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Ordering of SiOxHyCz islands deposited by atmospheric pressure microwave plasma torch on Si(100) substrates patterned by nanoindentation

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  • Clusters and Nanostructures
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Abstract

SiO x H y C z nanometric layers are deposited from hexamethyldisiloxane by atmospheric pressure microwave plasma torch on Si(100) substrates submitted to temperatures varying on the range [0 °C; 120 °C]. Atomic force microscopy (AFM) characterizations of samples grown at intermediate substrate temperatures (~30 °C) demonstrate a layer-by-layer growth (Frank van der Merwe growth) leading to smooth flat and compact films while films deposited at lower and higher substrates temperatures show an island-like growth (Volmer-Weber growth) generating a high surface roughness. Concomitantly, a detailed infrared spectroscopy analysis of the growing films evidences structural modifications due to changes in the bond types, Si-O-Si conformation and stoichiometry correlated with scanning electron microscopy and AFM characterizations. Then, deposition conditions and specific microstructure are selected with the aim of generating 3-dimensional SiO x H y C z nanostructure arrays on nanoindented Si (100) templates. The first results are discussed.

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References

  1. J.H. Lim, D.S. Ginger, K.B. Lee, J. Heo, J.M. Nam, C.A. Mirkin, Angew. Chem. Int. Ed. 42, 2309 (2003)

    Article  Google Scholar 

  2. Y.L. Wua, J.J. Lin, P.Y. Hsua, C.P. Hsu, Sens. Actuators B 155, 709 (2011)

    Article  Google Scholar 

  3. A. Bruckbauer, D.J. Zhou, L.M. Ying, Y.E. Korchev, C. Abell, D. Klenerman, J. Am. Chem. Soc. 125, 9834 (2011)

    Article  Google Scholar 

  4. B. Fousseret, M. Mougenot, F. Rossignol, J.F. Baumard, B. Soulestin, C. Boissière, F. Ribot, D. Jalabert, C. Carrion, C. Sanchez, M. Lejeune, Chem. Mater. 22, 3875 (2010)

    Article  Google Scholar 

  5. K. Teshima, Y. Inoue, H. Sugimura, O. Takai, Thin Solid Films 420-421, 324 (2002)

    Article  ADS  Google Scholar 

  6. K. Wadu-Mesthrige, S. Xu, N.A. Amro, G.Y. Liu, Langmuir 15, 8580 (1999)

    Article  Google Scholar 

  7. R.D. Piner, J. Zhu, F. Xu, S.H. Hong, C.A. Mirkin, Science 283, 661 (1999)

    Article  Google Scholar 

  8. H. Taha, R.S. Marks, L.A. Gheber, I. Rousso, J. Newman, C. Sukenik, A. Lewis, Appl. Phys. Lett. 83, 1041 (2003)

    Article  ADS  Google Scholar 

  9. S.Q. Sun, M. Montague, K. Critchley, M.S. Chen, W.J. Dressick, S.D. Evans, G.J. Leggett, Nano Lett. 6, 29 (2006)

    Article  ADS  Google Scholar 

  10. G. Arnoult, T. Belmonte, F. Kosior, M. Dossot, G. Henrion, J. Appl. Phys. 44, 174022 (2011)

    Google Scholar 

  11. I. Levchenko, U. Cvelbar, K. Ostrikov, Appl. Phys. Lett. 95, 021502 (2009)

    Article  Google Scholar 

  12. K. Ostrikov, I. Levchenko, U. Cvelbar, M. Sunkara, M. Mozetic, Nanoscale 2, 2012 (2010)

    Article  ADS  Google Scholar 

  13. X. Landreau, C. Dublanche-Tixier, C. Jaoul, C. Le Niniven, N. Lory, P. Tristant, Surf. Coat. Technol. 205, 335 (2011)

    Article  Google Scholar 

  14. J. Schäfer, R. Foest, A. Quade, A. Ohl, J. Meichsner, K.D. Weltmann, Eur. Phys. J. D 54, 211 (2009)

    Article  ADS  Google Scholar 

  15. R.F. Xiao, N.B. Ming, Phys. Rev. E 49, 4720 (1994)

    Article  ADS  Google Scholar 

  16. R.F. Xiao, J.I.D. Alexander, F. Rosenberger, Phys. Rev. A 43, 2977 (1991)

    Article  ADS  Google Scholar 

  17. S. Mahieu, P. Ghekiere, D. Depla, R. De Gryse, Thin Solid Films 515, 1229 (2006)

    Article  ADS  Google Scholar 

  18. S. Pratontep, M. Brinkmann, Phys. Rev. B 69, 165201 (2004)

    Article  ADS  Google Scholar 

  19. I.P. Lisovskii, V.G. Litovchenko, V.G. Lozinskii, G.I. Steblovskii, Thin Solid Films 213, 164 (1992)

    Article  ADS  Google Scholar 

  20. M.K. Gunde, Physica B 292, 286 (2000)

    Article  ADS  Google Scholar 

  21. D.W. Berreman, Phys. Rev. 130, 2193 (1963)

    Article  ADS  Google Scholar 

  22. R.A.B. Devine, Appl. Phys. Lett. 68, 3108 (1996)

    Article  ADS  Google Scholar 

  23. S.S. Kilchitskaya, S.V. Litvinenko, V.A. Skryshevsky, V.I. Strikha, V.P. Tolstoy, Poverhnost (Surface) 4, 99 (1987)

    Google Scholar 

  24. V.V. Tarasov, Problems of Glass Physics (Stroiizdat, Moscow, 1979)

  25. J. Schäfer, R. Foest, A. Quade, A. Ohl, K.D. Weltmann, Plasma Process. Polym. 6, S519 (2009)

    Article  Google Scholar 

  26. J. Schäfer, S. Horn, R. Foest, R. Brandenburg, P. Vasina, K.D. Weltmann, Surf. Coat. Technol. 205, S392 (2011)

    Article  Google Scholar 

  27. A. Brunet-Bruneau, J. Rivory, B. Rafin, J.Y. Robic, P. Chaton, J. Appl. Phys. 82, 1330 (1997)

    Article  ADS  Google Scholar 

  28. P.G. Pai, S.S. Chao, Y. Takagi, G. Lucovsky, J. Vac. Sci. Technol. 4, 690 (1986)

    ADS  Google Scholar 

  29. V.A. Skryshevsky, V.P. Tolstoy, Infrared Spectroscopy of Semiconductor Structures (Lybid, Kiev, 1991)

  30. A. Slaoui, J.P. Ponpon, P. Siffert, Appl. Phys. 43, 301 (1987)

    Article  Google Scholar 

  31. E.M. Allegretto, J.A. Bardwell, J. Vac. Sci. Technol. 14, 2437 (1996)

    Article  ADS  Google Scholar 

  32. H. Hu, H.J. Gao, F. Liu, Phys. Rev. Lett. 101, 216102 (2008)

    Article  ADS  Google Scholar 

  33. Z. Zhang, M.G. Lagally, Science 276, 377 (1997)

    Article  Google Scholar 

  34. W. Oswald, Phys. Chem. 34, 495 (1900)

    Google Scholar 

  35. B.K. Chakraverty, J. Phys. Chem. Solids 28, 2401 (1967)

    Article  ADS  Google Scholar 

  36. T.I. Kamins, E.C. Carrs, R.S. Williams, S.J. Rosner, J. Appl. Phys. 81, 211 (1997)

    Article  ADS  Google Scholar 

  37. Z. Zhong, O.G. Schmidt, G. Bauer, Appl. Phys. Lett. 87, 133111 (2005)

    Article  ADS  Google Scholar 

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Landreau, X., Lanfant, B., Merle, T. et al. Ordering of SiOxHyCz islands deposited by atmospheric pressure microwave plasma torch on Si(100) substrates patterned by nanoindentation . Eur. Phys. J. D 65, 421–428 (2011). https://doi.org/10.1140/epjd/e2011-20503-7

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  • DOI: https://doi.org/10.1140/epjd/e2011-20503-7

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