Abstract
A simple method for the determination of total sulfur content in vegetable and marine oils is described. The method involves combustion of the oil sample in an oxygen bomb to convert all forms of sulfur to sulfate ions with subsequent determination of the sulfate by ion chromatography and indirect ultraviolet detection. The ultraviolet system described is more sensitive than conductivity detection and enables the method to be applied more widely.
Application of the method to a variety of vegetable and marine oils showed the general occurrence of sulfur in fats and oils, albeit often at a low level. Among the samples examined, crude Canola oil had the highest sulfur content (25.0 mg/kg) followed by the marine oils (5.8-15.2 mg/kg) and the non-Cruciferae vegetable oils (2.0-6.1 mg/kg).
Similar content being viewed by others
References
Ackman, R.G., inHigh and Low Erucic Acid Rapeseed Oils, edited by J.K.G. Kramer, F.D. Saurer and W.J. Pigden, Academic Press, New York, 1983, pp. 85–129.
Daun, J.K., and F.W. Hougen,J. Am. Oil Chem. Soc. 55:169 (1976).
Daun, J.K., and F.W. Hougen,Ibid. 54:351 (1977).
Rutkowski, A., S. Gwizada and K. Krygier,Ibid. 59:1 (1982).
Devinat, G., and S. Biasini,Rev. Fr. Corps Gras. 27:563 (1980).
deMan, J.M., E. Pogorzelska and L. deMan,J. Am. Oil Chem. Soc. 60:558 (1983).
Moser, H.A., CD. Evans, G. Mustakas and J.C. Cowan,Ibid. 42:811 (1965).
Stevenson S.G., L. Jeffery, M. Vaisy-Genser, B. Fyfe, F.W. Hougen and N.A.M. Eskin,Can. Inst. Food Sci. Technol. J. 17:187 (1984).
Ackman, R.G., J. Hingley and K.T. MacKay,J. Fish. Res. Bd. Canada 29:1085 (1972).
Christensen, B.W., A. Kjaer and J. Ogaard Mansen,J. Am. Oil Chem. Soc. 58:1053 (1981).
Olsen, K.B., N.C. Jensen and K.H. Reimers,Sulfur in Fish Oil, Technical University of Denmark Report, 1980.
Granatelli, L.,Anal. Chem. 31:434 (1959).
Devinat, G., S. Biasini and M. Naudet,Rev. Fr. Corps. Gras. 27:229 (1980).
Abraham, V., and J.M. deMan,J. Am. Oil Chem. Soc. 64:384 (1987).
Jupille, T.H., and D.T. Gjerde,J. Chromatogr. Sci. 24:427 (1986).
Small, H., and T.E. Miller,Anal. Chem. 54:462 (1982).
Cochrane, R.A., and D.E. Hillman,J. Chromatogr. 242:392 (1982).
Elson, CM., R.G. Ackman and A. Chatt,J. Am. Oil Chem. Soc. 60:829 (1983).
Wijesundera, R.C., and R.G. Ackman,Ibid. 65:959 (1988).
Wijesundera, R.C., and R.G. Ackman,Ibid. 65:1531 (1988).
Author information
Authors and Affiliations
Additional information
To whom correspondence should be addressed.
About this article
Cite this article
Wijesundera, R.C., Ackman, R.G., Abraham, V. et al. Determination of sulfur contents of vegetable and marine oils by ion chromatography and indirect ultraviolet photometry of their combustion products. J Am Oil Chem Soc 65, 1526–1530 (1988). https://doi.org/10.1007/BF02898321
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02898321