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Experimental Investigation and Thermodynamic Calculation of the Phase Equilibria in the Cu-Fe-Ta System

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Abstract

The phase equilibria in the Cu-Fe-Ta ternary system at 1000, 1100 and 1200  C have been experimentally determined by optical microscopy, electron probe micro-analyzer and x-ray diffraction on ternary equilibrated alloys. The Cu-Ta binary system was reassessed and the thermodynamic assessments of the Cu-Fe-Ta ternary system were carried out by using calculation of phase diagrams method on the basis of the experimental data investigated in the present work. A consistent set of the thermodynamic parameters leading to reasonable agreement between the calculated results and experimental data was obtained in the Cu-Ta and Cu-Fe-Ta systems.

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References

  1. C.P. Wang, X.J. Liu, I. Ohnuma, R. Kainuma, and K. Ishida, Formation of Immiscible Alloy Powders with Egg-Type Microstructure, Science, 2002, 297, p 990-993

    Article  ADS  Google Scholar 

  2. S.K. Ghosh, T. Bera, C. Saxena, S. Bhattacharya, and G.K. Dey, Effect of Pulse Plating and Additive on Phase Separation in Cu-Co Nano-Granular Alloys, J. Alloys Compd., 2009, 475, p 676-682

    Article  Google Scholar 

  3. I. Ohnuma, T. Saegusa, Y. Takaku, C.P. Wang, X.J. Liu, R. Kainuma, and K. Ishida, Microstructural Evolution of Alloy Powder for Electronic Materials with Liquid Miscibility Gap, J. Electron. Mater., 2009, 38, p 2-9

    Article  ADS  Google Scholar 

  4. H.J. Chang, W. Yook, E.S. Park, J.S. Kyeong, and D.H. Kim, Synthesis of Metallic Glass Composites Using Phase Separation Phenomena, Acta Mater., 2010, 58, p 2483-2491

    Article  Google Scholar 

  5. Y. Yu, Y. Takaku, M. Nagasako, C.P. Wang, X.J. Liu, R. Kainuma, and K. Ishida, Liquid-Immiscibility-Induced Formation of Micron-Scale Crystalline/Amorphous Composite Powder, Intermetallics, 2012, 25, p 95-100

    Article  Google Scholar 

  6. X.J. Liu, J.H. Zhu, S.Y. Yang, W.W. Xu, and C.P. Wang, Formation of Cu-Rich Crystalline/NiNb-Rich Amorphous Composite Induced by Liquid Phase Separation, Mater. Lett., 2014, 116, p 328-331

    Article  Google Scholar 

  7. A. Inoue, B.L. Shen, H. Koshiba, H. Kato, and A.R. Yavari, Cobalt-Based Bulk Glassy Alloy with Ultrahigh Strength and Soft Magnetic Properties, Nat. Mater., 2003, 2, p 661-663

    Article  ADS  Google Scholar 

  8. A. Inoue, B.L. Shen, H. Koshiba, H. Kato, and A.R. Yavari, Ultra-High Strength Above 5000 MPa and Soft Magnetic Properties of Co-Fe-Ta-B Bulk Glassy Alloys, Acta Mater., 2004, 52, p 1631-1637

    Article  Google Scholar 

  9. Z.Z. Yuan, B.X. Wang, Y.D. Tong, and X.D. Chen, Effect of Annealing on the Kinetics of Glass Transition and Crystallization in Co-Fe-Ta-B Amorphous Alloy, J. Alloys Compd., 2007, 429, p 104-110

    Article  Google Scholar 

  10. P.R. Subramanian and D.E. Laughlin, The Cu-Ta (Copper-Tantalum) System, Bull. Alloy Phase Diagr., 1989, 10, p 652-655

    Article  Google Scholar 

  11. P.R. Subramanian, D.J. Chakrabarti, and D.E. Laughlin, Phase Diagrams of Binary Copper Alloys, ASM International, Materials Park, OH, 1994

    Google Scholar 

  12. J.D. Verhoeven, F.A. Schmidt, E.D. Gibson, and W.A. Spitzig, Copper-Refractory Metal Alloys, J. Met., 1986, 38, p 20-24

    Google Scholar 

  13. H. Okamoto, Reevaluation of Thermodynamic Models for Phase Diagram Evaluation, J. Phase Equilib., 1991, 12, p 623-643

    Article  Google Scholar 

  14. A.T. Dinsdale, SGTE data for pure elements, CALPHAD, 1991, 15, p 317-425

    Article  Google Scholar 

  15. O. Redlich and A.T. Kister, Algebraic Representation of Thermodynamic Properties and the Classification of Solutions, Ind. Eng. Chem., 1948, 40, p 345-348

    Article  Google Scholar 

  16. M. Hillert and M. Jarl, A Model for Alloying in Ferromagnetic Metals, CALPHAD, 1978, 2, p 227-238

    Article  Google Scholar 

  17. A. Takeuchi and A. Inoue, Classification of Bulk Metallic Glasses by Atomic Size Difference, Heat of Mixing and Period of Constituent Elements and Its Application to Characterization of the Main Alloying Element, Mater. Trans., 2005, 46, p 2817-2829

    Article  Google Scholar 

  18. Q. Chen and Z. Jin, The Fe-Cu System: A Thermodynamic Evaluation, Metall. Mater. Trans. A, 1995, 26, p 417-426

    Article  Google Scholar 

  19. V.T. Witusiewicz, A.A. Bondar, U. Hecht, V.M. Voblikov, O.S. Fomichov, V.M. Petyukh, and S. Rex, Experimental Study and Thermodynamic Re-Assessment of the Binary Fe-Ta System, Intermetallics, 2011, 19, p 1059-1075

    Article  Google Scholar 

  20. C.P. Wang, X.J. Liu, I. Ohnuma, R. Kainuma, and K. Ishida, Phase Equilibria in Fe-Cu-X (X: Co, Cr, Si, V) Ternary System, J. Phase Equilib., 2002, 23, p 236-245

    Article  Google Scholar 

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (Grant Nos. 51031003 and 51171159), the Ministry of Education of China (Grant Nos. 20120120130004) and the National Key Basic Research Program of China (973 Program) (No. 2012CB825700). The supports from the China Aviation Industry Group are also acknowledged.

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Correspondence to Cuiping Wang.

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Liu, X., Huang, W., Guo, Y. et al. Experimental Investigation and Thermodynamic Calculation of the Phase Equilibria in the Cu-Fe-Ta System. J. Phase Equilib. Diffus. 36, 28–38 (2015). https://doi.org/10.1007/s11669-014-0349-z

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  • DOI: https://doi.org/10.1007/s11669-014-0349-z

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