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Deposition of Ag doped TiO2 on cotton fabric for wash durable UV protective and antibacterial properties at very low silver concentration

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Abstract

Cotton fabric with wash durable UV protective and effective antibacterial properties was developed in this work. In this work, TiO2 was deposited on cotton fabric by a sol gel process using titanium tetra iso-propoxide as the precursor. In the initial stage of its deposition, TiO2 is amorphous in nature which has to be given a prolonged hydrothermal treatment for development of anatase crystalline form and enhanced catalytic activity. As a novelty, a small amount of silver precursor was added during the hydrothermal stage. It was found that TiO2 was doped with silver during hydrothermal stage with very low silver concentration. The concentration of silver was low enough (<100 ppm) not to cause any change in the color of cotton fabric but high enough to develop strong antibacterial character in cotton both against Staphylococcus aureus and Eschrichia coli. The presence of TiO2 ensured good UV protection (UPF > 60). However, the UPF increased dramatically when TiO2 was doped with silver.

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References

  • Akhavan O, Ghaderi E (2010) Self-accumulated Ag nanoparticles on mesoporous TiO2 thin film with high bactericidal activities. Surf Coat Technol 204:3676–3683

    Article  CAS  Google Scholar 

  • Albert E, Albouy PA, Ayral A, Basa P, Csík G, Nagy N, Roualdès S, Rouessac V, Sáfrán G, Suhajda A, Zolnai Z, Hórvölgy Z (2015) Antibacterial properties of Ag–TiO2 composite Sol–gel coatings. RSC Adv 5:59070–59081

    Article  CAS  Google Scholar 

  • Ansari SA, Khan MM, Ansari MO, Cho MH (2015) Silver nanoparticles and defect-induced visible light photocatalytic and photoelectrochemical performance of Ag@m-TiO2 nanocomposite. Sol Energy Mater Sol Cells 141:162–170

    Article  CAS  Google Scholar 

  • Bokare A, Sanap A, Pai M, Sabharwal S, Athawale AA (2013) Antibacterial activities of Nd doped and Ag coated TiO2 nanoparticles under solar light irradiation. Coll Surf B Biointerfaces 102:273–280

    Article  CAS  Google Scholar 

  • Chauhan I, Mohanty P (2015) In situ decoloration of TiO2 nanoparticles on the surface of cellulose fibers and study of their photocatalytic and antibacterial activities. Cellulose 22:507–519

    Article  CAS  Google Scholar 

  • Chauhan I, Aggrawal S, Mohanty P (2015) ZnO nanowire-immobilized paper matrices for visible light-induced antibacterial activity against Escherichia Coli. Environ Sci Nano 2:273–279

    Article  CAS  Google Scholar 

  • Davis S, Capjack L, Kerr N, Fedosejevs R (1997) Clothing as protection from ultraviolet radiation: which fabric is most effective. Int J Dermatol 36:374–379

    Article  CAS  Google Scholar 

  • Deng ZY, Wang W, Mao LH, Wang CF, Chen S (2014) Versatile superhydrophobic and photocatalytic films generated from TiO2–SiO2@PDMS and their applications on fabrics. J Mater Chem A 2:4178–4184

    Article  CAS  Google Scholar 

  • Gambichler T, Hatch KL, Hoffmann K (2002) UV protection factor of fabrics: comparison of laboratory and field-based measurements. Photodermatol Photoimmunol Photomed 18:135–140

    Article  Google Scholar 

  • Gil EM, Kim TH (2000) UV-induced immune suppression and sunscreen. Photodermatol Photoimmunol Photomed 16:101–110

    Article  CAS  Google Scholar 

  • Gorjanc M, Sala M (2016) Durable antibacterial and UV protective properties of cellulose fabric functionalized with Ag/TiO2 nanocomposite during dyeing with reactive dyes. Cellulose 23:2199–2209

    Article  CAS  Google Scholar 

  • Gouda M, Aljaafari AI (2012) Augmentation of multifunctional properties of cellulosic cotton fabric using titanium dioxide nanoparticles. Adv Nanoparticles 1:29–36

    Article  CAS  Google Scholar 

  • Hebeish AA, Abdelhady MM, Youssef AM (2013) TiO2 nanowire and TiO2 nanowire doped Ag-PVP nanocomposite for antimicrobial and self-cleaning cotton textile. Carbohydr Polym 91:549–559

    Article  CAS  Google Scholar 

  • Hoffmann K, Kaspar K, Gambichler T, Altmeyer P (2000) In vitro and in vivo determination of the uv protection factor for lightweight cotton and viscose summer fabrics: a preliminary study. J Am Acad Dermatol 43:1009–1016

    Article  CAS  Google Scholar 

  • Huang JY, Li SH, Ge MZ, Wang LN, Xing TL, Chen GQ, Liu XF, Al-Deyab SS, Zhang KQ, Chen T, Lai YK (2015) Robust superhydrophobic TiO2@fabrics for UV shielding, self-cleaning and oil–water separation. J Mater Chem A 3:2825–2832

    Article  CAS  Google Scholar 

  • Jaiswal S, Duffy B, McHale P (2012) Preparation and rapid analysis of antibacterial silver, copper and zinc doped sol gel surfaces. J Coll Surf B Biointerfaces 94:170–176

    Article  CAS  Google Scholar 

  • Karimi L, Yazdanshenas ME, Khajavi R, Rashidi A, Mirjalili M (2014) Using graphene/TiO2 nanocomposite as a new route for preparation of electroconductive, self-cleaning, antibacterial and antifungal cotton fabric without toxicity. Cellulose 21:3813–3827

    Article  CAS  Google Scholar 

  • Kequinq H, Muhuo Y (2006) Study of the preparation and properties of UV-blocking fabrics of a PET/TiO2 nano composite prepared by in situ polycondensation. J Appl Polym Sci 100:1588–1594

    Article  Google Scholar 

  • Khalilabad MS, Yazdanshenas ME (2013) Fabrication of superhydrophobic, antibacterial and ultraviolet-blocking cotton fabric. J Text I 104:861–869

    Article  Google Scholar 

  • Khalilabad MS, Yazdanshenas ME, Etemadifar A (2013) Fabricating multifunctional silver nanoparticles-coated cotton fabric. Arab J Chem. doi:10.1016/j.arabjc.2013.08.013

  • Kullavanijaya P, Lim HW (2005) Photoprotection. J Am Acad Dermatol 52:937–958

    Article  Google Scholar 

  • Lee HJ, Jeong SH (2005) Bacteriostasis and skin innoxiousness of nanosize silver colloids on textile fabrics. Text Res J 75:551–556

    Article  CAS  Google Scholar 

  • Li S, Huang J, Ge M, Cao C, Deng S, Zhang S, Chen G, Zhang K, Al-Deyab SS, Lai Y (2015) Robust flower-like TiO2@cotton fabrics with special wettability for effective self-cleaning and versatile oil/water separation. Adv Mater Interfaces 2:1500220

    Article  Google Scholar 

  • Li S, Huang J, Chen Z, Chen G, Lai Y (2017) A review on special wettability textiles: theoretical models, fabrication technologies and multifunctional applications. J Mater Chem A 5:31–55

    Article  CAS  Google Scholar 

  • Liu R, Wang P, Wang X, Yu H, Yu J (2012) UV- and visible-light photocatalytic activity of simultaneously deposited and doped Ag/Ag(I)–TiO2 photocatalyst. J Phys Chem C 116:17721–17728

    Article  CAS  Google Scholar 

  • Liu H, Gao SW, Cai JS, He CL, Mao JJ, Zhu TX, Chen Z, Huang JY, Meng K, Zhang KQ, Al-Deyab SS, Lai YK (2016) Recent progress in fabrication and applications of superhydrophobic coating on cellulose-based substrates. Materials 9:124

    Article  Google Scholar 

  • Mallik SK, Arora T (2003) UV radiations: problems and remedies. Man Made Text India 5:164–169

    Google Scholar 

  • McEvoy JG, Zhang Z (2014) Antimicrobial and photocatalytic disinfection mechanisms in silver-modified photocatalysts under dark and light conditions. J Photochem Photobiol C Photochem Rev 19:62–75

    Article  Google Scholar 

  • Milosevic M, Radoicic M, Saponjic Z, Nunney T, Deeks C, Lazic V, Mitric M, Radetic T, Radetic M (2014) In situ photoreduction of Ag+ ions by TiO2 nanoparticles deposited on cotton and cotton/PET fabrics. Cellulose 21:3781–3795

    Article  CAS  Google Scholar 

  • Montazer M, Seifollahzadeh S (2011) Enhanced self-cleaning, antibacterial and uv protection properties of nano TiO2 treated textile through enzymatic pretreatment. Photochem Photobiol 87:877–883

    Article  CAS  Google Scholar 

  • Onar N, Aksit AC, Sen Y, Mutlu M (2011) Antimicrobial UV-protective and self-cleaning properties of cotton fabrics coated by dip-coating and solvothermal coating methods. Fibers Polym 12(4):461–470

    Article  CAS  Google Scholar 

  • Pakdel E, Daoud WA (2013) Self-cleaning cotton functionalized with TiO2/SiO2: focus on the role of silica. J Coll Interface Sci 401:1–7

    Article  CAS  Google Scholar 

  • Paul R, Bautista L, Varga MDL, Botet JM, Casals E, Puntes V, Marsal F (2010) Nano-cotton fabrics with high ultraviolet protection. Text Res J 80:454–462

    Article  CAS  Google Scholar 

  • Perera S, Bhushan B, Bandara R, Rajapakse G, Rajapakse S, Bandara C (2013) Morphological antimicrobial, durability and physical properties of untreated and treated textiles using silver-nanoparticles. Coll Surf A Physicochem Eng Asp 436:170–176

    Article  Google Scholar 

  • Pranaitytė B, Padarauskas A, Naujalis E (2007) Application of ICP-MS for the determination of trace metals in textiles. Chemija 18:16–19

    Google Scholar 

  • Qi K, Xin JH (2010) Room-temperature synthesis of single-phase anatase TiO2 by aging and its self-cleaning properties. ACS Appl Mater Interfaces 2:3479–3485

    Article  CAS  Google Scholar 

  • Rana M, Hao B, Mu L, Chen L, Ma PC (2016) Development of multi-functional cotton fabrics with Ag/AgBr–TiO2 nanocomposite coating. Compos Sci Technol 122:104–112

    Article  CAS  Google Scholar 

  • Roelandts R (1998) Shedding light on sunscreens. Clin Exp Dermatol 23:147–157

    Article  CAS  Google Scholar 

  • Rupp J, Bohringer A, Yonenaga A, Hilden J (2001) Textiles for protection against harmful ultraviolet radiation. Int Text Bull 6:8–20

    Google Scholar 

  • Rupp ME, Fitzgerald T, Marion N, Helget V, Puumala S, Anderson JR, Fey PD (2004) Effect of silver-coated urinary catheters: efficacy, cost-effectiveness and antimicrobial resistance. Am J Infect Control 32:445–450

    Article  Google Scholar 

  • Sadu RB, Chen DH, Kucknoor AS, Guo Z, Gomes AJ (2014) Silver-doped TiO2/polyurethane nanocomposites for antibacterial textile coating. BioNanoScience. 4:136–148

    Article  Google Scholar 

  • Su C, Liu L, Zhang M, Zhanga Y, Shao C (2012) Fabrication of Ag/TiO2 nano heterostructures with visible light photocatalytic function via a solvothermal approach. Cryst Eng Comm 14:3989–3999

    Article  CAS  Google Scholar 

  • Tan B, Gao B, Guo J, Guo X, Long M (2013) A comparison of TiO2 coated self-cleaning cotton by the sols from peptizing and hydrothermal routes. Surf Coat Technol 232:26–32

    Article  CAS  Google Scholar 

  • Uğur SS, Sarıışık M, Aktaş AH, Uçar MC, Erden E (2010) Modifying of cotton fabric surface with nano-ZnO multilayer films by layer-by-layer deposition method. Nanoscale Res Lett 5:1204–1210

    Article  Google Scholar 

  • Wang SQ, Kopf AW, Marx J, Bogdan A, Polsky D, Bart RS (2001) Reduction of ultraviolet transmission through cotton T-shirt fabrics with low ultraviolet protection by various laundering methods and dyeing: clinical implications. J Am Acad Dermatol 44:767–774

    Article  CAS  Google Scholar 

  • Wang L, Zhang X, Li B, Sun P, Yang J, Xu H, Liu Y (2011) Superhydrophobic and ultraviolet-blocking cotton textiles. Appl Mater Interfaces 3:1277–1281

    Article  CAS  Google Scholar 

  • Wijesena RN, Tissera ND, Perera R, De Silva KMN, Amaratunga GAJ (2015) Slightly carbomethylated cotton supported TiO2 nanoparticles as self-cleaning fabrics. J Mol Catal A Chem 398:107–114

    Article  CAS  Google Scholar 

  • Wong W, Lam JKC, Kan C, Postle R (2013) Influence of knitted fabric construction on the ultraviolet protection factor of greige and bleached cotton fabrics. Text Res J 83:683–699

    Article  CAS  Google Scholar 

  • Wu D, Long M (2011a) Enhancing visible-light activity of the self-cleaning TiO2-coated Cotton fabrics by loading AgI particles. Surf Coat Technol 206:1175–1179

    Article  CAS  Google Scholar 

  • Wu D, Long M (2011b) Realizing visible-light-induced self-cleaning property of cotton through coating N-TiO2 film and loading AgI particles. ACS Appl Mater Interfaces 3:4770–4774

    Article  CAS  Google Scholar 

  • Wu D, Long M, Zhou J, Cai W, Zhu X, Chen C, Wu Y (2009) Synthesis and characterization of self-cleaning cotton fabrics modified by TiO2 through a facile approach. Surf Coat Technol 203:3728–3733

    Article  CAS  Google Scholar 

  • Xiao XF, Liu X, Chen FX, Fang D, Zhang C, Xia L, Xu W (2015) Highly anti-UV properties of silk fiber with uniform and conformal nanoscale TiO2 coatings via atomic layer deposition. Appl Mater Interfaces 7(38):21326–21333

    Article  CAS  Google Scholar 

  • Xin B, Jing L, Ren Z, Wang B, Fu H (2005) Effects of simultaneously doped and deposited Ag on the photocatalytic activity and surface states of TiO2. J Phys Chem B 109:2805–2809

    Article  CAS  Google Scholar 

  • Xu B, Ding J, Feng L, Ding Y, Ge F, Cai Z (2015) Self-cleaning cotton fabrics via combination of photocatalytic TiO2 and superhydrophobic SiO2. Surf Coat Technol 262:70–76

    Article  CAS  Google Scholar 

  • Yu M, Wang Z, Liu H, Xie S, Wu J, Jiang H, Zhang J, Li L, Li J (2013) Laundering durability of photocatalyzed self-cleaning cotton fabric with TiO2 nanoparticles covalently immobilized. Appl Mater Interfaces 5:3697–3703

    Article  CAS  Google Scholar 

  • Yuranova T, Rincon AG, Pulgarin C, Laub DN, Xantopoulos N, Mathieu HJ, Kiwi J (2006) Performance and characterization of Ag–cotton and Ag/TiO2 Loaded textiles during the abatement of E. Coli. J Photochem Photobiol A Chem 81:363–369

    Article  Google Scholar 

  • Zhang H, Liang C, Liu J, Tian Z, Wang G, Cai W (2012) Defect-mediated formation of Ag cluster-doped TiO2 nanoparticles for efficient photodegradation of pentachlorophenol. Langmuir 28:3938–3944

    Article  CAS  Google Scholar 

  • Zhang YY, Xu QB, Fu FY, Liu XD (2016) Durable antimicrobial cotton textiles modified with inorganic nanoparticles. Cellulose 23:2791–2808

    Article  CAS  Google Scholar 

  • Zielińskaa A, Kowalskaa E, Sobczakd JW, Łąckab I, Gazdac M, Ohtanie B, Hupkaa J, Zaleska A (2010) Silver-doped TiO2 prepared by microemulsion method: surface properties, bio and photoactivity. Sep Purif Technol 72(3):309–318

    Article  Google Scholar 

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Correspondence to Bhupendra Singh Butola.

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Mishra, A., Butola, B.S. Deposition of Ag doped TiO2 on cotton fabric for wash durable UV protective and antibacterial properties at very low silver concentration. Cellulose 24, 3555–3571 (2017). https://doi.org/10.1007/s10570-017-1352-4

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