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Influence of conditions of polyaniline synthesis in perfluorinated membrane on electrotransport properties and surface morphology of composites

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Abstract

The conductivity, diffusion, and electroosmotic permeability of composites, obtained in different conditions of polyaniline synthesis on the surface or in volume of perfluorinated MF-4SK membrane, were studied. The oxidative polymerization of aniline was carried out in static conditions in mixture of monomer and oxidant solutions, in concentration field by method of successive diffusion of polymerization solutions through the membrane in water, and in an external electrical field. The concentration of polymerization solutions, the type of electron acceptors, duration of synthesis, and current density were varied to obtain a set of composites. The certain advantages of every method of polyaniline chemical template synthesis were revealed to prepare the materials with required set of the electrotransport characteristics.

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References

  1. García M, Batalla P, Escarpa A (2014) Metallic and polymeric nanowires for electrochemical sensing and biosensing. TrAC Trends Anal Chem 57:6–22

    Article  Google Scholar 

  2. Nekrasov AA, Ivanov VF, Vannikov AV (2001) A comparative voltabsorptometric study of polyaniline films prepared by different methods. Electrochim Acta 46:3301–3307

    Article  CAS  Google Scholar 

  3. Sazou D, Kosseoglou D (2006) Corrosion inhibition by nafion-polyaniline composite films deposited on stainless steel in a two step process. Electrochim Acta 51:2503–2511

    Article  CAS  Google Scholar 

  4. Sivaraman P, Chavan JG, Thakur AP, Hande VR, Samui AB (2007) Electrochemical modification of cationexchange membrane with polyaniline for improvement in permselectivity. Electrochim Acta 52:5046–5052

    Article  CAS  Google Scholar 

  5. Munar A, Suarez K, Solorza O, Berezina NP, Compañ V (2010) Performance of hydrogen fuel cell MEAs based on perfluorinated nanocomposite membranes modified by polyaniline. J Electrochem Soc 4(1):B1186–B1194

    Article  Google Scholar 

  6. Bhadra S, Khastgir D, Singha NK, Lee JH (2009) Progress in preparation, processing and application of polyaniline. Prog Polym Sci 34:783–810

    Article  CAS  Google Scholar 

  7. Konev DV, Devillers CH, Lizgina KV, Baulin VE, Vorotyntsev MA (2015) Electropolymerization of non-substituted Mg(II) porphine: effects of proton acceptor addition. J Electroanal Chem 737:235–242

    Article  CAS  Google Scholar 

  8. Peighambardoust SJ, Rowshanzamir S, Amjadi M (2010) Review of the proton exchange membranes for fuel cell applications. Int J Hydrog Energy 35:9349–9384

    Article  CAS  Google Scholar 

  9. Yang J, Shen PK, Varcoe J, Wei Z (2009) Nafion/polyaniline composite membranes specifically designed to allow proton exchange membrane fuel cells operation at low humidity. J Power Sources 189:1016–1019

    Article  CAS  Google Scholar 

  10. Mokhtarian N, Ghasemi M, Wan Daud WR, Ismail M, Najafpour G, Alam J (2013) Improvement of microbial fuel cell performance by using nafion polyaniline composite membranes as a separator. J Fuel Cell Sci Technol 10(4):041008–041008-6. doi:10.1115/1.4024866

    Article  Google Scholar 

  11. Tan S, Belanger D (2005) Characterization and transport properties of nafion/polyaniline composite membranes. J Phys Chem B 109(49):23480–23490

    Article  CAS  Google Scholar 

  12. Farrokhzad H, Darvishmanesh S, Genduso G, Van Gerven T, Van der Bruggen B (2015) Development of bivalent cation selective ion exchange membranes by varying molecular weight of polyaniline. Electrochim Acta 158:64–72

    Article  CAS  Google Scholar 

  13. Kumar M, Khan MA, AlOthman ZA, Siddiqui MR (2013) Polyaniline modified organic–inorganic hybrid cation-exchange membranes for the separation of monovalent and multivalent ions. Desalination 325:95–103

    Article  CAS  Google Scholar 

  14. Amado FDR, Rodrigues MAS, Morisso FDP, Bernardes AM, Ferreira JZ, Ferreira CA (2008) High-impact polystyrene/polyaniline membranes for acid solution treatment by electrodialysis: preparation, evaluation, and chemical calculation. J Colloid Interface Sci 320(1):52–61

    Article  CAS  Google Scholar 

  15. Blinova NV, Stejskal J, Trchova M, Sapurina I, Ćirić-Marjanović G (2009) The oxidation of aniline with silver nitrate to polyaniline–silver composites. Polymer 50:50–56

    Article  CAS  Google Scholar 

  16. Li G, Jiang L, Peng H (2007) One-dimensional polyaniline nanostructures with controllable surfaces and diameters using vanadic acid as the oxidant. Macromolecules 40(22):7890

    Article  CAS  Google Scholar 

  17. Magdesieva TV, Nikitin OM, Levitsky OA, Zinovyeva VA, Bezverkhyy I, Zolotukhina EV, Vorotyntsev MA (2012) Polypyrrole–palladium nanoparticles composite as efficient catalyst for Suzuki–Miyaura coupling. J Mol Catal A Chem 353–354:50–57

    Article  Google Scholar 

  18. Lysova AA, Stenina IA, Gorbunova YG, Yaroslavtsev AB (2011) Preparation of MF-4SC composite membranes with the anisotropic distribution of polyaniline and ion-transport asymmetry. Polym Sci Ser B 53(1–2):35–41

    Article  CAS  Google Scholar 

  19. Tan S, Tieu JH, Belanger D (2005) Chemical polymerization of aniline on a poly(styrene sulfonic acid) membrane: controlling the polymerization site using different oxidants. J Phys Chem B 109(29):14085–14092

    Article  CAS  Google Scholar 

  20. Berezina N, Falina I, Sytcheva A, Shkirskaya S, Timofeyev S (2010) New generation of nanocomposite materials based on perfluorinated membranes and polyaniline: intercalation phenomena, morphology and transport properties. Desalin Water Treat 14:246–251

    Article  CAS  Google Scholar 

  21. Berezina NP, Kononenko NA, Sytcheva AA-R, Loza NV, Shkirskaya SA, Hegman N, Pungor A (2009) Perfluorinated nanocomposite membranes modified by polyaniline: electrotransport phenomena and morphology. Electrochim Acta 54(8):2342–2352

    Article  CAS  Google Scholar 

  22. Kononenko NA, Berezina NP, Dolgopolov SV, Polovinko TP, Falina IV (2011) Patent RF, No 2011149509/05(074299). 05.12.2011

  23. Choi BG, Park H, Im HS, Kim YJ, Hong WH (2008) Influence of oxidation state of polyaniline on physicochemical and transport properties of nafion/polyaniline composite membrane for DMFC. J Membr Sci 324(1–2):102–110

    Article  CAS  Google Scholar 

  24. Sapurina Y, Kompan ME, Malyshkin VV, Rosanov VV, Stejskal J (2009) Properties of proton-conducting nafion-type membranes with nanometer-thick polyaniline surface layers. Russ J Electrochem 45(6):697–706

    Article  CAS  Google Scholar 

  25. Johnson D, Hilal N (2015) Characterisation and quantification of membrane surface properties using atomic force microscopy: a comprehensive review. Desalination 356:149–164

    Article  CAS  Google Scholar 

  26. Vorotyntsev MA, Konev DV, Ul L, Tolmachev YV, Skompska M (2013) Atomic force microscopy study of conducting polymer films near electrode’s edge or grown on microband electrode. Electrochim Acta 110:452–458

    Article  CAS  Google Scholar 

  27. Berezina NP, Kononenko NA, Dyomina OA, Gnusin NP (2008) Characterization of ion-exchange membrane materials: properties vs structure. Adv Colloid Interf Sci 139:3–28

    Article  CAS  Google Scholar 

  28. Blythe T, Bloor D (2005) Electrical properties of polymers. Cambridge University Press, New York. ISBN 0521552192

    Google Scholar 

  29. Ivanov VF, Gribkova OL, Novikov SV, Nekrasov AA, Isakova AA, Vannikov AV, Meshkov GB, Yaminsky IV (2005) Redox heterogeneity of polyaniline: from molecular to macroscopic scale. Synth Met 152(1–3):153–156

    Article  CAS  Google Scholar 

  30. Falina IV, Berezina NP (2010) Diffusion of solutions in the course of the matrix synthesis of composite membranes MF-4SC-polyaniline and their transport properties. Polym Sci Ser B 52(3–4):244–251

    Article  Google Scholar 

  31. Yaroslavtsev AB, Stenina IA, Voropaeva EY, Ilyina AA (2009) Ion transfer in composite membranes based on MF-4SC incorporating nanoparticles of silica, zirconia and polyaniline. Polym Adv Technol 20:566–570

    Article  CAS  Google Scholar 

  32. Filippov AN, Iksanov RK, Kononenko NA, Berezina NP, Falina IV (2010) Theoretical and experimental study of asymmetry of diffusion permeability of composite membranes. Colloid J 72(2):243–254

    Article  CAS  Google Scholar 

  33. Berezina NP, Shkirskaya SA, Sycheva AA-R, Krishtopa MV (2008) The electric transport of proton-bound water in MF-4SK/PANI nanocomposite membranes. Colloid J 70(4):397–406

    Article  CAS  Google Scholar 

  34. Marcus Y (1986) The hydration of ions and their effects on the structure of water. J Chem Soc Faraday Trans 82:233–242

    Article  CAS  Google Scholar 

  35. Berezina NP, Shkirskaya SA, Kolechko MV, Popova OV, Senchikhin IN, Roldugin VI (2011) Barrier effects of polyaniline layer in surface modified MF-4SK/polyaniline membranes. Russ J Electrochem 47(9):995–1005

    Article  CAS  Google Scholar 

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Acknowledgments

The present work is supported by the Russian Foundation for Basic Research (project nos 14-38-50268, 14-08-31526, 14-08-00893, and 15-08-03285).

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Authors and Affiliations

  1. Department of Physical Chemistry, Kuban State University, Krasnodar, Russian Federation

    N. A. Kononenko, N. V. Loza, S. A. Shkirskaya & I. V. Falina

  2. Gubkin Russian State University of Oil and Gas, Moscow, Russian Federation

    D. Yu. Khanukaeva

Authors
  1. N. A. Kononenko
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  2. N. V. Loza
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  3. S. A. Shkirskaya
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  4. I. V. Falina
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  5. D. Yu. Khanukaeva
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Correspondence to N. A. Kononenko.

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Kononenko, N.A., Loza, N.V., Shkirskaya, S.A. et al. Influence of conditions of polyaniline synthesis in perfluorinated membrane on electrotransport properties and surface morphology of composites. J Solid State Electrochem 19, 2623–2631 (2015). https://doi.org/10.1007/s10008-015-2829-4

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  • DOI: https://doi.org/10.1007/s10008-015-2829-4

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