Abstract
A correlation between structure and vibrational properties related to a ferroelectric to paraelectric phase transition in perovskite Pb(1−x)(Na0.5Sm0.5) x TiO3 (0 ≤ x ≤ 0.5) (PNST-x) polycrystalline powders is discussed. Substitution leads to reduction of tetragonality which is associated with a shift of the phase transition to lower temperatures. The nature of the phase transition gets diffused with increasing substitution.
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E.C. Paris, MFC Gurgel, M.R. Joya, G.P. Casali, C.O. Paiva-Santos, T.M. Boschi, P.S. Pizani, J.A. Varela, E. Longo, Structural deformation monitored by vibrational properties and orbital modeling in (Pb,Sm)TiO3 systems. J. Phys. Chem. Solids 71, 12–17 (2010)
J. Hlinka, M. Kempa, J. Kulda, P. Bourges, A. Kania, J. Petzelt, Lattice dynamics of ferroelectric PbTiO3 by inelastic neutron scattering. Phys. Rev. B 73, 140101 (2006)
I. Tomeno, J.A. Fernandez-Baca, K.J. Marty, K. Oka, Y. Tsunoda, Simultaneous softening of acoustic and optical modes in cubic PbTiO3. Phys. Rev. B 86, 134306 (2012)
H. Shigematsu, H. Nakadaira, T. Futatsugi, T. Matsui, Ti-isotope effect on ferroelectric phase transition of PbTiO3 studied by heat capacity measurement. Thermochim. Acta 352–353, 43–46 (2000)
N. Jaouen, A.C. Dhaussy, J.P. Itié, A. Rogalev, S. Marinel, Y. Joly, High-pressure dependent ferroelectric phase transition in lead titanate. Phys. Rev. B 75, 224115 (2007)
Q. Zhang, X. Zhu, Y. Xu, H. Gao, Y. Xiao, D. Liang, J. Zhu, J. Zhu, D. Xiao, Effect of La3+ substitution on the phase transitions, microstructure and electrical properties of Bi1–xLaxFeO3 ceramics. J. Alloys Compd. 546, 57–62 (2013)
G.S. Szabó, R.E. Cohen, H. Krakauer, First-principles study of piezoelectricity in PbTiO3. Phys. Rev. Lett. 80, 4321 (1998)
J. Chen, H. Shi, G. Liu, J. Cheng, S. Dong, Temperature dependence of dielectric, piezoelectric and elastic properties of BiScO3–PbTiO3 high temperature ceramics with morphotropic phase boundary (MPB) composition. J. Alloys Compd. 537, 280–285 (2012)
D.D. Shah, P.K. Mehta, M.S. Desai, C.J. Panchal, Origin of giant dielectric constant in Ba[(Fe1–xCox)1/2Nb1/2]O3. J. Alloys Compd. 509, 1800–1808 (2011)
J.S. Forrester, J.S. Zobec, D. Phelan, E.H. Kisi, Synthesis of PbTiO3 ceramics using mechanical alloying and solid state sintering. J. Solid State Chem. 177, 3553–3559 (2004)
M. Alguero, P. Ramos, R. Jimenez, H. Amorin, E. Vila, A. Castro, High temperature piezoelectric BiScO3–PbTiO3 synthesized by mechanochemical methods. Acta Mater. 60, 1174–1183 (2012)
Z. Wu, R.E. Cohen, Pressure-induced anomalous phase transitions and colossal enhancement of piezoelectricity in PbTiO3. Phys. Rev. Lett. 95, 037601 (2005)
A.A. Bokov, Recent advances in diffuse ferroelectric phase transitions. Ferroelectrics 131, 49–55 (1992)
A.A. Bokov, L.A. Shpak, I.P. Rayevsky, Diffuse phase transition in Pb(Fe0.5Nb0.5)O3-based solid solutions. J. Phys. Chem. Solids 54, 495–498 (1993)
N. Abdelmoula, H. Chaabane, H. Khemakhem, R. Vonder Mühll, A. Simon, x(Sm0.5Na0.5)xTiO3. Solid State Sci 8, 880–887 (2006)
D.I. Woodward, I.M. Reaney, Electron diffraction of tilted perovskites. Acta Crystallogr. Sect. B 61, 387–399 (2005)
W. Zhao, R. Zuo, F. Li, L. Li, Structural, dielectric, ferroelectric and strain properties in CaZrO3-modified Bi(Mg0.5Ti0.5)O3–PbTiO3 solid solutions. J. Alloys Compd. 591, 218–223 (2014)
X. Chou, J. Zhai, H. Jiang, X. Yao, Dielectric properties and relaxor behavior of rare-earth (La, Sm, Eu, Dy, Y) substituted barium zirconium titanate ceramics. J. Appl. Phys. 102, 084106 (2007)
W. Zhong, R.D. King-Smith, D. Vanderbilt, Giant LO-TO Splitting in Perovskite ferroelectrics. Phys. Rev. Lett. 72, 3618–3621 (1994)
B.K. Mani, C.M. Chang, I. Ponomareva, Atomistic study of soft-mode dynamics in PbTiO3. Phys. Rev. B 88, 064306 (2013)
G. Burns, B.A. Scott, Lattice modes in ferroelectric perovskites: PbTiO3. Phys. Rev. B 7, 3088 (1973)
C.M. Foster, Z. Li, M. Grimsditch, S.K. Chan, D.J. Lam, Anharmonicity of the lowest-frequency A1(TO) phonon in PbTiO3. Phys. Rev. B 48, 10160 (1993)
J.A. Sanjurjo, E.L. Cruz, G. Burns, High-pressure Raman study of zone-center phonons in PbTiO3. Phys. Rev. B 28, 7260 (1983)
C. Sun, J. Wang, P. Hu, M.J. Kim, X. Xing, Effects of Al substitution on the spontaneous polarization and lattice dynamics of the PbTi1–xAlxO3. Dalton Trans. 39, 5183 (2010)
E.C. Paris, MFC Gurgel, T.M. Boschi, M.R. Joya, P.S. Pizani, A.G. Souza, E.R. Leite, J.A. Varela, E. Longo, Investigation on the structural properties in Er-doped PbTiO3 compounds: a correlation between experimental and theoretical results. J. Alloys Compd. 462, 157–163 (2008)
L. Sun, Y.F. Chen, L. He, C.Z. Ge, D.S. Ding, T. Yu, M.S. Zhang, N.B. Ming, Phonon-mode hardening in epitaxial PbTiO3 ferroelectric thin films. Phys. Rev. B 55, 12218 (1997)
S.M. Cho, H.M. jang, Softening and mode crossing of the lowest-frequency A1(transverse-optical) phonon in single-crystal PbTiO3. Appl. Phys. Lett. 76, 3014–3016 (2000)
D. Wu, A. Li, N. Ming, Dielectric characterization of Bi3.25La0.75Ti3O12 thin films. Appl. Phys. Lett. 84, 4505–4507 (2004)
H. Gu, Y. Hu, J. You, Z. Hu, Y. Yuan, T. Zhang, Characterization of single-crystalline PbTiO3 nanowire growth via surfactant-free hydrothermal method. J. Appl. Phys. 101, 024319 (2007)
S. Bhaskar, S.B. Majumder, R.S. Katiyara, Diffuse phase transition and relaxor behavior in (PbLa)TiO3 thin films. Appl. Phys. Lett. 80, 3997 (2002)
A. Singh, R. Chatterjee, Multiferroic properties of La-Rich BiFeO3-PbTiO3 solid solutions. Ferroelectrics 433, 180 (2012)
X.P. Jiang, J.W. Fang, H.R. Zeng, B.J. Chu, G.R. Li, D.R. Chen, Q.R. Yin, The influence of PbZrO3/PbTiO3 ratio on diffuse phase transition of Pb(Zn1/3Nb2/3)O3–PbZrO3–PbTiO3 system near the morphotropic phase boundary. Mater. Lett. 44, 219–222 (2000)
T. Nakamura, M. Takashige, Diffuse phase transition and low temperature dielectric constant in PbTiO3. Ferroelectrics 108, 159–164 (1990)
J. Chen, Y. Qi, G. Shi, X. Yan, S. Yu, J. Cheng, Diffused phase transition and multiferroic properties of 0.57(Bi1–xLax)FeO3–0.43PbTiO3 crystalline solutions. J. Appl. Phys. 104, 064124 (2008)
W. Ji, X. He, W. Cheng, P. Qiu, X. Zeng, B. Xia, D. Wang, Effect of La content on dielectric, ferroelectric and electro-optic properties of Pb(Mg1/3Nb2/3)O3–PbTiO3 transparent ceramics. Ceram. Int 41, 1950–1956 (2015)
I.A. Santos, J.A. Eiras, Phenomenological description of the diffuse phase transition in ferroelectrics. J. Phys. 13, 11733 (2001)
J.F. Scott, Ferroelectrics go bananas. J. Phys. 20, 021001 (2008)
A.J. Priyanka, K.J. Pardeep, A.K. Jha, R.K. Kotnala, R.K. Drivedi, Phase transformation and two-mode phonon behavior of (1 – x)[BaZr0.025Ti0.975O3]–(x) [BiFeO3] solid solutions. J. Alloys Compd. 600, 186–192 (2014)
A.K. Yadav, P. Rajput, O. Alshammari, M. Khan, Anita, G. Kumar, S. Kumar, P.M. Shirage, S. Biring, S. Sen, Structural distortion, ferroelectricity and ferromagnetism in Pb(Ti1–xFex)O3. J. Alloys Compd. 701, 619–625 (2017)
F.A. Kröger, H.J. Vink, in Solid State Physics, ed. by S. Frederick, T. David. Relations Between the Concentrations of Imperfections in Crystalline Solids, vol 3 (Academic Press, New York, 1956), pp. 307–435
N. Yuji, M. Ichiro, G. Yu, M. Masaru, Defect control for large remanent polarization in bismuth titanate ferroelectrics—doping effect of higher-valent cations. Jpn. J. Appl. Phys. 39, L1259–L1262 (2000)
K. Sunil, K.B.R. Verma, Influence of lanthanum doping on the dielectric, ferroelectric and relaxor behaviour of barium bismuth titanate ceramics. J. Phys. D 42, 075405 (2009)
Acknowledgements
One of the authors Arun Kumar Yadav is grateful to the university Grants Commission to award me fellowship (NFO-2015-17-OBC-UTT-28455).Principle investigator expresses sincere thanks to Indian Institute of Technology, Indore for funding the research and also using the Sophisticated Instrument Centre (SIC) for the research. The authors thank to Mr. Rituraj Sharma for providing the HR Raman facility in IISER Bhopal.
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Yadav, A.K., Anita, Kumar, S. et al. Structural and dielectric properties of Pb(1−x)(Na0.5Sm0.5) x TiO3 ceramics. J Mater Sci: Mater Electron 28, 10730–10738 (2017). https://doi.org/10.1007/s10854-017-6849-y
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DOI: https://doi.org/10.1007/s10854-017-6849-y