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Electrochemical behavior of SeO2 in sodium citrate solution on a polycrystalline SnO2 electrode

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An Erratum to this article was published on 11 February 2016

Abstract

Preliminary results regarding the electrochemical behavior of Se(IV) in sodium citrate solution on a polycrystalline SnO2 electrode are presented. A schematic diagram of the energy levels for an n-type SnO2 electrode in contact with the working electrolyte was constructed. The results of cyclic voltammetry (CV) show that SeO 2−3 reduction occurs through a surface state in a complex multistep pathway. After a minute amount of Se is deposited, the electrode is expected to behave locally like a Schottky diode in contact with the solution. CV analysis and current transient results indicate that selenium growth on the polycrystalline SnO2 surface proceeds without nucleation. A thin Se film obtained at a potential of −0.8 V vs. Ag|AgCl, KCl(sat) was analyzed by lateral force and atomic force microscopy.

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Authors and Affiliations

  1. Department of Physical and Inorganic Chemistry, Kaunas University of Technology, Radvilėnų pl.19, Kaunas, LT-50254, Lithuania

    N. Dukštienė & D. Sinkevičiūtė

  2. AB “Achema”, Resarch and Development Department, Jonalaukio, LT-55550, Lithuania

    L. Tatariškinaitė

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  1. N. Dukštienė
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  2. D. Sinkevičiūtė
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  3. L. Tatariškinaitė
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Correspondence to D. Sinkevičiūtė.

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Dukštienė, N., Sinkevičiūtė, D. & Tatariškinaitė, L. Electrochemical behavior of SeO2 in sodium citrate solution on a polycrystalline SnO2 electrode. J Solid State Electrochem 20, 813–825 (2016). https://doi.org/10.1007/s10008-015-2974-9

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  • DOI: https://doi.org/10.1007/s10008-015-2974-9

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