Abstract
Cellulose nanofibrils (CNFs) have already been proved to be a potential candidate as one of the next-generation renewable and sustainable packaging materials. However, the mechanical and barrier properties of CNF films are not yet up to the mark for certain applications, especially at higher relative humidity. Those properties can be controlled by the degree of fibrillation of fibers and drying methods of films. Here we prepared CNF films from CNF suspensions with two different degrees of fibrillation- standard CNF (90% fine) and high-fine CNF (97% fine) by casting and filtration. These were dried in four different ways (air, oven, heat gun, and hot press drying) to better understand how these methods affect the physical, mechanical as well as oil, water vapor and oxygen barrier properties of the films. The CNF films made by hot press drying showed the highest tensile strength (98.82 MPa) and lowest water vapor permeability (13.91 g.mm/m2 day kPa). Hot press compaction on the dried films further improved the tensile strength by 13.1% and reduced the water vapor and oxygen permeability by 22.3% and 43%, respectively. The average value of oxygen permeability after hot press compaction was found to be 403.2 cc µm/m2 day atm, which can be considered as high oxygen barrier at 80% relative humidity. All prepared films showed maximum oil resistance value with kit number ‘12’, regardless of their preparation techniques. The result of folding a representative CNF film showed that the CNF film retained its oxygen barrier properties after a single line folding, but failed after two crossline folding.
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Abbreviations
- CNF:
-
Cellulose nanofibril
- CNC:
-
Cellulose nanocrystal
- PVC:
-
Polyvinyl chloride
- AFM:
-
Atomic force microscopy
- SU:
-
Sheffield Unit
- XRD:
-
X-ray diffraction
- CI:
-
Crystallinity Index
- SEM:
-
Scanning electron microscopy
- WVTR:
-
Water vapor transmission rate
- WVP:
-
Water vapor permeability
- OTR:
-
Oxygen transmission rate
- ANOVA:
-
Analysis of variance
References
Abral H, Ariksa J, Mahardika M et al (2020) Effect of heat treatment on thermal resistance, transparency and antimicrobial activity of sonicated ginger cellulose film. Carbohydr Polym 240:116287. https://doi.org/10.1016/j.carbpol.2020.116287
Amini E, Hafez I, Tajvidi M, Bousfield DW (2020) Cellulose and lignocellulose nanofibril suspensions and films: a comparison. Carbohydr Polym 250:117011. https://doi.org/10.1016/j.carbpol.2020.117011
Aulin C, Gällstedt M, Lindström T (2010) Oxygen and oil barrier properties of microfibrillated cellulose films and coatings. Cellulose 17:559–574. https://doi.org/10.1007/s10570-009-9393-y
Bilodeau M, Paradis M (2018) High efficiency production of nanofibrillated cellulose, US Patent No. 9,988,762 B2
Chowdhury RA, Clarkson C, Montes F et al (2019a) Cellulose nanocrystal ( CNC ) coatings with controlled anisotropy as high-performance gas barrier films. ACS Appl Mater Interfaces 11:1376–1383. https://doi.org/10.1021/acsami.8b16897
Chowdhury RA, Nuruddin M, Clarkson C et al (2019b) Cellulose nanocrystal (CNC) coatings with controlled anisotropy as high-performance gas barrier films. ACS Appl Mater Interfaces 11:1376–1383. https://doi.org/10.1021/acsami.8b16897
Du H, Liu W, Zhang M et al (2019) Cellulose nanocrystals and cellulose nanofibrils based hydrogels for biomedical applications. Carbohydr Polym 209:130–144. https://doi.org/10.1016/j.carbpol.2019.01.020
El Awad Azrak SM, Clarkson CM, Moon RJ et al (2019) Wet-stacking lamination of multilayer mechanically fibrillated cellulose nanofibril (CNF) sheets with increased mechanical performance for use in high-strength and lightweight structural and packaging applications. ACS Appl Polym Mater 1:2525–2534. https://doi.org/10.1021/acsapm.9b00635
Fein K, Bous DW, Gramlich WM (2021a) Processing effects on structure, strength, and barrier properties of refiner-produced cellulose nanofibril layers. ACS Appl Polym Mater 3:3666–3678. https://doi.org/10.1021/acsapm.1c00620
Fein K, Bousfield DW, Gramlich WM (2021b) Processing effects on structure, strength, and barrier properties of refiner-produced cellulose nanofibril layers. ACS Appl Polym Mater 3:3666–3678. https://doi.org/10.1021/acsapm.1c00620
Findenig G, Leimgruber S, Kargl R et al (2012) Creating water vapor barrier coatings from hydrophilic components. ACS Appl Mater Interfaces 4:3199–3206. https://doi.org/10.1021/am300542h
French AD (2014) Idealized powder diffraction patterns for cellulose polymorphs. Cellulose 21:885–896. https://doi.org/10.1007/s10570-013-0030-4
Fu T, Moon RJ, Zavattieri P et al (2017) Cellulose nanomaterials as additives for cementitious materials. Woodhead publishing series in composites science and engineering. Woodhead Publishing, Cambridge, pp 455–482
Ghasemi S, Tajvidi M, Bousfield DW et al (2017) Dry-spun neat cellulose nanofibril filaments: influence of drying temperature and nanofibril structure on filament properties. Polymers (basel) 9:392. https://doi.org/10.3390/polym9090392
Ghasemi S, Rahimzadeh-Bajgiran P, Tajvidi M, Shaler SM (2020) Birefringence-based orientation mapping of cellulose nanofibrils in thin films. Cellulose 27:677–692. https://doi.org/10.1007/s10570-019-02821-2
Groh KJ, Backhaus T, Carney-Almroth B et al (2019) Overview of known plastic packaging-associated chemicals and their hazards. Sci Total Environ 651:3253–3268. https://doi.org/10.1016/j.scitotenv.2018.10.015
Guan QF, Bin YH, Han ZM et al (2020) Lightweight, tough, and sustainable cellulose nanofiber-derived bulk structural materials with low thermal expansion coefficient. Sci Adv 6:1–9. https://doi.org/10.1126/sciadv.aaz1114
Hafez I, Amini E, Tajvidi M (2020) The synergy between cellulose nanofibrils and calcium carbonate in a hybrid composite system. Cellulose 27:3773–3787. https://doi.org/10.1007/s10570-020-03032-w
Hossain R, Tajvidi M, Bousfield D, Gardner DJ (2021) Multi-layer oil-resistant food serving containers made using cellulose nanofiber coated wood flour composites. Carbohydr Polym. https://doi.org/10.1016/j.carbpol.2021.118221
Hossen MR, Dadoo N, Holomakoff DG et al (2018) Wet stable and mechanically robust cellulose nano fi brils (CNF) based hydrogel. Polymer (guildf) 151:231–241. https://doi.org/10.1016/j.polymer.2018.07.016
Hossen MR, Talbot MW, Gramlich WM, Mason MD (2020a) Robust nanofibrillated cellulose composite SERS substrate for capillary preconcentration and trace level detection of organic molecules. Cellulose 27:10119–10137. https://doi.org/10.1007/s10570-020-03478-y
Hossen MR, Talbot MW, Kennard R et al (2020b) A comparative study of methods for porosity determination of cellulose based porous materials. Cellulose 27:6849–6860. https://doi.org/10.1007/s10570-020-03257-9
Hsieh MC, Koga H, Suganuma K, Nogi M (2017) Hazy transparent cellulose nanopaper. Sci Rep 7:1–7. https://doi.org/10.1038/srep41590
Kelly PV, Gardner DJ, Gramlich WM (2021) Optimizing lignocellulosic nanofibril dimensions and morphology by mechanical refining for enhanced adhesion. Carbohydr Polym 273:118566
Kumar V, Kothari SH (1999) Effect of compressional force on the crystallinity of directly compressible cellulose excipients. Int J Pharm 177:173–182. https://doi.org/10.1016/S0378-5173(98)00340-8
Lin YJ, Dias P, Chum S et al (2007) Surface roughness and light transmission of biaxially oriented polypropylene films. Polym Eng Sci 47:1658–1665. https://doi.org/10.1002/pen.20850
Mashkour M, Kimura T, Kimura F et al (2014) Tunable self-assembly of cellulose nanowhiskers and polyvinyl alcohol chains induced by surface tension torque. Biomacromol 15:60–65. https://doi.org/10.1021/bm401287s
Moon RJ, Schueneman GT, Simonsen J (2016) Overview of cellulose nanomaterials, their capabilities and applications. Jom 68:2383–2394. https://doi.org/10.1007/s11837-016-2018-7
Nadeem H, Naseri M, Shanmugam K et al (2020) An energy efficient production of high moisture barrier nanocellulose/carboxymethyl cellulose films via spray-deposition technique. Carbohydr Polym 250:116911. https://doi.org/10.1016/j.carbpol.2020.116911
Nair SS, Zhu JY, Deng Y, Ragauskas AJ (2014) High performance green barriers based on nanocellulose. Sustain Chem Process 2:1–7. https://doi.org/10.1186/s40508-014-0023-0
Nogi M, Iwamoto S, Nakagaito AN, Yano H (2009) Optically transparent nanofiber paper. Adv Mater 21:1595–1598. https://doi.org/10.1002/adma.200803174
Nuruddin M, Chowdhury RA, Szeto R et al (2021) Structure − property relationship of cellulose nanocrystal − polyvinyl alcohol thin films for high barrier coating applications. ACS Appl Mater Interfaces 13:12472–12482. https://doi.org/10.1021/acsami.0c21525
Österberg M, Vartiainen J, Lucenius J et al (2013) A fast method to produce strong NFC films as a platform for barrier and functional materials. ACS Appl Mater Interfaces 5:4640–4647. https://doi.org/10.1021/am401046x
Owens DK, Wendt RC (1969) Estimation of the surface free energy of polymers. J Appl Polym Sci 13:1741–1747. https://doi.org/10.1002/app.1969.070130815
Qing Y, Sabo R, Wu Y et al (2015) Self-assembled optically transparent cellulose nanofibril films: effect of nanofibril morphology and drying procedure. Cellulose 22:1091–1102. https://doi.org/10.1007/s10570-015-0563-9
Sacui IA, Nieuwendaal RC, Burnett DJ et al (2014) Comparison of the properties of cellulose nanocrystals and cellulose nanofibrils isolated from bacteria, tunicate, and wood processed using acid, enzymatic, mechanical, and oxidative methods. ACS Appl Mater Interfaces 6:6127–6138. https://doi.org/10.1021/am500359f
Satam CC, Irvin CW, Lang AW et al (2018) Spray-coated multilayer cellulose nanocrystal - chitin nanofiber films for barrier applications. ACS Sustain Chem Eng 6:10637–10644. https://doi.org/10.1021/acssuschemeng.8b01536
Segal L, Creely JJ, Martin AE, Conrad CM (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer. Text Res J 29:786–794. https://doi.org/10.1177/004051755902901003
Sehaqui H, Ezekiel Mushi N, Morimune S et al (2012) Cellulose nanofiber orientation in nanopaper and nanocomposites by cold drawing. ACS Appl Mater Interfaces 4:1043–1049. https://doi.org/10.1021/am2016766
Shimizu M, Saito T, Fukuzumi H, Isogai A (2014) Hydrophobic, ductile, and transparent nanocellulose films with quaternary alkylammonium carboxylates on nanofibril surfaces. Biomacromol 15:4320–4325. https://doi.org/10.1021/bm501329v
Tayeb AH, Tajvidi M (2019) Sustainable barrier system via self-assembly of colloidal montmorillonite and cross-linking resins on nanocellulose interfaces. ACS Appl Mater Interfaces 11:1604–1615. https://doi.org/10.1021/acsami.8b16659
Tayeb AH, Tajvidi M (2020) Enhancing the oxygen barrier properties of nanocellulose at high humidity: numerical and experimental assessment. Sustain Chem 1:198–208. https://doi.org/10.3390/suschem1030014
Tayeb P, Tayeb HA (2019) Nanocellulose applications in sustainable electrochemical and piezoelectric systems: a review. Carbohydr Polym 224:115149. https://doi.org/10.1016/j.carbpol.2019.115149
Tayeb AH, Amini E, Ghasemi S, Tajvidi M (2018) Cellulose nanomaterials-binding properties and applications: a review. Molecules 23:1–24. https://doi.org/10.3390/molecules23102684
Tayeb AH, Tajvidi M, Bousfield D (2020) Paper-based oil barrier packaging using lignin-containing cellulose nanofibrils. Molecules. https://doi.org/10.3390/molecules25061344
Technical Association of the Pulp and Paper Industry (1996a) Test method T 538 om-96: Roughness of paper and paperboard (Sheffield method)
Technical Association of the Pulp and Paper Industry (1996b) Test Method T 559 cm-12, Grease resistance test for paper and paperboard
Tyagi P, Lucia LA, Hubbe MA, Pal L (2019) Nanocellulose-based multilayer barrier coatings for gas, oil, and grease resistance. Carbohydr Polym 206:281–288. https://doi.org/10.1016/j.carbpol.2018.10.114
Uddin AJ, Araki J, Gotoh Y (2011) Toward “Strong” Green nanocomposites: polyvinyl alcohol reinforced with extremely oriented cellulose whiskers. Biomacromol 12:617–624. https://doi.org/10.1021/bm101280f
Wakabayashi M, Fujisawa S, Saito T, Isogai A (2020) Nanocellulose film properties tunable by controlling degree of fibrillation of TEMPO-oxidized cellulose. Front Chem 8:1–9. https://doi.org/10.3389/fchem.2020.00037
Wang J, Gardner DJ, Stark NM et al (2018) Moisture and oxygen barrier properties of cellulose nanomaterial-based films. ACS Sustain Chem Eng 6:49–70. https://doi.org/10.1021/acssuschemeng.7b03523
Wang L, Chen C, Wang J et al (2020) Cellulose nanofibrils versus cellulose nanocrystals: Comparison of performance in flexible multilayer films for packaging applications. Food Packag Shelf Life 23:100464. https://doi.org/10.1016/j.fpsl.2020.100464
Wenzel R (2015) Resistance of solid surfaces to wetting by water. Ind Eng Chem 28:988–994. https://doi.org/10.1021/ie50320a024
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This work was partially supported through the agreement 19-JV-11111124–062 between the U.S. Forest Service and the University of Maine and by USDA Agricultural Research Service (ARS).
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Hasan, I., Wang, J. & Tajvidi, M. Tuning physical, mechanical and barrier properties of cellulose nanofibril films through film drying techniques coupled with thermal compression. Cellulose 28, 11345–11366 (2021). https://doi.org/10.1007/s10570-021-04269-9
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DOI: https://doi.org/10.1007/s10570-021-04269-9