Skip to main content

Advertisement

SpringerLink
Log in

The oxidation of viscose fiber optimized by response surface methodology and its further amination with PEI for CO2 adsorption

  • Original Paper
  • Published:
Cellulose Aims and scope Submit manuscript

Abstract

Viscose fiber was oxidized with sodium periodate to prepare a reactive dialdehyde viscose fiber (DAVF) containing abundant aldehyde groups. A solid amine adsorbent (DAVF-PEI) with high amino density for CO2 capture was then prepared by modifying DAVF with polyethylenimine (PEI). Response surface methodology (RSM) based on a three-level, three-factorial design was used to optimize the synthesis conditions of DAVF, in which multiple linear regression equations of aldehyde content and fiber mass loss degree were constructed. The well-designed DAVF was then employed as a support to graft with PEI via Schiff base reaction to prepare a solid amine fiber (DAVF-PEI) for CO2 adsorption. The experimental results verified that DAVF-PEI possessed good thermo-stability and high CO2 adsorption capacity (4.11 mmol/g). DAVF-PEI also showed promising regeneration performance, which could maintain almost the same adsorption capacity for CO2 after ten adsorption and desorption recycles.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Scheme 2
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  • Amini M, Younesi H, Bahramifar N, Lorestani AAZ, Ghorbani F, Daneshi A, Sharifzadeh M (2008) Application of response surface methodology for optimization of lead biosorption in an aqueous solution by Aspergillus niger. J Hazard Mater 154:694–702

    Article  CAS  Google Scholar 

  • Bezerra MA, Santelli RE, Oliveira EP, Villar LS, Escaleira LA (2008) Response surface methodology (RSM) as a tool for optimization in analytical chemistry. Talanta 76:965–977

    Article  CAS  Google Scholar 

  • Calvini P, Conio G, Princi E, Vicini S, Pedemonte E (2006) Viscometric determination of dialdehyde content in periodate oxycellulose part II. Topochemistry of oxidation. Cellulose 13:571–579

    Article  CAS  Google Scholar 

  • Deanna M, D’Alessandro Berend S, Jeffrey RL (2010) Carbon dioxide capture: prospects for new materials. Angew Chem Int Edit 49:6058–6082

    Article  Google Scholar 

  • Drese JH, Choi S, Lively RP, Koros WJ, Fauth DJ, Gray ML, Jones CW (2009) Synthesis–structure–property relationships for hyperbranched aminosilica CO2 adsorbents. Adv Funct Mater 19:3821–3832

    Article  CAS  Google Scholar 

  • Gray ML, Soong Y, Champagne KJ, Pennline H, Baltrus JP, Stevens JRW, Khatri R, Chuang SSC, Filburn T (2005) Improved immobilized carbon dioxide capture sorbents. Fuel Process Technol 86:1449–1455

    Article  CAS  Google Scholar 

  • Harun N, Nittaya T, Douglas PL (2012) Dynamic simulation of MEA absorption process for CO2 capture from power plants. Int J Greenh Gas Control 10:295–309

    Article  CAS  Google Scholar 

  • Hicks JC, Se JH, Fauth DJ (2008) Designing adsorbents for CO2 capture from flue gas-hyperbranched aminosilicas capable of capturing CO2 reversibly. J Am Chem Soc 130:274–278

    Article  Google Scholar 

  • Kalavathy MH, Regupathi I, Pillai MG, Miranda LR (2009) Modelling, analysis and optimization of adsorption parameters for H3PO4 activated rubber wood sawdust using response surface methodology (RSM). Colloids Surf B 70:35–45

    Article  Google Scholar 

  • Kim HK, Kim JG, Cho JD, Hong JW (2003) Optimization and characterization of UV-curable adhesives for optical communications by response surface methodology. Polym Test 22:899–906

    Article  CAS  Google Scholar 

  • Kim UJ, Wada M, Kuga S (2004) Solubilization of dialdehyde cellulose by hot water. Carbohyd Polym 56:7–10

    Article  CAS  Google Scholar 

  • Kumari S, Chauhan GS (2014) New Cellulose-lysine schiff-base-based sensor-adsorbent for mercury ions. ACS Appl Mater Interfaces 6:5908–5917

    Article  CAS  Google Scholar 

  • Li W, Choi S, Drese J (2010) Steam-stripping for regeneration of supported amine-based CO2 adsorbents. Chemsuschem 3:899–903

    Article  CAS  Google Scholar 

  • Li H, Wu B, Mu C, Lin W (2011) Concomitant degradation in periodate oxidation of carboxymethyl cellulose. Carbohyd Polym 84:881–886

    Article  CAS  Google Scholar 

  • Liu XL, Wang LJ, Song XP, Song HN, Zhao JR, Wang SF (2012a) A kinetic model for oxidative degradation of bagasse pulp fiber by sodium periodate. Carbohyd Polym 90:218–223

    Article  CAS  Google Scholar 

  • Liu Y, Wang JT, Zheng Y, Wang AQ (2012b) Adsorption of methylene blue by kapok fiber treated by sodium chlorite optimized with response surface methodology. Chem Eng J 184:248–255

    Article  CAS  Google Scholar 

  • Pevida C, Plaza MG, Arias B (2008) Surface modification of activated carbons for CO2 capture. Appl Surf Sci 254:7165–7172

    Article  CAS  Google Scholar 

  • Potthast A, Kostic M, Schiehser S, Kosma P, Rosenau T (2007) Studies on oxidative modifications of cellulose in the periodate system: molecular weight distribution and carbonyl group profiles. Holzforschung 61:662–667

    Article  CAS  Google Scholar 

  • Sayari A, Belmabkhout Y, Serna-Guerrero R (2011) Flue gas treatment via CO2 adsorption. Chem Eng J 171:760–774

    Article  CAS  Google Scholar 

  • Schrier J (2012) Carbon dioxide separation with a two-dimensional polymer membrane. Acs Appl Mater Inter 4:3745–3752

    Article  CAS  Google Scholar 

  • Serna-Guerrero R, Sayari A (2010) Modeling adsorption of CO2 on amine-functionalized mesoporous Silica. 2: kinetics and breakthrough curves. Chem Eng J 161:182–190

    Article  CAS  Google Scholar 

  • Siriwardane RV, Shen MS, Fisher EP, Poston JA (2001) Adsorption of CO2 on molecular sieves and activated carbon. Energy Fuels 15:279–284

    Article  CAS  Google Scholar 

  • Sirvio J, Hyvakko U, Liimatainen U, Niinimaki J, Hormia O (2011) Periodate oxidation of cellulose at elevated temperatures using metal salts as cellulose activators. Carbohyd Polym 83:1293–1297

    Article  CAS  Google Scholar 

  • Wang X, Ma X, Song C (2012) Molecular basket sorbents polyethylenimine–SBA-15 for CO2 capture from flue gas: characterization and sorption properties. Micropor Mesopor Mater 169:103–111

    Article  Google Scholar 

  • Wu M, Kuga S (2006) Cationization of cellulose fabrics by polyallylamine binding. J Appl Polym Sci 100:1668–1672

    Article  CAS  Google Scholar 

  • Wu QH, Chen SX, Liu H (2014) Effect of surface chemistry of polyethyleneimine-grafted polypropylene fiber on its CO2 adsorption. RSC Adv 4:27176–27183

    Article  CAS  Google Scholar 

  • Xu T, Wu QH, Chen SX, Deng MW (2015) Preparation of polypropylene based hyperbranched absorbent fibers and the study of their adsorption of CO2. RSC Adv 5:32902–32908

    Article  CAS  Google Scholar 

  • Yang Y, Li HC, Chen SX, Zhao YN, Li QH (2010) Preparation and characterization of a solid amine adsorbent for capturing CO2 by grafting allylamine onto PAN fiber. Langmuir 26:13897–13902

    Article  CAS  Google Scholar 

  • Zhang QK, Zhang SJ, Chen SX, Li PY, Qin TY, Yuan SG (2008) Preparation and characterization of a strong basic anion exchanger by radiation-induced grafting of styrene onto poly(tetrafluoroethylene) fiber. J Colloid Interface Sci 322:421–428

    Article  CAS  Google Scholar 

  • Zhao Y, Seredych M, Zhong Q, Bandosz TJ (2013) Superior performance of copper based mof and aminated graphite oxide composites as CO2 adsorbents at room temperature. ACS Appl Mater Interfaces 5:4951–4959

    Article  CAS  Google Scholar 

  • Zhuang LZ, Chen SX, Lin RJ, Xu XZ (2013) Preparation of a solid amine adsorbent based on polypropylene fiber and its performance for CO2 capture. J Mater Res 28:2881–2889

    Article  CAS  Google Scholar 

  • Zukal A, Dominguez I, Mayerova J, Ejka J (2009) Functionalization of delaminated zeolite ITQ-6 for the adsorption of carbon dioxide. Langmuir 25:10314–10321

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors gratefully acknowledge the financial support provided by the National Natural Science Foundation of China (Grant No. 51473187), Natural Science Foundation of Guangdong Province (2014A030313192).

Author information

Authors and Affiliations

  1. PCFM Lab, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, 510275, People’s Republic of China

    Hui He, Xunan Hou, Beibei Ma, Linzhou Zhuang, Chuanfa Li, Shihong He & Shuixia Chen

  2. Materials Science Institute, Sun Yat-Sen University, Guangzhou, 510275, People’s Republic of China

    Shuixia Chen

Authors
  1. Hui He
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Xunan Hou
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Beibei Ma
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Linzhou Zhuang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Chuanfa Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Shihong He
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Shuixia Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Shuixia Chen.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOCX 30 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

He, H., Hou, X., Ma, B. et al. The oxidation of viscose fiber optimized by response surface methodology and its further amination with PEI for CO2 adsorption. Cellulose 23, 2539–2548 (2016). https://doi.org/10.1007/s10570-016-0955-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10570-016-0955-5

Keywords

Search

Navigation