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Eprspectra of free radicals generated by electrochemical reduction of 3-nitrohexahydroquinol-5-ones and 4-nitrohexahydroisoquinol-8-ones

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The polarographic characteristics (potentials, number of electrons, reversibility) of the electrochemical reducation of 7,7-dimethyl-3-nitro-1,4,5,6,7,8-hexahydroquinol-5-ones and 1,6,6-trimethyl-4-nitro-2,4a,5,6,7,8-hexahydroisoquinol-8-ones in DMF are determined. Secondary anion-radicals have been proved to arise during the electrochemical reduation and the hyperfine structure and coupling constants of their EPR spectra are established.

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Authors
  1. R. Gavars
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  2. L. Baumane
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  3. J. Stradins
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  4. B. Vigante
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  5. J. Ozols
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  6. G. Duburs
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Additional information

Dedicated to Professor Henk van der Plas on his 70th birthday.

Latvian Institute of Organic Synthesis, Riga LV-1006

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 510–515, April, 1999.

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Gavars, R., Baumane, L., Stradins, J. et al. Eprspectra of free radicals generated by electrochemical reduction of 3-nitrohexahydroquinol-5-ones and 4-nitrohexahydroisoquinol-8-ones. Chem Heterocycl Compd 35, 450–454 (1999). https://doi.org/10.1007/BF02319333

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  • DOI: https://doi.org/10.1007/BF02319333

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