Abstract
Applications of hemp fibers, as a promising natural material in the textile field, mostly require improved fiber properties. In this paper, the oxidation of hemp fibers with potassium permanganate was applied to reduce the amount of non-cellulosic substances and moisture sorption; to introduce functional groups and increase capillarity; make fibers finer, softer and suitable for application in sport wears. The changes in sorption properties were characterized by capillary rise measurement and the ability of water retention and moisture sorption, while changes in mechanical properties were estimated by determination of tenacity and elongation of modified hemp fibers in comparison to the appropriate characteristic of unmodified fibers. ATR-FTIR, SEM techniques, and zeta potential measurement were used for the characterization of fiber structure, morphological and electrokinetic properties. We obtained a finer fiber with increased capillarity (up to 3.68 times) but reduced moisture sorption (down to 1.5 times) and water retention capacity (down to 2.8 times), with accomplished satisfactory preservation of mechanical properties. Obtained oxidized hemp fibers with attained features present a very suitable material for sportswear production. Additionally, in this paper, an improvement of the capillary rise measurement is given.
Similar content being viewed by others
References
J. Kozlowska, R. Kozlowski, and S. Manys, Current Situation and Future Perspective of Flax and Hemp at the Turn of the 20th and 21th Centuries (Book of Abstract of the Scientific-practical Conference “Flax — on the Threshold of the XXI Century”), 2000.
J. Cruz and R. Fangueiro, Procedia Eng., 155, 285 (2016).
B. M. Prasad, M. M. Sain, and D. N. Roy, Macromol. Mater. Eng., 289, 581 (2004).
I. H. Mondal, “Textiles: History, Properties and Performance and Applications”, Nova Science Publishers, Inc., Hauppauge, New York, 2014.
M. Kostic, B. Pejic, and P. Skundric, Bioresour. Technol., 99, 94 (2008).
B. M. Pejic, M. M. Kostic, P. D. Skundric, and J. Z. Praskalo, Bioresour. Technol., 99, 7152 (2008).
S. Kalia, B. S. Kaith, and I. Kaur, Polym. Eng. Sci., 49, 1253 (2009).
D. Filingeri, B. Redortier, S. Hodder, and G. Havenith, Ski. Res. Technol., 21, 9 (2015).
M. Raccuglia, S. Hodder, and G. Havenith, Text. Res. J., 87, 2449 (2017).
K. Parsons, “Human Thermal Environments: The Effects of Hot, Moderate, Andcold Environments on Human Health,Comfort, and Performance”, 3rd ed., CRC Press, Taylor & Francis Group, Boca Raton, London, New York, 2014.
D. Grujic and J. Geršak, Text. Res. J., 87, 1522 (2017).
E. A. DenHartog and C. L. Koerhuis, J. Text. Inst., 108, 664 (2017).
H. M. Wang, R. Postle, R. W. Kessler, and W. Kessler, Text. Res. J., 73, 664 (2003).
Z. Jinqiu and Z. Jianchun, Text. Res. J., 80, 744 (2010).
L. Liu, Y. Xiang, R. Zhang, B. Li, and J. Yu, Text. Res. J., 89, 76 (2019).
J. Milanovic, M. Kostic, P. Milanovic, and P. Skundric, Ind. Eng. Chem. Res., 51, 9750 (2012).
X. Yeping, Y. Jianyong, L. Liu, Z. Ruiyun, Q. Yongshuai, and J. Miaolei, Text. Res. J., 89, 2433 (2019).
P. J. Wakelyn, “Cotton Fiber Chemistry and Technology”, 1st ed., CRC Press Taylor & Francis Group, Boca Raton, London, New York, 2006.
M. Lewin, Macromol. Symp., 118, 715 (1997).
M. S. Sreekala, M. G. Kumaran, and S. Thomas, Compos. Part A-Appl. Sci. Manuf., 33, 763 (2002).
A. Paul, K. Joseph, and S. Thomas, Compos. Sci. Technol., 57, 67 (1997).
S. Mishra, J. B. Naik, and Y. P. Patil, Compos. Sci. Technol., 60, 1729 (2000).
M. S. Sreekala, M. G. Kumaran, S. Joseph, M. Jacob, and S. Thomas, Appl. Compos. Mater., 7, 295 (2000).
M. M. Kostic, J. Z. Milanovic, M. V. Baljak, K. Mihajlovski, and A. D. Kramar, Fiber. Polym., 15, 57 (2014).
A. I. Koblyakov, “Laboratory Practice in the Study of Textile Materials”, Mir Publ. Moscow, 1989.
Micro Kappa Number, Tappi UM 246, 1991.
V. Kumar and T. Yang, Carbohydr. Polym., 48, 403 (2002).
E. C. Yackel and W. O. Kenyon, J. Am. Chem. Soc., 64, 121 (1942).
E. Parks and R. Hebert, Tappi J., 55, 1510 (1972).
J. Praskalo, M. Kostic, A. Potthast, G. Popov, B. Pejic, and P. Skundric, Carbohydr. Polym., 77, 791 (2009).
T. Luxbacher, “The Zeta Potential for Solid Surface Analysis”, pp.42–72, 1st ed., Anton Paar GmbH: Graz, Austria, 2014.
ASTM D 2402-07, “Standard Test Method for Water Retention of Fibers (Centrifuge Method)”, 2012.
ASTM D 1776-74, “Conditioning Textiles and Textile Products for Testing”, 1974.
S. Alix, E. Philippe, A. Bessadok, L. Lebrun, C. Morvan, and S. Marais, Bioresour. Technol., 100, 4742 (2009).
I. Bykov, Master thesis, Luleå Univ. Technol, Luleå, 2008.
M.-C. Popescu, C.-M. Popescu, G. Lisa, and Y. Sakata, J. Mol. Struct., 988, 65 (2011).
T. Kondo, Cellulose, 4, 281 (1997).
Y. Ge, Z. Li, D. Xiao, P. Xiong, and N. Ye, J. Ind. Eng. Chem., 20, 1765 (2014).
M. Poletto, H. Ornaghi, and A. Zattera, Materials, 7, 6105 (2014).
H. Zhang, R. Ming, G. Yang, Y. Li, Q. Li, and H. Shao, Polym. Eng. Sci., 55, 2553 (2015).
A. M. Shaker, J. Colloid Interface Sci., 233, 197 (2001).
B. D. Lazić, B. M. Pejić, A. D. Kramar, M. M. Vukčević, K. R. Mihajlovski, J. D. Rusmirović, and M. M. Kostić, Cellulose, 25, 697 (2018).
F. Tanasă, M. Zănoagă, C. A. Teacă, M. Nechifor, and A. Shahzad, Polym. Compos., 41, 5 (2020).
V. Hospodarova, E. Singovszka, and N. Stevulova, Am. J. Anal. Chem., 9, 303 (2018).
E. Terpáková, L. Kidalová, A. Eštoková, J. Čigášová, and N. Števulová, Procedia Eng., 931 (2012).
F. Xu, J. Yu, T. Tesso, F. Dowell, and D. Wang, Appl. Energy, 104, 801 (2013).
D. Fakin, V. Golob, K. S. Kleinschek, and A. M. le Marechal, Text. Res. J., 76, 448 (2006).
S. Köstler, V. Ribitsch, K. Stana-Kleinschek, G. Jakopic, and S. Strnad, Colloids Surfaces A-Physicochem. Eng. Asp., 270-271, 107 (2005).
K. Stana-Kleinschek, S. Strnad, and V. Ribitsch, Polym. Eng. Sci., 39, 1412 (1999).
K. K. Wong, X. M. Tao, C. W. M. Yuen, and K. W. Yeung, Text. Res. J., 71, 49 (2001).
T. Kreze, S. Strnad, K. Stana-Kleinschek, and V. Ribitsch, Mater. Res. Innov., 4, 107 (2001).
Acknowledgments
This work was supported by the Ministry of Education, Science and Technological Development of the Republic of Serbia (Contract No. 451-03-68/2020-14/200135). The authors also thank ITES Odzaci (Serbia) for supplying the hemp fibers, and Ph.D. student A. Ivanovska for taking part in measuring of the WRV and MS.
Author information
Authors and Affiliations
Corresponding author
Supplementary Files for Manuscript
12221_2021_450_MOESM1_ESM.pdf
Oxidized hemp fibers with simultaneously increased capillarity and reduced moisture sorption as suitable textile material for advanced application in sportswear
Rights and permissions
About this article
Cite this article
Milanovic, J.Z., Milosevic, M., Korica, M. et al. Oxidized Hemp Fibers with Simultaneously Increased Capillarity and Reduced Moisture Sorption as Suitable Textile Material for Advanced Application in Sportswear. Fibers Polym 22, 2052–2062 (2021). https://doi.org/10.1007/s12221-021-0450-y
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12221-021-0450-y