Skip to main content
SpringerLink
Log in

Study on the magnetic ODSA-in-water Pickering emulsion stabilized by Fe3O4 nanoparticle

  • Original Contribution
  • Published:
Colloid and Polymer Science Aims and scope Submit manuscript

Abstract

Octadecenyl succinic anhydride (ODSA) is an oily paper sizing agent that is generally introduced into the paper-manufacturing system as an ODSA-in-water emulsion. In this paper, magnetic ODSA-in-water emulsions are prepared by homogenizing the mixture of ODSA and aqueous dispersion of Fe3O4 nanoparticle. The emulsion droplets are covered with magnetic nanoparticles and easily deform at the present of magnetic field. Recoverable structure and time hysteresis effect have been observed in the as-prepared emulsions with viscoelasticity. The shear moduli G′ and G′′ increase logarithmically with the increasing angular frequency; it is noted that G′ remained higher than G′′ throughout the entire experiment, which is characteristic for elastic system, illustrating the evolution of particles and the particulate network in the system. Raman spectroscopy reflects the good hydrolysis stability of as-prepared ODSA emulsions. Paper coated by as-prepared ODSA Pickering emulsion containing Fe3O4 nanoparticles shows good hydrophobicity and magnetic induction.

ᅟ

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. Ramsden W (1903) Separation of solids in the surface-layers of solution and ‘suspensions’-preliminary account. Proc R Soc Lond 72:156–164

    Article  CAS  Google Scholar 

  2. Pickering SU (1907) Emulsions. J Chem Soc 1:2001–2021

    Article  Google Scholar 

  3. David E. Tambe, M. M. S. (1995) Factors controlling the stability of colloid-stabilized emulsions: III. Measurement of the Rheological Properties of Colloid-Laden Interfaces. J Colloid Interf Sci 171: 456-462

  4. Binks BP, Clint JH, Whitby CP (2005) Rheological behavior of water-in-oil emulsions stabilized by hydrophobic bentonite particles. Langmuir 21:5307–5316

    Article  CAS  Google Scholar 

  5. G. Lagaly, M. R. S. A. (1999) Smectites as colloidal stabilizers of emulsions I. Preparation and properties of emulsions with smectites and nonionic surfactants. Appl Clay Sci 14: 83-103

  6. Aveyard R, Binks BP, Clint JH (2003) Emulsions stabilised solely by colloidal particles. Adv Colloid Interf 100:503–546

    Article  Google Scholar 

  7. Dickinson E (2010) Food emulsions and foams: stabilization by particles. Curr Opin Colloid Interface 15:40–49

    Article  CAS  Google Scholar 

  8. Nonomura Y, Kobayashi N (2009) Phase inversion of the Pickering emulsions stabilized by plate-shaped clay particles. J Colloid Interf Sci 330:463–466

    Article  CAS  Google Scholar 

  9. Simovic S, Prestidge CA (2007) Nanoparticle layers controlling drug release from emulsions. Eur J Pharm Biopharm 67:39–47

    Article  CAS  Google Scholar 

  10. Lin Y, Skaff H, Emrick T, Dinsmore AD, Russell TP (2003) Nanoparticle assembly and transport at liquid-liquid interfaces. Russell. Science 299:226–229

    Article  CAS  Google Scholar 

  11. Sejong K, Barraza H, Velev OD (2009) Intense and selective coloration of foams stabilized with functionalized particles. J Mater Chem 19:7043–7049

    Article  Google Scholar 

  12. Fujii S, Armes SP, Binks BP, Murakami R (2006) Stimulus-responsive particulate emulsifiers based on lightly cross-linked poly(4-vinylpyridine)-silica nanocomposite microgels. Langmuir 22:6818–6825

    Article  CAS  Google Scholar 

  13. Binks BP, Murakami R (2006) Phase inversion of particle-stabilized materials from foams to dry water. Nat Mater 5:865–869

    Article  CAS  Google Scholar 

  14. Zhou J, Wang LJ, Qiao XY, Binks BP, Sun K (2012) Pickering emulsions stabilized by surface-modified Fe3O4 nanoparticles. J Colloid Interf Sci 367:213–224

    Article  CAS  Google Scholar 

  15. Melle S, Lask M, Fuller GG (2005) Pickering emulsions with controllable stability. Langmuir 21:2158–2162

    Article  CAS  Google Scholar 

  16. Lam S, Blanco E, Smoukov SK, Velikov KP, Velev OD (2011) Magnetically responsive Pickering foams. J Am Chem Soc 133:13856–13859

    Article  CAS  Google Scholar 

  17. Kim YJ, Liu YD, Seo Y, Choi HJ (2013) Pickering emulsion polymerized polystyrene/Fe2O3 composite particles and their magnetoresponsive characteristics. Langmuir 29:4959–4965

    Article  CAS  Google Scholar 

  18. Liu YD, Zhang WL, Hyoung JC (2012) Pickering emulsion polymerization of core shell structured polyaniline@SiO2 nanoparticles and their electrorheological response. Colloid Polym Sci 290:855–860

    Article  CAS  Google Scholar 

  19. Abend S, Bonnke N, Gutschner U, Lagaly G (1998) Stabilization of emulsions by heterocoagulation of clay minerals and layered double hydroxides. Colloid Polym Sci 276:730–737

    Article  CAS  Google Scholar 

  20. Monteux C, Fuller GG, Bergeron V (2004) Shear and dilational surface rheology of oppositely charged polyelectrolyte/surfactant microgels adsorbed at the air-water interface. Influence on foam stability. J Phys Chem B 108:16473–16482

    Article  CAS  Google Scholar 

  21. Ma HA, Dai LL (2011) Particle self-assembly in ionic liquid-in-water Pickering emulsions. Langmuir 27:508–512

    Article  CAS  Google Scholar 

  22. Frost DS, Dai LL (2011) Molecular dynamics simulations of nanoparticle self-assembly at ionic liquid-water and ionic liquid-oil interfaces. Langmuir 27:11339–11346

    Article  CAS  Google Scholar 

  23. Li J, Hitchcock AP, Stover H (2010) Pickering emulsion templated interfacial atom transfer radical polymerization for microencapsulation. Langmuir 26:17926–17935

    Article  CAS  Google Scholar 

  24. Ding P, Liu W, Zhao Z (2011) Roles of short amine in preparation and sizing performance of partly hydrolyzed ASA emulsion stabilized by Laponite particles. Colloid Surf A 384:150–156

    Article  CAS  Google Scholar 

  25. Mohit T, Bhadra K, Goswami S, Agarwal NK (2007) Successful trials & optimization of ASA sizing. IPPTA 19:143

    Google Scholar 

  26. Yu DH, Lin ZY, Li YM (2013) Octadecenylsuccinic anhydride pickering emulsion stabilized by gamma-methacryloxy propyl trimethoxysilane grafted montmorillonite. Colloid Surf A 422:100–109

    Article  CAS  Google Scholar 

  27. Yu DH, Lin ZY, Li YM (2013) Pickering-type emulsions of ODSA sizing agent stabilized by nano-montmorillonite and N-dodecane. Appl Mech Mater 319:233–238

    Article  CAS  Google Scholar 

  28. Li H, Liu W, Zhang W, Qian K, Wang H (2013) Laponite and PAS costabilized ASA emulsion with high hydrolysis resistance and sizing efficiency. J Appl Polym Sci 129:3209–3218

    Article  CAS  Google Scholar 

  29. Qian KF, Liu WX, Zhang J, Li HD, Wang HL, Wang Z (2013) Using urea to improve stability, sizing performance and hydrolysis resistance of ASA emulsion stabilized by Laponite. Colloid Surf A 421:125–134

    Article  CAS  Google Scholar 

  30. Sacca L, Drelich A, Gomez F, Pezron I, Clausse D (2008) Composition ripening in mixed water-in-oil emulsions stabilized with solid particles. J Disper Sci Technol 29:948–952

    Article  CAS  Google Scholar 

  31. Huang H, You B, Zhou SX, Wu LM (2007) Rheological behavior of aqueous organosilicone resin emulsion stabilized by colloidal nanosilica particles. J Colloid Interface Sci 310:121–127

    Article  CAS  Google Scholar 

  32. Lee MN, Chan HK, Mohraz A (2011) Characteristics of Pickering emulsion gels formed by droplet bridging. Langmuir 28:3085–3091

    Article  Google Scholar 

  33. Binks B, Lumsdon S (1999) Stability of oil-in-water emulsions stabilised by silica particles. Phys Chem Chem Phys 1:3007–3016

    Article  CAS  Google Scholar 

  34. Genovese DB (2012) Shear rheology of hard-sphere, dispersed, and aggregated suspensions, and filler-matrix composites. Adv Colloid Interf 171:1–16

    Article  Google Scholar 

  35. Qin KD, Zaman AA (2003) Viscosity of concentrated colloidal suspensions: comparison of bidisperse models. J Colloid Interf Sci 266:461–467

    Article  CAS  Google Scholar 

  36. Gess JM, Rende DS (2005) Alkenyl succinic anhydride (ASA). TAPPI J 4:25–30

    CAS  Google Scholar 

Download references

Acknowledgments

We are grateful for the financial support of the National Natural Science Foundation of China (20776055).

Author information

Authors and Affiliations

  1. State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Wushan Road, Guangzhou, Guangdong, 510640, People’s Republic of China

    Zhaoyun Lin & Youming Li

  2. Shandong Provincial Key Laboratory of Fine Chemicals, Qilu University of Technology, Daxue Road, Western University Science Park, Jinan, Shandong, 250353, People’s Republic of China

    Dehai Yu

Authors
  1. Zhaoyun Lin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Dehai Yu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Youming Li
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Youming Li.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Lin, Z., Yu, D. & Li, Y. Study on the magnetic ODSA-in-water Pickering emulsion stabilized by Fe3O4 nanoparticle. Colloid Polym Sci 293, 125–134 (2015). https://doi.org/10.1007/s00396-014-3371-0

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00396-014-3371-0

Keywords

Search

Navigation