Abstract
The mechanical, rheological, thermal, and surface behaviors of three polyacrylamide/dextran (PAAm/Dx) semi-interpenetrating polymer network (semi-IPN) hydrogels, prepared at 22°C, 5°C and −18°C, were investigated. The results were compared with those obtained on cross-linked PAAm without Dx synthesized under the same conditions. Hydrogels prepared at the lowest temperature were the most mechanically stable. The thermal stability of the semi-IPN hydrogels is slightly lower than the corresponding PAAm gels, irrespective of preparation temperature. The water vapor sorption capacity depended on the presence of Dx as well as preparation temperature, which determines the network morphology.
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A. Spanoudaki, D. Fragiadakis, K. Vartzelinikaki, P. Pissis, J.C.R. Hernandez, M.M. Pradas, In: J.P. Blitz, V.M. Gun’ko (Eds.), Surface chemistry in biomedical and environmental science (Springer, Dordrecht, 2006) 229
D.E. Rodriguez-Felix, C.J. Perez-Martinez, M.M. Castillo-Ortega, M. Perez-Tello, J. Romero-Garcia, A.S. Ledezma-Perez, T. Del Castillo-Castro, F. Rodriguez-Felix, Polym. Bull. 68, 197 (2012)
C.C. Lin, K.S. Anseth, Pharma. Res. 26, 631 (2009)
X. Zhong, C. Ji, A.K.L. Chan, S.G. Kazarian, A. Ruys, F. Dehghani, J. Mater. Sci: Mater. Med. 22, 279 (2011)
J. Michalek, M. Pradny, A. Artyukhov, M. Slouf, K. Smetana Jr., J. Mater. Sci: Mater. Med. 16, 783 (2005)
M.V. Dinu, M.M. Perju, E.S. Drăgan, Macromol. Chem. Phys. 212, 240 (2011)
D. Myung, D. Waters, M. Wiseman, P.E. Duhamel, J. Noolandi, C.N. Ta, C.W. Frank, Polym. Adv. Technol. 19, 647 (2008)
V.I. Lozinsky, Russ. Chem. Bull. Int. Ed. 57, 1015 (2008)
M.V. Dinu, M.M. Perju, E.S. Drăgan, React. Funct. Polym. 71, 881 (2011)
E.S. Drăgan, M.M. Perju, M.V. Dinu, Carbohydr. Polym. 88, 270 (2012)
E.S. Dragan, D.F. Apopei, Chem. Eng. J. 178, 252 (2011)
E.S. Dragan, M.M. Lazar, M.V. Dinu, F. Doroftei, Chem. Eng. J. 204–206, 198 (2012)
A.K. Kabiri, H. Omidian, M.J. Zohuriaan-Mehr, S. Doroudiani, Polym. Compos. 32, 277 (2011)
Y. Yu, X. Chang, H. Ning, S. Zhang, Cent. Eur. J. Chem. 6, 107 (2008)
Y. Yu, Y. Li, C. Zhu, L. Liu, Cent. Eur. J. Chem. 8, 426 (2010)
W. Wang, Q. Wang, A. Wang, Macromol. Res. 19, 57 (2011)
L.H. Sperling, In: D. Klempner, L.H. Sperling, L.A. Utracki (Eds.), Interpenetrating polymer networks (American Chemical Society, Washington, 1994) 3
M.V. Dinu, M.M. Ozmen, E.S. Drăgan, O. Okay, Polymer 48, 195 (2007)
H. Kirsebom, D. Topgaard, I. Yu. Galaev, B. Mattiasson, Langmuir 26, 16129 (2010)
N. Orakdogen, P. Karacan, O. Okay, React. Funct. Polym. 71, 782 (2011)
A. Tripathi, A. Kumar, Macromol. Biosci. 11, 22 (2011)
A.P. Rokhade, S.A. Patil, T.M. Aminabhavi, Carbohydr. Polym. 67, 605 (2007)
Y. Liu, M.B. Chan-Park, Biomaterials 30, 196 (2009)
R.Y. Cheung, Y. Ying, A.M. Rauth, N. Marcon, X. Yu Wu, Biomaterials 26, 5375 (2005)
A. Autissier, C. Le Visage, C. Pouzet, F. Chaubet, D. Letourneur, Acta Biomaterialia 6, 3640 (2010)
C. Sayil, O. Okay, Polymer, 42, 7639 (2001)
C. Seidel, W.M. Kulicke, C. Heß, B. Hartmann, M.D. Lechner, W. Lazik, Starch/Stärke 56, 157 (2004)
O.S. Lawal, J. Storz, H. Storz, D. Lohmann, D. Lechner, W.M. Kulicke, Eur. Polym. J. 45, 3399 (2009)
A. Martinez-Ruvalcaba, E. Chornet, D. Rodrigue, Carbohydr. Polym. 67, 586 (2007)
P. Petrov, E. Petrova, R. Stamenova, C.B. Tsvetanov, G. Riess, Polymer 47, 6481 (2006)
X. Yang, Q. Liu, X. Chen, F. Yu, Z. Zhu, Carbohydr. Polym. 73, 401 (2008)
Q. Zhao, J. Sun, X. Wu, Y. Lin, Soft Matter 7, 4284 (2011)
J. Chen, M. Liu, H. Liu, L. Ma, C. Gao, S. Zhu, S. Zhang, Chem. Eng. J. 159, 247 (2010)
T.T. Reddy, A. Takahara, Polymer 50, 3537 (2009)
L.R.G. Treloar, In: L.R.G. Treloar (Ed.), The elasticity of a molecular network (University Press, Oxford, 1975) 59
L. Janovák, J. Varga, L. Kemény, I. Dékány, Colloid Polym. Sci. 286, 1575 (2008)
Y. Liu, Y. Cui, Polym. Int. 60, 1117 (2011)
Y. Zhou, D. Yang, X. Gao, X. Chen, Q. Xu, F. Lu, J. Nie, Carbohydr. Polym. 75, 293 (2009)
D.L. Merlin, B. Sivasankar, Eur. Polym. J. 45, 165 (2009)
M.N. Khalid, F. Agnely, N. Yagoubi, J.L. Grossiord, G. Couarraze, Eur. J. Pharma. Sci. 15, 425 (2002)
N.B. Milosavljević, N.Z. Milašinović, I.G. Popović, J.M. Filipović, M.T. Krušić Kalagasidis, Polym. Int. 60, 443 (2010)
K. Burugapalli, D. Bhatia, V. Koul, V. Choudhary, J. Appl. Polym. Sci. 82, 217 (2001)
S. Chen, J. Hu, H. Zhuo, J. Mat. Sci. 46, 6581 (2011)
Y.K. Sung, M.S. Jhon, D.E. Gregonis, J.D. Andrade, Polymer (Korea) 8, 123 (1984)
A. Stathopoulos, P. Klonos, A. Kyritsis, P. Pissis, C. Christodoulides, J.C.M. Rodriguez Hernández, M. Pradas, J.L. Gómez Ribelles, Eur. Polym. J. 46, 101 (2010)
L. Zhou, Master Thesis, University of Minnesota (Minnesota, USA, 2010)
C.G.V. Burgess, D.H. Everett, S. Nuttall, Pure Appl. Chem. 61, 1845 (1989)
S. Brunauer, P.H. Emmett, E. Teller, J. Am. Chem. Soc. 60, 309 (1938)
S.L. Wang, C.T. Johnston, D.L. Bish, J.L. White, S.L. Hem, J. Col.Interf. Sci. 260, 26 (2003)
L. Czepirski, E. Komorowska-Czepirska, J. Szymońska, Appl. Surf. Sci. 196, 150 (2002)
Z. Sokołowska, J. Jamroz, P. Bańka, Int. Agrophys. 22, 75 (2008)
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Dinu, M.V., Cazacu, M. & Drăgan, E.S. Mechanical, thermal and surface properties of polyacrylamide/dextran semi-interpenetrating network hydrogels tuned by the synthesis temperature. cent.eur.j.chem. 11, 248–258 (2013). https://doi.org/10.2478/s11532-012-0155-6
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DOI: https://doi.org/10.2478/s11532-012-0155-6