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Generalized Jarzynski’s Equality of Inhomogeneous Multidimensional Diffusion Processes

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Abstract

Applying the well-known Feynman-Kac formula of inhomogeneous case, an interesting and rigorous mathematical proof of generalized Jarzynski’s equality of inhomogeneous multidimensional diffusion processes is presented, followed by an extension of the second law of thermodynamics. Then, we explain its physical meaning and applications, extending Hummer and Szabo’s work (Proc. Natl. Acad. Sci. USA 98(7):3658–3661, [2001]) and Hatano-Sasa equality of steady state thermodynamics (Phys. Rev. Lett. 86:3463–3466, [2001]) to the general multidimensional case.

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References

  1. Baiesi, M., Jacobs, T., Maes, C., Skantzos, N.S.: Fluctuation symmetries for work and heat. Phys. Rev. E 74, 021111 (2006)

    Article  ADS  Google Scholar 

  2. Crooks, G.E.: Nonequilibrium measurements of free energy differences for microscopically reversible Markovian systems. J. Stat. Phys. 90, 1481–1487 (1998)

    Article  MATH  MathSciNet  Google Scholar 

  3. Crooks, G.E.: Entropy production fluctuation theorem and the nonequilibrium work relation for free energy differences. Phys. Rev. E 60, 2721–2726 (1999)

    Article  ADS  Google Scholar 

  4. Crooks, G.E.: Path-ensemble averages in systems driven far from equilibrium. Phys. Rev. E 61(3), 2361–2366 (2000)

    Article  ADS  Google Scholar 

  5. Dynkin, E.B.: Die Grundlagen der Theorie der Markoffschen Prozesse. Springer, Berlin (1961)

    MATH  Google Scholar 

  6. Dynkin, E.B.: Markov Processes, vols. 1, 2. Springer, Berlin (1965)

    Google Scholar 

  7. Friedman, A.: Partial Differential Equations of Parabolic Type. Englewood Cliffs (1964)

  8. Ge, H., Qian, M.: Generalized Jarzynski’s equality in inhomogeneous Markov chains. J. Math. Phys. 48, 053302 (2007)

    Article  ADS  MathSciNet  Google Scholar 

  9. Ge, H., Jiang, D.Q., Qian, M.: A simple discrete model of Brownian motors: time-periodic Markov chains. J. Stat. Phys. 123(4), 831–859 (2006)

    Article  MATH  ADS  MathSciNet  Google Scholar 

  10. Ge, H., Jiang, D.Q., Qian, M.: Reversibility and entropy production of inhomogeneous Markov chains. J. Appl. Probab. 43(4), 1028–1043 (2006)

    Article  MATH  MathSciNet  Google Scholar 

  11. Glansdorff, P., Prigogine, I.: Thermodynamic Theory of Structure, Stability and Fluctuations. Wiley–Interscience, London (1971)

    MATH  Google Scholar 

  12. Haken, H.: Synergetics: An Introduction: Nonequilibrium Phase Transitions and Self-Organization in Physics, Chemistry, and Biology. Springer, Berlin (1977)

    MATH  Google Scholar 

  13. Haken, H.: Advanced Synergetics: Instability Hierarchies of Self-Organizing Systems and Devices. Springer, Berlin (1983)

    MATH  Google Scholar 

  14. Has’minskii, R.Z.: Stochastic Stability of Differential Equations. Sijthoff and Noorrdhoff, Alphen aan den Rijn-Germantown (1980)

    Google Scholar 

  15. Hatano, T., Sasa, S.: Steady-states thermodynamics of Langevin systems. Phys. Rev. Lett. 86, 3463–3466 (2001)

    Article  ADS  Google Scholar 

  16. Hill, T.L.: Studies in irreversible thermodynamics IV. Diagrammatic representation of steady state fluxes for unimolecular systems. J. Theor. Biol. 10, 442–459 (1966)

    Article  Google Scholar 

  17. Hill, T.L.: Free Energy Transduction in Biology. Academic, New York (1977)

    Google Scholar 

  18. Hill, T.L.: Free Energy Transduction and Biochemical Cycle Kinetics. Springer, New York (1995)

    Google Scholar 

  19. Hill, T., Chen, Y.: Stochastics of cycle completions (fluxes) in biochemical kinetic diagrams. Proc. Natl. Acad. Sci. USA 72, 1291–1295 (1975)

    Article  ADS  Google Scholar 

  20. Hummer, G., Szabo, A.: Free energy reconstruction from nonequilibrium single-molecule pulling experiments. Proc. Natl. Acad. Sci. USA 98(7), 3658–3661 (2001)

    Article  ADS  Google Scholar 

  21. Jarzynski, C.: Nonequilibrium equality for free energy differences. Phys. Rev. Lett. 78, 2690–2693 (1997)

    Article  ADS  Google Scholar 

  22. Jarzynski, C.: Equilibrium free-energy differences from nonequilibrium measurements: A master-equation approach. Phys. Rev. E 56, 5018–5035 (1997)

    Article  ADS  Google Scholar 

  23. Jarzynski, C.: Microscopic analysis of Clausius-Duhem processes. J. Stat. Phys. 96, 415–427 (1999)

    Article  MATH  Google Scholar 

  24. Jarzynski, C.: Hamiltonian derivation of a detailed fluctuation theorem. J. Stat. Phys. 98, 77–102 (2000)

    Article  MATH  MathSciNet  Google Scholar 

  25. Jiang, D.Q., Qian, M., Qian, M.P.: Mathematical Theory of Nonequilibrium Steady States—On the Frontier of Probability and Dynamical Systems. Lect. Notes Math., vol. 1833. Springer, Berlin (2004)

    MATH  Google Scholar 

  26. Keizer, J.: Statistical Thermodynamics of Nonequilibrium Processes. Springer, New York (1987)

    Google Scholar 

  27. Karatzas, I., Shreve, E.S.: Brownian Motion and Stochastic Calculus. Springer, New York (1988)

    MATH  Google Scholar 

  28. Lasota, A., Mackey, M.C.: Chaos, Fractals, and Noise: Stochastic Aspects of Dynamics. Springer, New York (1994)

    MATH  Google Scholar 

  29. Liphardt, J., Dumont, S., Smith, S.B., Tinoco, I., Bustamante, C.: Equilibrium information from nonequilibrium measurements in an experimental test of Jarzynski’s equality. Science 296, 1832–1835 (2002)

    Article  ADS  Google Scholar 

  30. Nicolis, G., Prigogine, I.: Self-Organization in Nonequilibrium Systems: From Dissipative Structures to Order through Fluctuations. Wiley, New York (1977)

    MATH  Google Scholar 

  31. Oono, Y., Paniconi, M.: Steady state thermodynamics. Prog. Theor. Phys. Suppl. 130, 29–44 (1998)

    Article  ADS  MathSciNet  Google Scholar 

  32. Qian, H.: Mathematical formalism for isothermal linear reversibility. Proc. R. Soc. Lond. Ser. A 457, 1645–1655 (2001)

    Article  MATH  ADS  Google Scholar 

  33. Qian, H.: Cycle kinetics, steady state thermodynamics and motors-a paradigm for living matter physics. J. Phys. Condens. Matter 17, S3783–S3794 (2005)

    Article  ADS  Google Scholar 

  34. Qian, M.P., Qian, M.: Circulation for recurrent Markov chains. Z. Wahrsch. Verw. Geb. 59, 203–210 (1982)

    Article  MATH  Google Scholar 

  35. Qian, M.P., Qian, M.: The entropy production and reversibility of Markov processes. Sci. Bull. 30(3), 165–167 (1985)

    Google Scholar 

  36. Qian, M.P., Qian, C., Qian, M.: Circulations of Markov chains with continuous time and the probability interpretation of some determinants. Sci. Sin. (Ser. A) 27(5), 470–481 (1984)

    MATH  Google Scholar 

  37. Qian, M.P., Qian, M., Gong, G.L.: The reversibility and the entropy production of Markov processes. Contemp. Math. 118, 255–261 (1991)

    MathSciNet  Google Scholar 

  38. Sekimoto, K.: Kinetic characterization of heat bath and the energetics of thermal ratchet models. J. Phys. Soc. Jpn. 66, 1234–1237 (1997)

    Article  ADS  Google Scholar 

  39. Strook, D.W., Varadhan, S.R.S.: Multidimensional Diffusion Processes. Springer, Berlin (1979)

    Google Scholar 

  40. van Zon, R., Cohen, E.G.D.: Stationary and transient work-fluctuation theorems for a dragged Brownian particle. Phys. Rev. E 67, 046102 (2003)

    Article  ADS  Google Scholar 

  41. van Zon, R., Cohen, E.G.D.: Extension of the fluctuation theorem. Phys. Rev. Lett. 91, 110601 (2003)

    Article  Google Scholar 

  42. van Zon, R., Cohen, E.G.D.: Extended heat-fluctuation theorems for a system with deterministic and stochastic forces. Phys. Rev. E 69, 056121 (2004)

    Article  ADS  Google Scholar 

  43. Zhang, Z.S.: Mathematical Analysis, vols. 1, 2, 3. Peking University Press (1991) (in Chinese)

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Ge, H., Jiang, DQ. Generalized Jarzynski’s Equality of Inhomogeneous Multidimensional Diffusion Processes. J Stat Phys 131, 675–689 (2008). https://doi.org/10.1007/s10955-008-9520-4

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