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SnO2 Nanoparticle-Decorated Graphene Oxide Sheets Efficiently Catalyze Baeyer–Villiger Oxidation with H2O2

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Abstract

Uniform rutile SnO2 nanoparticles with small size (ca. 3 nm) were highly dispersed on both sides of GO sheets through electrostatic interactions, giving pseudo-homogeneous catalysts of SnO2/GO nanocomposites. The SnO2-decorated GO nanocomposites, especially, SnO2 (15 wt%)/GO was highly efficient and reusable in Baeyer–Villiger oxidation of ketones with H2O2.

Graphical Abstract

SnO2/GO nanocomposites, where uniform SnO2 nanoparticles were tightly gripped on both sides of GO sheets by surface oxygenated functional groups through electrostatic interaction, have proved to be a versatile, efficient and reusable catalyst for the BV oxidation of ketones with H2O2.

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Acknowledgments

The project was financially supported by the National Natural Science Foundation of China (Grant No. 21476069), the Scientific Research Fund of Hunan Provincial Education Department (13B072), the Program for Excellent Talents in Hunan Normal University (ET14103), the Hunan Provincial Innovation Foundation for Postgraduate (CX2013B209) and the Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province.

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Authors and Affiliations

  1. Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Ministry of Education) and Key Laboratory of the Assembly and Application for Organic Functional Molecules, Hunan Normal University, Changsha, 410081, People’s Republic of China

    Weiguo Zheng, Rong Tan, Xuanfeng Luo, Chen Xing & Donghong Yin

  2. Technology Center, China Tobacco Hunan Industrial Corporation, NO. 426 Laodong Road, Changsha, 410014, Hunan, People’s Republic of China

    Donghong Yin

Authors
  1. Weiguo Zheng
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  2. Rong Tan
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  3. Xuanfeng Luo
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  4. Chen Xing
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  5. Donghong Yin
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Corresponding authors

Correspondence to Rong Tan or Donghong Yin.

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Zheng, W., Tan, R., Luo, X. et al. SnO2 Nanoparticle-Decorated Graphene Oxide Sheets Efficiently Catalyze Baeyer–Villiger Oxidation with H2O2 . Catal Lett 146, 281–290 (2016). https://doi.org/10.1007/s10562-015-1639-8

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  • DOI: https://doi.org/10.1007/s10562-015-1639-8

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