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Palladium supported on triphenylphosphine-functionalized porous organic polymer: an efficient heterogeneous catalyst for aminocarbonylation

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Abstract

An efficient route for the catalytic synthesis of aryl amides via the aminocarbonylation of aryl iodides with amines is described using palladium supported on triphenylphosphine-functionalized porous organic polymer (Pd@KAPs(Ph-PPh3)) as the catalyst. Under low carbon monoxide pressure, the catalyst exhibited remarkable activity, and only 0.5 mol% palladium loading was required to achieve moderate to excellent yields (70–97 %) of aryl amides. The catalyst can be easily separated by a simple filtration process and recycled up to seven times with only minor loss of activity. The salient features of this protocol are the simplicity in handling of catalyst, low CO pressure, good functional group tolerance, high catalytic activity, negligible palladium leaching and effective catalyst recyclability.

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Acknowledgments

This work is partly supported financially by the 863 Program of Ministry of Science and Technology of China (NC2010 MA0137). The authors thank for financial support from the National Natural Science Foundation of China (51504134), Guizhou “125 Plan” Key Project of Science and Technology Project [Qian jiao he zhong da zhuang xiang zi (2013) 026] and Liupanshui normal university creative team (LPSSYKJTD201401).

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Authors and Affiliations

  1. Department of Chemistry and Chemical Engineering, Liupanshui Normal University, Liupanshui, 553004, Guizhou, People’s Republic of China

    Yizhu Lei & Kaiyi Shi

  2. School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Luoyu Road 1037, Wuhan, 430074, Hubei, People’s Republic of China

    Xuefeng Zhang, Yanlong Gu, Jianglin Hu & Guangxing Li

Authors
  1. Yizhu Lei
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  2. Xuefeng Zhang
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  3. Yanlong Gu
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  4. Jianglin Hu
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  5. Guangxing Li
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  6. Kaiyi Shi
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Corresponding authors

Correspondence to Yizhu Lei or Guangxing Li.

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Lei, Y., Zhang, X., Gu, Y. et al. Palladium supported on triphenylphosphine-functionalized porous organic polymer: an efficient heterogeneous catalyst for aminocarbonylation. Transition Met Chem 41, 1–7 (2016). https://doi.org/10.1007/s11243-015-9990-6

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  • DOI: https://doi.org/10.1007/s11243-015-9990-6

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