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Two new supramolecular hybrids based on bi-capped Keggin {PMo12V2O42} clusters and transition metal mixed-organic-ligand complexes

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Abstract

Two supramolecular compounds [Cu(imz)2][Cu(phen)(imz)]2{[Cu(phen)]2[PMo6 VIMo6 VV2 IVO42]}(1) and [Co2(2,2′-bpy)4(C2O4)][Co(2,2′-bpy)3][PMo7 VIMo5 VV2 IVO42](2,2′-bpy)0.5·H2O(2)(phen=1,10′-phenanthroline, imz= imidazole, 2,2′-bpy=2.2′-bipyridine) have been synthesized hydrothermally and characterized by elemental analyses, infrared spectrum, UV-Vis, X-ray photoelectron spectroscopy(XPS), electron spin resonance(ESR) spectra, thermogravimetry analyses and single crystal X-ray diffraction analyses. Single-crystal X-ray diffraction analyses revealed that both the compounds represent the examples of compounds based on the bi-capped Keggin polyoxoanion {PMo12V2O42} and transition metal mixed-organic-ligand coordination complexes. Compound 1 consists of bi-capped Keggin polyoxoanion [PMo12V2O42]5− supported copper coordination groups, which are further inter-connected with two types of copper complex fragments forming a 3D supramolecular framework via π⋯π stacking, C-H⋯O and N-H⋯O hydrothermal bonding interactions. Compound 2 is a new hybrid consisted of polyoxoanion [PMo12V2O42]4−, [Co2(2,2′-bpy)4(C2O4)]2+ and [Co(2,2′-bpy)3]2+. There are no direct interactions in compound 2, but the polyoxoanions together with two different cobalt complex groups construct a 3D supramolecular network through C-H⋯O hydrogen bonding interactions.

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Authors and Affiliations

  1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, 130012, P. R. China

    Weijie Duan, Shihui Jiao, Xu Liu, Jinlei Chen, Xuan Cao, Yan Chen, Wei Xu, Xiaobing Cui, Jiqing Xu & Guangsheng Pang

Authors
  1. Weijie Duan
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  2. Shihui Jiao
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  3. Xu Liu
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  4. Jinlei Chen
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  5. Xuan Cao
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  6. Yan Chen
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  7. Wei Xu
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  8. Xiaobing Cui
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  9. Jiqing Xu
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  10. Guangsheng Pang
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Correspondence to Xiaobing Cui or Guangsheng Pang.

Additional information

Supported by the National Natural Science Foundation of China(No.21371066).

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Duan, W., Jiao, S., Liu, X. et al. Two new supramolecular hybrids based on bi-capped Keggin {PMo12V2O42} clusters and transition metal mixed-organic-ligand complexes. Chem. Res. Chin. Univ. 31, 179–186 (2015). https://doi.org/10.1007/s40242-015-5033-2

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  • DOI: https://doi.org/10.1007/s40242-015-5033-2

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