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Stereoselective total synthesis of decarestrictine J

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Abstract

Stereoselective total synthesis of decarestrictine J has been accomplished from inexpensive and commercially available starting materials. This concise synthesis utilizes Jacobsen’s hydrolytic kinetic resolution, regioselective ring opening of epoxide, and Yamaguchi macrolactonisation as key steps.

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Authors and Affiliations

  1. Division of Chemistry, Department of Sciences and Humanities, Vignan’s Foundation for Science, Technology and Research University (VFSTRU; Vignan’s University), Vadlamudi, Guntur, 522 213, Andhra Pradesh, India

    V. B. Ramanujan & Chebolu Naga Sesha Sai Pavan Kumar

  2. Department of Chemistry, University College of Engineering (Autonomous), Jawaharlal Nehru Technological University, Kakinada, 533 003, Andhra Pradesh, India

    Reddymasu Sreenivasulu

  3. Centre of Excellence in Advanced Materials, Manufacturing, Processing and Characterization (CoExAMMPC), Vignan’s Foundation for Science, Technology and Research University (VFSTRU; Vignan’s University), Vadlamudi, Guntur, 522 213, Andhra Pradesh, India

    Murthy Chavali

Authors
  1. V. B. Ramanujan
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  2. Reddymasu Sreenivasulu
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  3. Murthy Chavali
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  4. Chebolu Naga Sesha Sai Pavan Kumar
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Corresponding authors

Correspondence to Reddymasu Sreenivasulu or Chebolu Naga Sesha Sai Pavan Kumar.

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Ramanujan, V.B., Sreenivasulu, R., Chavali, M. et al. Stereoselective total synthesis of decarestrictine J. Monatsh Chem 148, 1865–1869 (2017). https://doi.org/10.1007/s00706-017-1947-3

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  • DOI: https://doi.org/10.1007/s00706-017-1947-3

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