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Synthesis of ADI/HDI hybrid isocyanurate and its application in polyurethane coating

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Abstract

Hybrid isocyanurate was prepared by solvent-free trimerization of hexamethylene diisocyanate (HDI) and bis(isocyanatomethyl) cyclohexane (ADI), and characterized by gel permeation chromatography (GPC), gas chromatography (GC), nuclear magnetic resonance (NMR), and electrospray ionization mass spectrometry (ESI–MS). The results showed that ADI/HDI hybrid isocyanurate could be prepared with 2-hydroxypropyl-trimethyl-azanium catalyst at reaction temperatures between 50°C and 70°C. Both the GC and 1H NMR analyses identified a favorable linear relationship between the feed ratio of the starting monomers and the amount of each individual isocyanate incorporated into the oligomer (reaction ratio). Compared to coatings prepared from the mixture of ADI isocyanurate and HDI isocyanurate, the coatings from ADI/HDI hybrid isocyanurate possess higher distinctness of image.

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Acknowledgments

This research was supported by Dow Chemical Company Limited. The authors wish to thank Prof. Zhiping Zhang for his assistance.

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Authors and Affiliations

  1. Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai, 200237, China

    Guiyou Wang, Kang Li, Wei Zou, Aiguo Hu & Chunpu Hu

  2. Dow Chemical Company Limited, No. 936, Zhang Heng Road, Zhangjiang Hi-Tech Park, Shanghai, 201203, China

    Yangping Zhu, Chen Chen, Glynn Guo & Aaron Yang

  3. The Dow Chemical Company, Midland, MI, 48674, USA

    Ray Drumright & John Argyropoulos

Authors
  1. Guiyou Wang
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  2. Kang Li
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  3. Wei Zou
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Correspondence to Guiyou Wang.

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Wang, G., Li, K., Zou, W. et al. Synthesis of ADI/HDI hybrid isocyanurate and its application in polyurethane coating. J Coat Technol Res 12, 543–553 (2015). https://doi.org/10.1007/s11998-014-9650-3

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  • DOI: https://doi.org/10.1007/s11998-014-9650-3

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