction of the elastic, electronic, and optical properties of Sb2S3 and Sb2Se3 compounds. Solid State Sci. 14, 1211–1220 (2012)
S.L. Benjamin, C.H. de Groot, A.L. Hector, R. Huang, E. Koukharenko, W. Levason, G. Reid, Chemical vapour deposition of antimony chalcogenides with positional and orientational control: precursor design and substrate selectivity. J. Mater. Chem. C Mater. Opt. Electron. Device 3(2), 423–430 (2015)
C. Chen, D.C. Bobela, Y. Yang, L. Shuaicheng, K. Zeng, G. Cong, B. Yang, L. Gao, Y. Zhao, M.C. Beard, J. Tang, Characterization of basic physical properties of Sb2Se3 and its relevance for photovoltaics. Front. Optoelectron. 10, 18–30 (2017)
N. Hu, M.A. Cheney, Y. Hanifehpour, S.W. Joo, B.K. Min, Synthesis, characterization, and catalytic performance of Sb2Se3nanorods. J. Nanomater. 2017, 1–8 (2017)
A. Abdel Moez, Study of structure, optical and dielectric properties of nano Sb2Te3 and Sb2Se3 thin films as a new optical recording material. Aust. J. Basic Appl. Sci. 5(8), 1305–1312 (2011)
B.K. Abhijit, A. Jayaraman, M. Molli, Electronic band structure and optical properties of antimony selenide under pressure. AIP Conf. Proc. 1731, 090020–090021 (2016)
M. Molli, P. Pradhan, D. Dutta, A. Jayaraman, A.B. Kademane, V.S. Muthukumar, V. Kamisetti, R. Philip, Study of nonlinear optical absorption properties of Sb2Se3 nanoparticles in the nanosecond and femtosecond excitation regime. Appl. Phys. A 122, 549–553 (2016)
C. Chen, W. Li, Y. Zhou, C. Chen, M. Luo, X. Liu, K. Zeng, B. Yang, C. Zhang, J. Han, J. Tang, Optical properties of amorphous and polycrystalline Sb2Se3 thin films prepared by thermal evaporation. Appl. Phys. Lett. 107, 043905 (2015)
P. Sharma, I. Sharma, S.C. Katyal, Physical and optical properties of binary amorphous selenium-antimony thin films. J. Appl. Phys. 105, 053509 (2009)
K. Yang, B. Li, G. Zeng, Structural, morphological, compositional, optical and electrical properties of Sb2Se3 thin films deposited by pulsed laser deposition. Superlattices Microstruct. 145, 106618 (2020)
M. Malligavathy, R.T.A. Kumar, C. Das, S. Asokan, D.P. Padiyan, Growth and characteristics of amorphous Sb2Se3 thin films of various thicknesses for memory switching applications. J. Non-Cryst. Solids 429, 93–97 (2015)
X. Zheng, Y. Xie, L. Zhu, X. Jiang, Y. Jia, W. Song, Y. Sun, Growth of Sb2E3 (E = S, Se) polygonal tubular crystals via a novel solvent-relief-self-seeding process. Inorg. Chem. 41, 455–461 (2002)
H. Maghraoui-Meherzi, T. Ben Nasr, M. Dachraoui, Synthesis, structure and optical properties of Sb2Se3. Mater. Sci. Semicond. Process. 16, 179–184 (2013)
E. Cernoskova, R. Todorov, Z. Cernosek, J. Holubova, L. Benes, Thermal properties and the structure of amorphous Sb2Se3 thin film. J. Therm. Anal. Calorim. 118, 105–110 (2014)
E. El-Sayad, Compositional dependence of the optical properties of amorphous Sb2Se3−xSx thin films. J. Non-Cryst. Solids 354, 3806–3811 (2008)
A.M. Farid, E. Abd El-Wahabb, M. Fadel, Electrical and optical properties of (Sb2Se3)2 (Sb2Te3)1 thin films. J. Mater. Sci. Mater. Electron. 13, 609 (2002)
S.S. Chiad, A.E. Ibrahim, N.F. Habubi, Annealing effect on the optical properties of Sb2S3 thin films. J. Univ. Anbar Pure Sci. 5, 18–22 (2011)
M.M. Abou Sekkina, Effects of temperature and frequency changes on the dielectric properties of modified chalcogenides. Thermochim. Acta 120, 231 (1987)
T. Ben Nasr, H. Maghraoui-Meherzi, H. Ben Abdallah, R. Bennaceur, Electronic structure and optical properties of Sb2S3 crystal. Physica B Phys. Condens. Matter 406, 287–292 (2011)
R. Hamrouni, N.E.H. Segmane, D. Abdelkader, A. Amara, Linear and non linear optical properties of Sb2Se3 thin films elaborated from nano-crystalline mechanically alloyed powder. Appl. Phys. A 124, 861 (2018)
C. Liu, Y. Yuan, L. Cheng, J. Su, X. Zhang, X. Li, H. Zhang, X. Zhang, J. Li, Tunable nonlinear optical absorption in amorphous and crystalline Sb2Se3 thin films. J. Alloys Compd. 791, 753–760 (2019)
C. Liu, L. Cheng, Y. Yuan, J. Su, X. Zhang, X. Li, H. Zhao, H. Zhang, Y. Zheng, J. Li, Contrastive investigation on linear optical properties and nonlinear absorption behaviors between Sb2Se3 and Sb2Te3 thin films. Mater. Res. Express 6, 086446 (2019)
A.M. Salem, M.S. Selim, A.M. Salem, Structure and optical properties of chemically deposited Sb2S3 thin films. J. Phys. D Appl. Phys. 34, 12 (2001)
L. Meng, H. Meng, W. Gog, W. Liu, Z. Zhang, Growth and characterization of Bi2Se3 thin films by pulsed laser deposition using alloy target. Thin Solid Films 519, 7627–7631 (2011)
Y. Badr, I.K. Battisha, A.M.S. El Nahrawy, B. Elouadi, M. Kamal, Physical study of thin film and monolithic nano-composites [SiO2: 11P2O5: 3Al2O3: (1.2) Er (1.2, 1.8 and 3) Yb] prepared by sol gel technique, planar waveguide. New J. Glass Ceram. 1, 71–78 (2011)
F. Gu, S.F. Wang, M.K. Lu, G.J. Zhou, D. Xu, D.R. Yuan, Photoluminescence properties of SnO2 nanoparticles synthesized by sol−gel method. J. Phys. Chem. B 108, 8119–8123 (2004)
Z.R. Khan, M. Zulfequar, M.S. Khan, Optical and structural properties of thermally evaporated cadmium sulphide thin films on silicon (1 0 0) wafers. Mater. Sci. Eng. B 174, 145–149 (2010)
M. Fadel, S.A. Fayek, M.O. Abou-Helal, M.M. Ibrahium, A.M. Shakra, Structural and optical properties of SeGe and SeGeX (X = In, Sb and Bi) amorphous films. J. Alloys Compd. 485, 604–609 (2009)
J. Aranda, J.L. Morenza, J. Esteve, J.M. Codina, Optical properties of vacuum-evaporated CdTe thin films. Thin Solid Films 120, 23–30 (1984)
F. Urbach, The long-wavelength edge of photographic sensitivity and of the electronic absorption of solids. Phys. Rev. 92, 1324 (1953)
Optical Process in Semiconductors, ed. by J.I. Pankove, Dover Publications, Inc., New York, (1971).
A.I. Ali, A.H. Ammar, A. Abdel Moez, Influence of substrate temperature on structural, optical properties and dielectric results of nano-ZnO thin films prepared by Radio Frequency technique. Superlattices Microstructur. 65, 285–298 (2014)
A.I. Ali, J.Y. Son, A.H. Ammar, A. Abdel Moez, Y.S. Kim, Optical and dielectric results of Y0.225Sr0.775CoO3±δ thin films studied by spectroscopic ellipsometry technique. Results Phys. 3, 167–172 (2013)
A.M. Farid, I.K. El-Zawawi, A.H. Ammara, Compositional effects on the optical properties of Gex Sb40−x Se60 thin films. Vacuum 86, 1255–1261 (2012)
S.H. Wemple, M. DiDomenico Jr., Optical dispersion and the structure of solids. Phys. Rev. Lett. 23, 1156–1160 (1969)
K. Anshu, A. Sharma, Study of Se based quaternary Se Pb (Bi, Te) chalcogenide thin films for their linear and nonlinear optical properties. Optik 127, 48–54 (2016)
A.B. Djurišić, E.H. Li, Modeling the optical properties of sapphire (α-Al2O3). Opt. Commun. 157, 72–76 (1998)
H.A. Elmeleegi, Z.E.S. El Mandouh, A.A. Moez, Influence of composition on the structure and optoelectronic properties of PbxIn25-xSe75 thin films. Turk. J. Phys. 38, 145–154 (2014)
H. Tichá, L. Tichy, Semiempirical relation between non-linear susceptibility (refractive index), linear refractive index and optical gap and its application to amorphous chalcogenides. J. Optoelectron. Adv. Mater. 4(2), 381–386 (2002)
P. Zhou, G. You, J. Li, S. Wang, S. Qian, L. Chen, Annealing effect of linear and nonlinear optical properties of Ag:Bi2O3 nanocomposite films. Opt. Express 13, 1508–1514 (2005)
A.A. Ziabari, F.E. Ghodsi, Optoelectronic studies of sol–gel derived nanostructured CdO–ZnO composite films. J. Alloys Compd. 509, 8748–8755 (2011)
B. Derkowskaa, B. Sahraouia, X.N. Phua, W. Bala, Nonlinear optical properties in ZnSe crystals. Proc. SPIE Int. Soc. Opt. Eng. 4412, 337–341 (2001)
S.M. Sze, Physics of Semiconductor Devices (Wiley-Inter science, New York, 1969).
M.H. Shang, J. Zhang, S. Wei, Y. Zhu, L. Wang, H. Hou, Y. Wu, T. Fujikawab, N. Uenob, Bi-doped Sb2S3 for low effective mass and optimized optical properties. J. Mater. Chem. C 4, 5081–5090 (2016)
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Moez, A.A., Ali, A.I. Influence of exposure time of LASER radiations on structural, optical, nonlinear optical and dielectric results of Sb2Se3 nanofilms. J Mater Sci: Mater Electron 32, 1303–1315 (2021). https://doi.org/10.1007/s10854-020-04903-5
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DOI: https://doi.org/10.1007/s10854-020-04903-5