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Decavanadate Cage-like Cluster Templated by Organic Counter Cation: Synthesis, Characterization and Its Antimicrobial Effect Against Gram Positive E. Feacium

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Abstract

Decavanadate cluster templated with organic cation, [4-(CH3O)C6H4CH2NH3]6V10O28·2H2O (4MBAV10) has been prepared and characterized by elemental analysis, X-ray diffraction and IR., UV–Vis., fluorescence and 1H, 13C-NMR spectroscopies. The X-ray structure determination revealed the discrete decavanadate cage-like clusters [V10O28]6− (V10). These polymeric species associated to lattice water results into inorganic 2D-framework \( \left[ {{\text{V}}_{ 10} {\text{O}}_{ 2 8} \left( {{\text{H}}_{ 2} {\text{O}}} \right)_{ 4} } \right]_{\text{n}}^{6 - } \) stacked parallel to the (a,b) plane where the templating cations filled the interlayer spacing to perform 3D supramolecular network supported by a set of O–H···O, N–H···O, C–H···O and C–H···π interactions as well as electrostatic ones. The optical survey of 4MBAV10 has been used to determine the optical band gap and to provide the blue fluorescent behavior of grown crystals. Furthermore, antibacterial activity was tested and showed that the compound exhibited a reasonable activity against gramm positif Enterococcus feacium.

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Authors and Affiliations

  1. Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, Université de Carthage, 7021 Zarzouna, Bizerte, Tunisia

    Sirine Toumi & Samah Akriche

  2. CEMES-CNRS, 29 rue Jeanne Marvig, 31055, Toulouse Cedex 4, France

    Nicolas Ratel-Ramond

Authors
  1. Sirine Toumi
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  2. Nicolas Ratel-Ramond
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  3. Samah Akriche
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Correspondence to Samah Akriche.

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Toumi, S., Ratel-Ramond, N. & Akriche, S. Decavanadate Cage-like Cluster Templated by Organic Counter Cation: Synthesis, Characterization and Its Antimicrobial Effect Against Gram Positive E. Feacium . J Clust Sci 26, 1821–1831 (2015). https://doi.org/10.1007/s10876-015-0881-y

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