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Dissolution of powder celluloses in the dimethylacetamide-LiCl system and physicochemical characteristics of the regenerated samples

  • Macromolecular Compounds and Polymeric Materials
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Abstract

Dissolution of powder cellulose samples from flax wastes and wood pulps in the dimethylacetamide-LiCl solvent was studied. The decisive factors of cellulose dissolution are the degree of chemical “purity” of cellulose and the degree of polymerization. The cellulose I supramolecular structure of the initial samples transforms into a mixture of polymorphous modifications after dissolution and subsequent regeneration from solutions. The samples regenerated from solutions consist of highly porous spherical particles. The powder samples degrade at the fibrillar level in solutions.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia

    N. E. Kotel’nikova

  2. Institute of Chemistry, Komi Scientific Center, Ural Branch, Russian Academy of Sciences, Syktyvkar, Komi Republic, Russia

    Yu. V. Bykhovtsova & T. P. Shcherbakova

Authors
  1. N. E. Kotel’nikova
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  2. Yu. V. Bykhovtsova
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  3. T. P. Shcherbakova
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Correspondence to N. E. Kotel’nikova.

Additional information

Original Russian Text © N.E. Kotel’nikova, Yu.V. Bykhovtsova, T.P. Shcherbakova, 2013, published in Zhurnal Prikladnoi Khimii, 2013, Vol. 86, No. 1, pp. 105–113.

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Kotel’nikova, N.E., Bykhovtsova, Y.V. & Shcherbakova, T.P. Dissolution of powder celluloses in the dimethylacetamide-LiCl system and physicochemical characteristics of the regenerated samples. Russ J Appl Chem 86, 96–103 (2013). https://doi.org/10.1134/S1070427213010175

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  • DOI: https://doi.org/10.1134/S1070427213010175

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