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Utilization of Green Chemical Techniques in Enzymolysis of Cellulose

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Sustainable Production of Bulk Chemicals

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Abstract

The effective utilization of cellulose is topic concept. Among various methods, the interest in enzymolysis of cellulose is doubtless. Cellulase provides the highest selectivity for the hydrolysis of the β-glycosidic bonds of the cellulose backbone, with respect to any other chemical catalyst (i.e., acids, alkali, etc.). However, enzymolysis of cellulose suffers from slow reaction rates due in large part to the highly crystalline structure of cellulose and inaccessibility of enzyme adsorption sites. Ionic liquids (ILs) are recently being used as solvents or pretreatment for cellulose to improve the enzymolysis rates, which may well prove to be a potential route for utilizing cellulose as feedstock in biofuel and chemical production. Other methods such as chemical modification can further enhance the performance of cellulase in these ILs systems. This chapter reviews the recent research on cellulose-dissolving ILs, different chemical methods which are utilized to enhance the performance of cellulase in the IL systems and the design of compatible cellulase-IL systems.

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Authors and Affiliations

  1. College of Chemical Engineering, Qingdao University of Science and Technology, 266042, Qingdao, China

    Lu Li, Shitao Yu, Shiwei Liu & Fusheng Liu

  2. Key Laboratory of Eco-Chemical Engineering, Ministry of Education, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, 266042, Qingdao, China

    Congxia Xie

Authors
  1. Lu Li
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  2. Shitao Yu
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  3. Shiwei Liu
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  4. Fusheng Liu
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  5. Congxia Xie
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Corresponding authors

Correspondence to Lu Li or Shitao Yu .

Editor information

Editors and Affiliations

  1. Qingdao Institute of Bioenergy and , Qingdao, China

    Mo Xian

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Li, L., Yu, S., Liu, S., Liu, F., Xie, C. (2016). Utilization of Green Chemical Techniques in Enzymolysis of Cellulose. In: Xian, M. (eds) Sustainable Production of Bulk Chemicals. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-7475-8_6

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