Skip to main content
Log in

Membrane transfer in electrochemical utilization of lithium chloride

  • Chemistry and Technology of Chemical Fibres
  • Published:
Fibre Chemistry Aims and scope

Abstract

Analytical expressions for calculating the transport nunber through a membrane were obtained. It was found that the transport numbers in a cation-exchange membrane should be divided into cationic and electrical. The transport number for lithium ions and the electric number for transport of ions through a Nafion membrane vary from 0.95–1.0 to 0.91–0.95 and from 0.46 to 0.40–0.44, respectively, when the current density increases from 0.5 to 2.0 kA/m2. The coincidence or closeness of the values of the transport numbers with the doubled equations indicates the adequacy of real membrane mass transfer described by the equations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A. V. Skolunov and A. T. Serkov,Khim. Volokna, No. 4, 16 (1995).

    Google Scholar 

  2. A. V. Skolunov,Zh. Prikl. Khim.,68, No. 12, 1984 (1995).

    CAS  Google Scholar 

  3. A. F. Mazanko, G. M. Kamar'yan, and O. P. Romashin,Industrial Membrane Electrolysis [in Russian], Khimiya, Moscow (1989).

    Google Scholar 

  4. A. Lindheimer and C. Gavach,J. Membrane Sci.,46, 125 (1989).

    Article  CAS  Google Scholar 

  5. A. V. Skolunov,Elektrokhimiya,27, No. 8, 969 (1991).

    CAS  Google Scholar 

  6. I. D. Zaitsev and G. G. Aseev,Handbook of Physicochemical Properties of Binary and Multicomponent Solutions of Inorganic Compounds [in Russian], Khimiya, Moscow (1988).

    Google Scholar 

  7. V. I. Perel'man,Short Chemist's Handbook [in Russian], Goskhimizdat, Moscow (1963).

    Google Scholar 

  8. D. Dobosh,Electrochemical Constants [Russian translation], Mir, Moscow (1980).

    Google Scholar 

Download references

Authors

Additional information

UVIKOM, Mytishchi. Translated fromKhimicheskie Volokna, No. 1, pp. 21–24, January–February, 1999.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Skolunov, A.V. Membrane transfer in electrochemical utilization of lithium chloride. Fibre Chem 31, 26–31 (1999). https://doi.org/10.1007/BF02358697

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02358697

Keywords

Navigation