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Investigation of the catalytic behavior of a Cu coordination polymer capped polyoxometalate as an oxidation catalyst

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Abstract

A multifunctional organic–inorganic hybrid based on a Cu coordination polymer capped polyoxometalate (H3PMo12O40) designated as compound 1 with [CuI(4,4′-bipy)]3[PMo VI10 Mo V2 O40{CuII(2,2′-bipy)}] formula was prepared using CuCl2·2H2O, 4,4′-bipy, 2,2′-bipy and H3PMo12O4 in water under hydrothemal conditions. The prepared compound 1 was characterized by FTIR, XRD and chemical analysis techniques. It was found that the compound successfully catalyzes the epoxidation of various alkenes such as diphenyl ethylene, trans-stilbene, cyclohexene, norbornene, styrene and cyclooctene and oxidation of alkanes such as fluorene, adamantane, diphenylmethane, cyclohexane and cyclooctane, in acetonitrile with 20–99 % conversion and 53–100 % selectivity with tert-butyl hydroperoxide as oxidant under optimized condition. This heterogeneous catalyst could be easily recovered and reused after reaction without loss of activity.

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References

  1. Mizuno N, Kamata K (2011) Coord Chem Rev 255:2358–2370

    Article  CAS  Google Scholar 

  2. Pathare SP, Akamanchi KG (2013) Tetrahedron Lett 54:6455–6459

    Article  CAS  Google Scholar 

  3. Brocas A-L, Mantzaridis Ch, Tunc D, Carlotti S (2013) Prog Polym Sci 38:845–873

    Article  CAS  Google Scholar 

  4. Mirkhani V, Moghadam M, Tangestaninejad S, Mohammadpoor-Baltork I, Rasouli N (2008) Catal Commun 9:2411–2416

    Article  CAS  Google Scholar 

  5. Zamanifar E, Farzaneh F (2011) Reac Kinet Mech Cat 104:197–209

    Article  CAS  Google Scholar 

  6. Conte V, Floris B (2010) Inorg Chim Acta 363:1935–1946

    Article  CAS  Google Scholar 

  7. Maksimchuk NV, Timofeeva MN, Melgunov MS, Shmakov AN, Chesalov YA, Dybtsev DN, Fedin VP, Kholdeeva OA (2008) J Catal 257:315–323

    Article  CAS  Google Scholar 

  8. Salavati-Niasari M, Banitaba SH (2003) J Mol Catal A 201:43–54

    Article  CAS  Google Scholar 

  9. Ayala V, Corma A, Iglesiasc M, Sanchez F (2004) J Mol Catal A 221:201–208

    CAS  Google Scholar 

  10. Keggin JF (1933) Nature 131:908

    Article  CAS  Google Scholar 

  11. Zhang Z, Zhang F, Zhu Q, Zhao W, Ma B, Ding Y (2011) J Colloid Interface Sci 360:189–194

    Article  CAS  Google Scholar 

  12. Zhao S, Jia Y, Song YF (2013) Appl Catal A 453:188–194

    Article  CAS  Google Scholar 

  13. Jahier C, Mal SS, Al-Oweini R, Kortz U, Nlate S (2013) Polyhedron 57:57–63

    Article  CAS  Google Scholar 

  14. Karimi Z, Mahjoub AR (2011) Catal Commun 12:984–988

    Article  CAS  Google Scholar 

  15. Sousa JLC, Santos ICMS, Simões MMQ, Cavaleiro JAS, Nogueira HIS, Cavaleiro AMV (2011) Catal Commun 12:459–463

    Article  CAS  Google Scholar 

  16. Rafiee E, Eavani S (2013) J Mol Catal A 380:18–27

    Article  CAS  Google Scholar 

  17. Balula SS, Santos ICMS, Cunha-Silva L, Carvalho AP, Pires J, Freire C, Cavaleiro JAS, de Castro B, Cavaleiro AMV (2013) Catal Today 203:95–102

    Article  CAS  Google Scholar 

  18. Hill CL, Prosser-McCartha CM (1995) Coord Chem Rev 143:407–455

    Article  CAS  Google Scholar 

  19. Karimi Z, Mahjoub AR, Harati SM (2011) Inorg Chim Acta 376:1–9

    Article  CAS  Google Scholar 

  20. Kozhevnikov IV (1995) Catal Rev Sci Eng 37:311

    Article  CAS  Google Scholar 

  21. Zhang Ch-X, Chen Y-G, Tang Q, Zhang Z-C, Liu D-D, Meng H-X (2012) Inorg Chem Commun 17:155–158

    Article  CAS  Google Scholar 

  22. Semerci F, Yes-ilel OZ, Soylu MS, Keskin S, Büyükgüngor O (2013) Polyhedron 50:314–320

    Article  CAS  Google Scholar 

  23. Almeida FB, de Silva FH, Yoshida MI, de Abreu HA, Diniz R (2013) Inorg Chim Acta 402:60–68

    Article  Google Scholar 

  24. Tasaki-Handa Y, Abe Y, Ooi K, Tanaka M, Wakisaka A (2014) J Colloid Interface Sci 413:65–70

    Article  CAS  Google Scholar 

  25. Li C-P, Guo J, Du M (2013) Inorg Chem Commun 38:70–73

    Article  Google Scholar 

  26. Kirillov AM, Kirillova MV, Pombeiro AJL (2012) Coord Chem Rev 256(2012):2741–2759

    Article  CAS  Google Scholar 

  27. Zhenga Y-Z, Zhenga Z, Chen X-M (2014) Coord Chem Rev 258–259:1–15

    Article  Google Scholar 

  28. Ho M-L, Wang J-Ch, Wang T-Y, Lin C-Y, Zhu JF, Chen Y-A, Chen T-C (2014) Sens Actuators B 190:479–485

    Article  CAS  Google Scholar 

  29. Song YJ, Wak HK, Lee YM, Kim SH, Lee SH, Park BK, Jun JY, Yu SM, Kim C, Kim S-J, Kim Y (2009) Polyhedron 28:1241–1252

    Article  CAS  Google Scholar 

  30. Férey G, Mellot-Draznieks C, Serre C, Millange F, Dutour J, Surble S, Margiolaki I (2005) Science 309:2040

    Article  Google Scholar 

  31. Jin H, Qi Y, Wang E, Li Y, Wang X, Qin C, Chang S (2006) Cryst Growth Des 6:2693–2698

    Article  CAS  Google Scholar 

  32. Bar-Nahum I, Cohen H, Neumann R (2003) Inorg Chem 42:3677–3684

    Article  CAS  Google Scholar 

  33. Bar-Nahum I, Narasimhulu KV, Neumann R (2005) Inorg Chem 44:4900–4902

    Article  CAS  Google Scholar 

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Acknowledgments

Financial support from the Alzahra University is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Alzahra University, Vanak, Tehran, Iran

    Faezeh Farzaneh & Faezeh Moghzi

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  1. Faezeh Farzaneh
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  2. Faezeh Moghzi
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Correspondence to Faezeh Farzaneh.

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Farzaneh, F., Moghzi, F. Investigation of the catalytic behavior of a Cu coordination polymer capped polyoxometalate as an oxidation catalyst. Reac Kinet Mech Cat 115, 175–185 (2015). https://doi.org/10.1007/s11144-015-0834-3

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  • DOI: https://doi.org/10.1007/s11144-015-0834-3

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