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Synthesis, Infrared Spectroscopy and Crystal Structure Determination of a New Decavanadate

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Abstract

Synthesis, infrared spectroscopy and crystal structure of a new potassium decavanadate decahydrate, K6[V10O28]·10H2O, has been reported. The infrared spectrum is dominated by decavanadate polyanion and water bands. The X-ray crystallography analysis found the compound crystallizes in a triclinic system with the parameters a = 10.5334 (4) Å, b = 10.6600 (4) Å, c = 17.7351 (5) Å; α = 76.940 (2)°, β = 75.836 (2)°, γ = 64.776 (2)°; V = 1,729.86 (11) Å3; Z = 2, space group \( P\overline{1} \). The polyanion consists of ten [VO6] octahedra sharing edges, in which the V–O distances are in good agreement with those reported for other decavanadates. The crystal structure is stabilized by potassium cations and water molecules forming a complex pattern of hydrogen bonding and short contact ionic interactions.

Graphical Abstract

Synthesis, infrared spectroscopy and crystal structure of a new potassium decavanadate decahydrate, K6[V10O28]·10H2O are described. The infrared spectrum is dominated by decavanadate polyanion and water bands. The crystal structure shows a complex pattern composed by hydrogen bonds and short contacts between potassium cations and water molecules.

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Acknowledgments

The authors thank to Professor Eduardo E. Castellano for the useful discussions. Financial support: Capes, CNPq and FAPESP (Brazilian agencies). RSC acknowledges CNPq for fellowship.

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Authors and Affiliations

  1. Instituto de Química de Araraquara, Universidade Estadual Paulista, Araraquara, SP, Brazil

    Luciana Rebelo Guilherme, Antônio Carlos Massabni & Alessandra Cristina Dametto

  2. Instituto de Física de São Carlos, Universidade de São Paulo, São Carlos, SP, Brazil

    Rodrigo de Souza Corrêa & Alexandre Suman de Araujo

Authors
  1. Luciana Rebelo Guilherme
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  2. Antônio Carlos Massabni
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  3. Alessandra Cristina Dametto
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  4. Rodrigo de Souza Corrêa
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  5. Alexandre Suman de Araujo
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Correspondence to Alexandre Suman de Araujo.

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Guilherme, L.R., Massabni, A.C., Dametto, A.C. et al. Synthesis, Infrared Spectroscopy and Crystal Structure Determination of a New Decavanadate. J Chem Crystallogr 40, 897–901 (2010). https://doi.org/10.1007/s10870-010-9759-x

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  • DOI: https://doi.org/10.1007/s10870-010-9759-x

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