Abstract
Electronic structure of free and neutral Rb and K clusters containing from few tens to few hundred atoms has been studied using synchrotron radiation. Core-level photoelectron spectroscopy has been used to probe the metallic nature of Rb and K clusters. We show that the metallicity exists down to the dimensions of few nanometers. Simultaneously the emergence and evolution of the valence band structure has been monitored by the valence-level photoelectron spectroscopy.
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Mikkelä, M.H., Tchaplyguine, M., Jänkälä, K. et al. Size-dependent study of Rb and K clusters using core and valence level photoelectron spectroscopy. Eur. Phys. J. D 64, 347–352 (2011). https://doi.org/10.1140/epjd/e2011-20239-4
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DOI: https://doi.org/10.1140/epjd/e2011-20239-4