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Interaction of ammonia with organoboron nanoparticle-based coatings

  • Chemical Physics of Nanomaterials
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Abstract

The interaction between ammonia and (C2B10H4) n nanoparticle-coated and uncoated graphite plates combined with molybdenum surface heated to 700 K was investigated. It was found that in both cases the interaction leads to the decomposition of ammonia into hydrogen and nitrogen; however, the presence of organoboron nanoparticles (OBN) accelerates this process. The tunneling current-voltage dependences of the nanoparticles before and after interaction with NH3 were measured. The close similarity of the measured I–V curves suggests that the interaction preserves the organoboron-nanoparticle electronic structure.

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Authors and Affiliations

  1. Semenov Insitute of Chemical Physics of Russian Academy of Sciences, Moscow, Russia

    M. V. Grishin, A. K. Gatin, V. G. Slutskii, V. A. Kharitonov & B. R. Shub

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  1. M. V. Grishin
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  2. A. K. Gatin
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  3. V. G. Slutskii
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  4. V. A. Kharitonov
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  5. B. R. Shub
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Correspondence to M. V. Grishin.

Additional information

Original Russian Text © M.V. Grishin, A.K. Gatin, V.G. Slutskii, V.A. Kharitonov, B.R. Shub, 2014, published in Khimicheskaya Fizika, 2014, Vol. 33, No. 6, pp. 73–76.

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Grishin, M.V., Gatin, A.K., Slutskii, V.G. et al. Interaction of ammonia with organoboron nanoparticle-based coatings. Russ. J. Phys. Chem. B 8, 416–419 (2014). https://doi.org/10.1134/S1990793114030208

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  • DOI: https://doi.org/10.1134/S1990793114030208

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