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Effect of Delta Ferrite on Microstructure and Mechanical Properties of High-Chromium Martensitic Steel

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Abstract

The fusion zone of modified 9Cr-1Mo steel experiencing a peak temperature of 1450 °C and varying cooling rates between 1 and 40 °C/s from the peak temperature is simulated using Gleeble thermal simulator. Mechanical properties of the simulated samples are assessed by ball indentation and impression creep tests. The study evaluates the effect of cooling rate on volume fraction, morphology of retained delta ferrite in the simulated partially melted zone of an autogenous weld, and subsequently its effect on the mechanical properties of this zone. With varying cooling rate, volume fraction of delta ferrite does not change much; however, its morphology changes from polygonal island to grain boundary network in case of excessive slow cooling (1 °C/s). Morphological variation of delta ferrite affects the creep properties of this zone. Partially melted zone, which is cooled at 1 °C/s with delta ferrite present in the interdendritic regions, exhibits maximum creep strain and creep strain rate.

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References

  1. Masaki. Taneike, Kota. Sawada, and Fujio. Abe, Effect of Carbon Concentration on Precipitation Behavior of M23C6 Carbides and MX Carbonitrides in Martensitic 9Cr Steel During Heat Treatment, Metall. Mater. Trans. A, 2004, 35A, p 1255–1262

    Article  Google Scholar 

  2. C.R. Das, S.K. Albert, J. Swaminathan, S. Raju, A.K. Bhaduri, and B.S. Murty, Transition of Crack from Type IV to Type II, Resulting from Improved Utilization of Boron in the Modified 9Cr-1Mo Steel Weldment, Metall. Mater. Trans. A, 2012, 43(10), p 3724–3741

    Article  Google Scholar 

  3. Fujio. Abe, Precipitate Design for Creep Strengthening of 9% Cr Tempered Martensitic Steel for Ultra-Supercritical Power Plants, Sci. Technol. Adv. Mater., 2008, 9, p 1–15

    Article  Google Scholar 

  4. J.S. Park, S.J. Kim, and C.S. Lee, Effect of W Addition on the Low Cycle Fatigue Behavior of High Cr Ferritic Steels, Mater. Sci. Eng. A, 2001, 298, p 127–136

    Article  Google Scholar 

  5. L. Schafer, Influence of Delta Ferrite and Dendritic Carbides on the Impact and Tensile Properties of a Martensitic Chromium Steel, J. Nucl. Mater., 1998, 258–263, p 1336–1339

    Article  Google Scholar 

  6. K. Kimura, K. Sawasa, H. Kushima, and Y. Toda, Degradation behavior and long term creep strength of 12Cr ferritic creep resistant steels, in 8th International Conference on Materials for Advanced Power Engineering (Forschungszentrum Julich GmbH, Liege, 2006)

  7. X.Y. Liu and T. Fujita, Effect of Chromium Content on Creep Rupture Properties of a High Chromium Ferritic Heat Resisting Steels, ISIJ Int., 1989, 29(8), p 680–686

    Article  Google Scholar 

  8. P. Mayr, Evolution of Microstructure and Mechanical Properties of the Heat Affected Zone in B-Containing 9% Chromium Steels, Ph.D. dissertation (Graz University of Technology, Austria, 2007)

  9. S.K. Albert, C.R. Das, G. Chakraborty, A.K. Bhaduri, S. Lauf, S. Stuben-rauch, and A. Klenk, Study on effect of boron during the evaluation of HAZ microstructure in 9C-1Mo steel using gleeble weld simulator, in 37th MPA-Seminar, Stuttgart, Germany, 6-7 October, 2011

  10. M.D. Mathew, K.L. Murty, K.B.S. Rao, and S.L. Mannan, Ball Indentation Studies on the Effect of Aging on Mechanical Behavior of Alloy 625, Mater. Sci. Eng. A, 1999, 264, p 159–166

    Article  Google Scholar 

  11. Dipika.R. Barbadikar, A.R. Ballal, D.R. Peshwe, J. Ganeshkumar, K. Laha, and M.D. Mathew, Investigation on Mechanical Properties of P92 Steel Using Ball Indentation Technique, Mater. Sci. Eng. A, 2015, 624, p 92–101

    Article  Google Scholar 

  12. V. Rishi Pamnani, T. Karthik, M. Jayakumar, and T.Sakthivel. Vasudevan, Evaluation of Mechanical Properties Across Micro Alloyed HSLA Steel Weld Joints Using Automated Ball Indentation, Mater. Sci. Eng. A, 2016, 651, p 214–223

    Article  Google Scholar 

  13. D.H. Sastry, Impression Creep Technique—An Overview, Mater. Sci. Eng. A, 2005, 409, p 67–75

    Article  Google Scholar 

  14. M.D. Mathew, Naveena, and D. Vijayanand, Impression Creep Behavior of 316LN Stainless Steel, J. Mater. Eng. Perform., 2013, 22(2), p 492–497

    Article  Google Scholar 

  15. C.R. Das, A.K. Bhaduri, S. Raju, R. Balakrishnan, S. Mahadevan, S.K. Albert, and P. Mastanaiah, Influence of Electron Beam Welding Parameters on Microstructure and Charpy Impact Properties of Boron Added Modified 9Cr-1Mo Steel Weld, Weld World, 2016, 60, p 1141–1146

    Article  Google Scholar 

  16. J. Onoro, Weld Metal Microstructure Analysis of 9-12% Cr Steels, Press. Vessel. Pip., 2006, 83, p 540–545

    Article  Google Scholar 

  17. R. Kishore, R.N. Singh, T.K. Sinha, and B.P. Kashyap, The Morphology and Ageing Behavior of Delta Ferrite in a Modified 9Cr-1Mo Steel, J. Nucl. Mater., 1992, 195, p 198–204

    Article  Google Scholar 

  18. K. Laha, S. Latha, K. Bhanu Sankara Rao, S.L. Mannan, and D.H. Sastry, Comparison of Creep Behavior of 2.25Cr-1Mo/9Cr-1Mo Dissimilar Weld Joint with Its Base and Weld Metals, Mater. Sci. Technol., 2001, 17, p 1265–1272

    Article  Google Scholar 

  19. J.M. Vitek and R.L. Klueh, Precipitation Reactions During the Heat Treatment of Ferritic Steels, Metall. Trans. A, 1983, 14(5), p 1047–1055

    Article  Google Scholar 

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Correspondence to Gopa Chakraborty.

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Chakraborty, G., Ganesh Kumar, J., Vasantharaja, P. et al. Effect of Delta Ferrite on Microstructure and Mechanical Properties of High-Chromium Martensitic Steel. J. of Materi Eng and Perform 28, 876–885 (2019). https://doi.org/10.1007/s11665-019-3862-8

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  • DOI: https://doi.org/10.1007/s11665-019-3862-8

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