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Influence of carbon polymorphism towards improved sodium storage properties of Na3V2O2x (PO4)2F3-2x

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Abstract

The effects of 10 wt.% super P carbon, multiwalled carbon nanotubes (MWCNTs), and reduced graphene oxide (rGO) on particles size and electrochemical properties of Na3V2O2x (PO4)2F3-2x cathode material were studied. Among these three carbon polymorphs, using MWCNT in composite is effective to obtain low particle size and enhanced electrochemical properties of Na3V2O2x (PO4)2F3-2x . While using rGO to make the composite, the particle size becomes quite big, leading a smaller surface contact area with the electrolytes and thereby resulting in poor cyclability. Na3V2O2x (PO4)2F3-2x -MWCNT composite shows a high capacity of 98 mAh g−1at 0.1 C rate for 100 cycles, and further, it exhibits a stable capacity of 89 mAh g−1 at 0.2 C rate vs. NaTi2(PO4)3-MWCNT in full cell configuration.

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Acknowledgments

This work was supported by the Program to Solve Climate Changes (NRF-2010-C1AAA001-2010-0029031) of Korea (NRF), funded by the Ministry of Science, ICT, and Future Planning. It was also supported by the Climate Change Research Hub of KAIST (Grant No. N01150034).

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Authors and Affiliations

  1. Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology, Daejeon, 34141, Republic of Korea

    P. Ramesh Kumar, Young Hwa Jung & Do Kyung Kim

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  1. P. Ramesh Kumar
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  2. Young Hwa Jung
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  3. Do Kyung Kim
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Correspondence to Do Kyung Kim.

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Kumar, P.R., Jung, Y.H. & Kim, D.K. Influence of carbon polymorphism towards improved sodium storage properties of Na3V2O2x (PO4)2F3-2x . J Solid State Electrochem 21, 223–232 (2017). https://doi.org/10.1007/s10008-016-3365-6

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  • DOI: https://doi.org/10.1007/s10008-016-3365-6

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