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Supramolecular Architectures in Three Metal(II) Coordination Polymers with 2,5-Dichloroterephthalate and Flexible Bis(Benzimidazole) Ligands

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Abstract

Three supramolecular coordination polymers, namely [Ni(L1)(DCTP)(H2O)] n (1), [Cu(L2)(DCTP)] n (2), [Co(L3)(DCTP)] n (3) (L1 = 1,5-bis(5,6-dimethylbenzimidazole)pentane, L2 = 1,4-bis(5,6-dimethylbenzimidazole)butane, L3 = 1,4-bis(benzimidazole)-2-butylene) have been hydrothermally synthesized and characterized by single crystal X-ray structure determination, FT-IR, elemental analysis, X-ray powder diffraction (XPD), and thermogravimetric analysis (TGA). CP 1 exhibits 2D 63 honeycombed network structure, which is further extended into a 3D Moganite (mog) supramolecular framework by classical O–H⋯O hydrogen-bonding interaction. CPs 2 –3 present 2D (4,4) layers, and 3D supramolecular frameworks that are formed by π–π stacking interactions. Furthermore, the catalytic activities of CPs 1–3 for the degradation of methyl orange in a Fenton-like process has been investigated, and CPs 1–3 show strong photoluminescence properties at room temperature in solid state.

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Acknowledgements

The project was supported by the National Natural Science Foundation of China (51474086), Natural Science Foundation – Steel and Iron Foundation of Hebei Province (B2015209299).

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  1. College of Chemical Engineering, Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic Materials, North China University of Science and Technology, Tangshan, Hebei, 063009, People’s Republic of China

    Hai-Ning Chang, Suo-Xia Hou, Guang-Hua Cui & Sheng-Chun Wang

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  1. Hai-Ning Chang
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  2. Suo-Xia Hou
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  3. Guang-Hua Cui
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Correspondence to Guang-Hua Cui or Sheng-Chun Wang.

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Chang, HN., Hou, SX., Cui, GH. et al. Supramolecular Architectures in Three Metal(II) Coordination Polymers with 2,5-Dichloroterephthalate and Flexible Bis(Benzimidazole) Ligands. J Inorg Organomet Polym 27, 518–527 (2017). https://doi.org/10.1007/s10904-016-0494-4

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  • DOI: https://doi.org/10.1007/s10904-016-0494-4

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