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Synthesis and Characterization of Pure Phase Zn(II) and Cd(II) Oxide Nanoparticles via Thermal Decomposition of Four New Zn(II) and Cd(II) Coordination Polymers

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Abstract

Four new Zn(II) and Cd(II) coordination polymers, [Zn(2-AMP)2(N3)2]n (1), [Zn(2-AMP)2(SCN)2]n (2), [Cd(2-AMP)(N3)2]n (3) and [Cd(2-AMP)2(SCN)2]n (4) {2-AMP: 2-Aminomethylpyridine}, have been synthesized and characterized by single crystal X-ray diffraction, IR spectroscopy and elemental analyses. The Zinc(II) oxide and Cadmium(II) oxide nano-particles have been synthesized from thermolysis of 1–4 at 600 °C under air atmosphere for 4 h. The ZnO and CdO nanoparticles were characterized by X-ray diffraction and scanning electron microscopy (SEM). SEM images show the average size of produced ZnO and CdO nanoparticles are 60–70 nm in all compounds.

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References

  1. A. Morsali, M.Y. Masoumi, Coord. Chem. Rev. 253, 1882 (2009)

    Article  CAS  Google Scholar 

  2. G.K.H. Shimizu, G.D. Enright, C.I. Ratcliffe, K.F. Preston, J.L. Reid, J.A. Ripmeester, Chem. Commun. 1485, 82 (1999)

    Google Scholar 

  3. B. Moulton, M.J. Zawartko, Chem. Rev. 101, 1629 (2001)

    Article  CAS  Google Scholar 

  4. R. Kitaura, K. Fujimoto, S. Noro, M. Kondo, S. Kitagawa, Angew. Chem. Int. Ed. 41, 133 (2002)

    Article  CAS  Google Scholar 

  5. M. Oh, C.A. Mirkin, Nature 438, 651 (2005)

    Article  CAS  Google Scholar 

  6. G. Mahmoudi, A. Morsali, A.D. Hunter, M. Zeller, CrystEngComm 9, 704 (2007)

    Article  CAS  Google Scholar 

  7. S.R. Batten, S.M. Neville, D.R. Turner, Coordination polymer: design, analysis and application, Illustrated edn. (Royal Society of Chemistry, Science Park Cambridge, 2009)

    Google Scholar 

  8. A.Y. Robin, K.M. Fromm, Coord. Chem. Rev. 250, 2127 (2006)

    Article  CAS  Google Scholar 

  9. A. Aslani, A. Morsali, M. Zeller, Dalton Trans. 38, 5173 (2008)

    Article  Google Scholar 

  10. J. Zhou, Y.Z. Yuan, X. Liu, D.Q. Li, Z. Zhou, Z.-F. Chen, K.-B. Yu, J. Coord. Chem. 59, 1477 (2006)

    Article  CAS  Google Scholar 

  11. H.T. Shi, L.M. Qi, J.M. Ma, H.M. Cheng, J. Am. Chem. Soc. 125, 3450 (2003)

    Article  CAS  Google Scholar 

  12. H. Zhang, D.R. Yang, D.S. Li, X.Y. Ma, S.Z. Li, D.L. Que, Cryst. Growth Des. 5, 547 (2005)

    Article  CAS  Google Scholar 

  13. D.B. Kuang, A.W. Xu, Y.P. Fang, H.Q. Liu, C. Frommen, D. Fenske, Adv. Mater. 15, 1747 (2003)

    Article  CAS  Google Scholar 

  14. L. Hashemi, A. Morsali, Ultrason. Sonochem. 24, 146 (2015)

    Article  CAS  Google Scholar 

  15. A. Ennaoui, M. Weber, R. Scheer, H.J. Lewerenz, Sol. Energy Mater. Sol. Cells 54, 277 (1998)

    Article  CAS  Google Scholar 

  16. J. Liqiang, W. Baiq, X. Baifu, L. Shudan, S. Keying, C. Weimin, F. Honggang, J. Solid State Chem. 177, 4221 (2004)

    Article  Google Scholar 

  17. V.R. Shinde, T.P. Gujar, C.D. Lokhande, Sens. Actuators B 120, 551 (2007)

    Article  CAS  Google Scholar 

  18. S.K.N. Ayudhya, P. Tonto, O. Mekasuwandumrong, V. Pavarajarn, P. Praserthdam, Cryst. Growth Des. 6, 2446 (2006)

    Article  CAS  Google Scholar 

  19. M. Vafaee, M.S. Ghamsari, Mater. Lett. 61, 3265 (2007)

    Article  CAS  Google Scholar 

  20. Y.S. Kim, W.P. Tai, S.J. Shu, Thin Solid Films 491, 153 (2005)

    Article  CAS  Google Scholar 

  21. J.Z. Liu, P.X. Yan, G.H. Yue, L.B. Kong, R.F. Zhuo, Mater. Lett. 60, 3471 (2006)

    Article  CAS  Google Scholar 

  22. Y. He, J. Wang, Mater. Lett. 62, 1379 (2008)

    Article  CAS  Google Scholar 

  23. P.X. Gao, Z.L. Wang, Appl. Phys. Lett. 84, 2883 (2004)

    Article  CAS  Google Scholar 

  24. L. Vayssieres, Adv. Mater. 15, 464 (2003)

    Article  CAS  Google Scholar 

  25. C.H. Liu, J.A. Zapien, Y. Yao, X.M. Meng, C.S. Lee, S.S. Fan, Y. Lifshitz, S.T. Lee, Adv. Mater. 15, 838 (2003)

    Article  CAS  Google Scholar 

  26. H. Zhang, X.Y. Ma, J. Xu, J. Niu, D. Yang, Nanotechnology 14(4), 423 (2003)

    Article  CAS  Google Scholar 

  27. F. Bigdeli, A. Morsali, Mater. Lett. 64, 4 (2010)

    Article  CAS  Google Scholar 

  28. R. Jayakrishnan, G. Hodes, Thin Solid Films 440, 19 (2003)

    Article  CAS  Google Scholar 

  29. M. Ristic, S. Poporic, S. Music, Mater. Lett. 58, 2494 (2004)

    Article  CAS  Google Scholar 

  30. L.J. Farrugia, Ortep-3 for Windows. J. Appl. Cryst. 30, 565 (1997)

    Article  CAS  Google Scholar 

  31. Mercury 1.4.1, Copyright Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge, CB2 1EZ, UK, 2001–2005

  32. N.K. Karan, K.-T. Chan, H.M. Lee, Acta Crystallogr. Sect. E 65, m525 (2009)

    Article  CAS  Google Scholar 

  33. M. Shukla, N. Srivastava, S. Saha, T.R. Rao, S. Sunkari, Polyhedron 30, 754 (2011)

    Article  CAS  Google Scholar 

  34. F. Marandi, L. Hashemi, A. Morsali, H. Krautscheid, Ultrason. Sonochem. 32, 86 (2016)

    Article  CAS  Google Scholar 

  35. M.Y. Masoomi, A. Morsali, Ultrason. Sonochem. 28, 240 (2016)

    Article  CAS  Google Scholar 

  36. L. Hashemi, A. Morsali, P. Retailleau, Inorg. Chim. Acta 367, 207 (2011)

    Article  CAS  Google Scholar 

  37. F. Molaei, F. Bigdeli, A. Morsali, J. Ind. Eng. Chem. 24, 229 (2015)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

Support of this investigation by Tarbiat Modares University and Payame Noor University, are gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Payame Noor University, Tehran, 19395-4697, Islamic Republic of Iran

    Farzin Marandi

  2. Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14155-4838, Tehran, Islamic Republic of Iran

    Lida Hashemi & Ali Morsali

  3. Institut für Anorganische Chemie, Universität Leipzig, Johannisallee 29, 04103, Leipzig, Germany

    Harald Krautscheid

Authors
  1. Farzin Marandi
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  2. Lida Hashemi
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  3. Ali Morsali
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  4. Harald Krautscheid
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Correspondence to Farzin Marandi or Ali Morsali.

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Marandi, F., Hashemi, L., Morsali, A. et al. Synthesis and Characterization of Pure Phase Zn(II) and Cd(II) Oxide Nanoparticles via Thermal Decomposition of Four New Zn(II) and Cd(II) Coordination Polymers. J Inorg Organomet Polym 26, 962–974 (2016). https://doi.org/10.1007/s10904-016-0403-x

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  • DOI: https://doi.org/10.1007/s10904-016-0403-x

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