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A Nano-Hybrid of Molybdenum Oxide Intercalated by Dithiocarbamate as an Oxidation Catalyst

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Abstract

A novel nano-layered material based on molybdenum oxide has been synthesized by hydrothermal method using dithiocarbamate. On the basis of the X-ray diffraction, scanning electron microscopy, thermal analysis and infrared spectroscopy results, a possible arrangement of organic ligands in the interlayer space of molybdenum oxide has been proposed. Moreover, the catalytic activity of the synthesized nanohybrid of molybdenum oxide was investigated in oxygen transfer reactions. This reagent can oxidize alkenes, alcohols, sulfides, and amines in the presence of hydrogen peroxide with high yield and selectivity.

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References

  1. X.M. Wei, H.Ch. Zeng, Chem. Mater. 15, 433 (2003)

    Article  CAS  Google Scholar 

  2. Y. Zhao, J. Liu, Y. Zhou, Z. Zhang, Y. Xu, H. Naramoto, S. Yamamoto, J. Phys.: Condens. Matter 15, L547 (2003)

    Article  CAS  Google Scholar 

  3. A.M. Taurino, A. Forleo, L. Francioso, P. Siciliano, M. Stalder, R. Nesper, Appl. Phys. Lett. 88, 152111 (2006)

    Article  CAS  Google Scholar 

  4. S. Takenaka, T. Tanaka, T. Funabiki, S. Yshida, J. Phys. Chem. B 102, 2960 (1998)

    Article  CAS  Google Scholar 

  5. H. Tagaya, K. Ara, J.I. Kadokawa, M. Karasu, K. Chiba, J. Mater. Chem. 4, 551 (1994)

    Article  CAS  Google Scholar 

  6. S.T. Oyama, W. Zhang, J. Am. Chem. Soc. 118, 7173 (1996)

    Article  CAS  Google Scholar 

  7. W.M. Zhang, A. Desikan, S.T. Oyama, J. Phys. Chem. 99, 14468 (1995)

    Article  CAS  Google Scholar 

  8. S. Takenaka, T. Tanaka, T. Funabiki, J. Chem. Soc. Farad. Trans. 94, 695 (1998)

    Article  CAS  Google Scholar 

  9. S.T. Oyama, S. Radhakrishnan, M. Seman, J.N. Kondo, K. Domen, K. Asakura, J. Phys. Chem. B 107, 1845 (2003)

    Article  CAS  Google Scholar 

  10. R.H. Holm, Coord. Chem. Rev. 100, 183 (1990)

    Article  CAS  Google Scholar 

  11. R.C. Maurya, D.D. Mishra, Ind. J. Chem. 36A, 599 (1997)

    CAS  Google Scholar 

  12. J.B. Howard, D.C. Rees, Chem. Rev. 96, 2965 (1996)

    Article  CAS  Google Scholar 

  13. R. Hille, Chem. Rev. 96, 2757 (1996)

    Article  CAS  Google Scholar 

  14. M. Gomez, S. Jansat, Eur. J. Inorg. Chem. 1071 (2001)

  15. C. Lorber, M.R. Plutino, J. Chem. Soc. Dalton Trans. 3997 (1997)

  16. Y. Jing, Q. Pan, Z. Cheng, X. Dong, Y. Xiang, Mat. Sci. Eng. B 138, 55 (2007)

    Article  CAS  Google Scholar 

  17. O.Y. Posudievsky, S.A. Biskulova, V.D. Pokhodenko, J. Mater. Chem. 12, 1446 (2002)

    Article  CAS  Google Scholar 

  18. P.J. Zapf, R.L. Laduca, R.S. Rarig, K.M. Johnson, J. Zubieta, Inorg. Chem. 37, 3411 (1998)

    Article  CAS  Google Scholar 

  19. R.F. de Farias, Mater. Chem. Phys. 90, 302 (2005)

    Article  CAS  Google Scholar 

  20. Y. Xu, L.H. An, L.L. Koh, Chem. Mater. 8, 814 (1996)

    Article  CAS  Google Scholar 

  21. R.F. de Farias, Int. J. Inorg. Mater. 3, 931 (2001)

    Article  Google Scholar 

  22. P.J. Zapf, R.C. Haushalter, J. Zubieta, Chem. Mater. 9, 2019 (1997)

    Article  CAS  Google Scholar 

  23. W.Sh. You, X. Guo, X.L. Yu, C.Y. Huang, L.C. Zhang, Z.Y. Sun, Inorg. Chem. Commun. 10, 23 (2007)

    Article  CAS  Google Scholar 

  24. V.A. Ung, A.M.W.C. Thompson, D.A. Bardwell, D. Gaheschi, J.C. Jeffery, J.A. McCleverty, F. Totti, M.D. Ward, Inorg. Chem. 36, 3447 (1997)

    Article  CAS  Google Scholar 

  25. Y. Xu, J. Lu, Inorg. Chim. Acta 139, 311 (1999)

    Google Scholar 

  26. B. Yan, Y. Xu, N.K. Goh, L.S. Chia, Chem. Commun. 2169 (2000)

  27. P.J. Hagerman, R.L. Laduca, H.J. Koo, R. Rarig, R.C. Haushalter, M.H. Whangbo, J. Zubieta, Inorg. Chem. 39, 4311 (2000)

    Article  CAS  Google Scholar 

  28. M. Niederberger, F. Krumeich, H.J. Muhr, M. Muller, R. Nesper, J. Mater. Chem. 11, 1941 (2001)

    Article  CAS  Google Scholar 

  29. M.I. Schukoor, H.A. Therese, L. Gorgishvili, G. Glasser, U. Kolb, W. Tremel, Chem. Mater. 18, 2144 (2006)

    Article  CAS  Google Scholar 

  30. X.M. Wie, H.Ch. Zeng, J. Phys. Chem. B 107, 2619 (2003)

    Article  CAS  Google Scholar 

  31. R.C. Maurya, D.D. Mishra, Ind. J. Chem. A 36, 599 (1997)

    Article  Google Scholar 

  32. M. Gomez, S. Jansat, Eur. J. Inorg. Chem. 1071 (2001)

  33. C. Lorber, M.R. Plutino, J. Chem. Soc. Dalton Trans. 3997 (1997)

  34. W. Adam, D. Golsch, J. Sundermeyer, G. Wahl, Chem. Ber. 129, 1177 (1996)

    Article  CAS  Google Scholar 

  35. F.E. Kuhn, A.M. Santos, P.W. Roesky, E. Herdweck, W. Scherer, P. Gisdakis, I.V. Yudanov, C.Di Valentin, N. Rosch, Chem. Eur. J. 5, 3603 (1999)

    Article  Google Scholar 

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Acknowledgement

Support of this investigation by Tarbiat Modares University is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Tarbiat Modares University, Alleahmad Ave., 14155-4838, Tehran, Iran

    Maryam Afsharpour & Alireza Mahjoub

  2. Department of Chemistry, Shahid Beheshti University, 1983963113, Tehran, Iran

    Mostafa M. Amini

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  1. Maryam Afsharpour
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  2. Alireza Mahjoub
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  3. Mostafa M. Amini
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Correspondence to Alireza Mahjoub.

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Afsharpour, M., Mahjoub, A. & Amini, M.M. A Nano-Hybrid of Molybdenum Oxide Intercalated by Dithiocarbamate as an Oxidation Catalyst. J Inorg Organomet Polym 18, 472–476 (2008). https://doi.org/10.1007/s10904-008-9223-y

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