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Electrical impedance of ethylene-carbon monoxide/propylene-carbon monoxide (EPEC-69) thermoplastic polyketone

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Abstract

Electrical impedance technique was employed to investigate the electrical properties of ethylene-carbon monoxide/propylene-carbon monoxide terpolymer (EPEC-69). The measurements were performed in the frequency range 0.1–105 Hz and in the temperature range 30–110 °C. The results reveal that the dielectric constant, loss factor, modulus, and ac conductivity are dependent of frequency and temperature. A Debye relaxation peak was detected in the plot of Z″ versus frequency where the activation energy was determined and found to be 1.26 eV. When the surface phenomenon effects were separated using the imaginary part of the complex admittance a second dielectric dispersion was observed in the low frequency region. Two models were proposed from the impedance measurements depending on temperature range.

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Acknowledgement

Financial support by the Hashemite University is gratefully acknowledged. The authors would like to thank Mr. Abedal-Monim M. Said for carrying out the DSC measurements.

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Authors and Affiliations

  1. Department of Physics, Hashemite University, PO Box 150459, Zarqa, 13115, Jordan

    Saadi Abdul Jawad, Mufeed Maghrabi, Ziad Khattari & Manar Al-Obeid

  2. Department of Chemistry, Hashemite University, P.O. Box 150459, Zarqa, 13115, Jordan

    Adnan S. Abu-Surrah

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  1. Saadi Abdul Jawad
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  2. Adnan S. Abu-Surrah
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  3. Mufeed Maghrabi
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  4. Ziad Khattari
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Correspondence to Saadi Abdul Jawad.

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Jawad, S.A., Abu-Surrah, A.S., Maghrabi, M. et al. Electrical impedance of ethylene-carbon monoxide/propylene-carbon monoxide (EPEC-69) thermoplastic polyketone. J Mater Sci 46, 2748–2754 (2011). https://doi.org/10.1007/s10853-010-5148-2

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