Abstract
CuO supported on ceria and alumina is prepared by incipient wetness impregnation and its redox behavior is investigated by means of XRD, XPS and TPO experiments. CuO on ZrO2 and on ceria–zirconia are also synthesized for comparison. The support plays a major role on the dynamics of CuO–Cu2O transformation. On Al2O3 the formation of CuAl2O4 inhibits any oxygen exchange during TPO experiments, while on ceria, zirconia and ceria–zirconia supported catalysts CuO decomposition and re-oxidation take place with a hysteresis similar to that observed for Pd–PdO transformation. On CeO2 the hysteresis is significantly reduced, indicating a strong effect of ceria on CuO–Cu2O redox cycle.
Graphical Abstract
Similar content being viewed by others
References
Bartholomew CH, Farrauto RJ (2006) Fundamentals of industrial catalytic processes. Wiley, Hoboken
Skarman B, Nakayama T, Grandjean D, Benfield RE, Olsson E, Niihara K, Wallenberg LR (2002) Chem Mater 14:3686
Hu CQ, Zhu QS, Jiang Z, Chen L, Wu RF (2009) Chem Eng J 152:583
Cao HY, Li XS, Chen YQ, Gong MC, Wang JL (2012) J Rare Earths 30:871
Iamarino M, Chirone R, Lisi L, Pirone R, Salatino P, Russo G (2002) Catal Today 75:317
Kaddouri A, Dupont N, Gelin P, Delichere P (2011) Catal Lett 141:1581
Adanez J, de Diego LF, Garcia-Labiano F, Gayan P, Abad A, Palacios JM (2004) Energy Fuels 18:371
Arjmand M, Azad AM, Leion H, Mattisson T, Lyngfelt A (2012) Ind Eng Chem Res 51:13924
Zhao HY, Cao Y, Kang ZZ, Wang YB, Pan WP (2012) J Therm Anal Calorim 109:1105
Shah K, Moghtaderi B, Wall T (2012) Energy Fuels 26:2038
Shah K, Moghtaderi B, Zanganeh J, Wall T (2013) Fuel 107:356
Chen ZF, Meyer TJ (2013) Angew Chem-Int Ed 52:700
Chen ZF, Kang P, Zhang MT, Stoner BR, Meyer TJ (2013) Energy Environ Sci 6:813
Caputo T, Pirone R, Russo G (2006) Kinet Catal 47:756
Gamarra D, Camara AL, Monte M, Rasmussen SB, Chinchilla LE, Hungria AB, Munuera G, Gyorffy N, Schay Z, Corberan VC, Conesa JC, Martinez-Arias A (2013) Appl Catal B Environ 130:224
Di Benedetto A, Landi G, Lisi L, Russo G (2013) Appl Catal B Environ 142:169
Zhang L, Pan LW, Ni CJ, Sun TJ, Zhao SS, Wang SD, Wang AJ, Hu YK (2013) Int J Hydrogen Energy 38:4397
Tong WY, West A, Cheung K, Yu KM, Tsang SCE (2013) ACS Catal 3:1231
Nagai Y, Dohmae K, Nishimura YF, Kato H, Hirata H, Takahashi N (2013) Phys Chem Chem Phys 15:8461
Radlik M, Adamowska M, Laamacz A, Krzton A, Da Costa P, Turek W (2013) React Kinet Mech Catal 109:43
Kundakovic L, Flytzani-Stephanopoulos M (1998) J Catal 179:203
Artizzu P, Garbowski E, Primet M, Brulle Y, Saint-Just J (1999) Catal Today 47:83
Qu FF, Chu W, Shi LM, Chen MH, Hu JY (2007) Chin Chem Lett 18:993
Aguila G, Gracia F, Cortes J, Araya P (2008) Appl Catal B Environ 77:325
Luo JJ, Xu HY, Liu YF, Chu W, Jiang CF, Zhao XS (2012) Appl Catal A Gen 423:121
Trovarelli A (2002) Catalysis by ceria and related materials. Imperial College Press, London
Fornasiero P, Balducci G, DiMonte R, Kaspar J, Sergo V, Gubitosa G, Ferrero A, Graziani M (1996) J Catal 164:173
Si R, Zhang YW, Wang LM, Li SJ, Lin BX, Chu WS, Wu ZY, Yan CH (2007) J Phys Chem C 111:787
Wang QY, Zhao B, Li GF, Zhou RX (2010) Environ Sci Technol 44:3870
Ran R, Weng D, Wu XD, Fan J, Wang L (2011) J Rare Earths 29:1053
Wang JQ, Shen MQ, Wang J, Gao JD, Ma J, Liu SX (2012) J Rare Earths 30:878
Li GF, Wang QY, Zhao B, Zhou RX (2010) J Mol Catal A Chem 326:69
Jia LW, Shen MQ, Wang J, Chu X, Wang JM, Hu ZC (2008) J Rare Earths 26:523
Kim DK, Stowe K, Muller F, Maier WF (2007) J Catal 247:101
Liu W, Flytzani-Stephanopoulos M (1996) Chem Eng J 64:283
Wang XQ, Rodriguez JA, Hanson JC, Gamarra D, Martinez-Arias A, Fernandez-Garcia M (2006) J Phys Chem B 110:428
Martinez-Arias A, Fernandez-Garcia M, Soria J, Conesa JC (1999) J Catal 182:367
Martinez-Arias A, Hungria AB, Fernandez-Garcia M, Conesa JC, Munuera G (2004) J Phys Chem B 108:17983
Caputo T, Lisi L, Pirone R, Russo G (2008) Appl Catal A Gen 348:42
Liu LJ, Yao ZJ, Liu B, Dong L (2010) J Catal 275:45
Chen JF, Zhan YY, Zhu JJ, Chen CQ, Lin XY, Zheng Q (2010) Appl Catal A Gen 377:121
Colussi S, Trovarelli A, Vesselli E, Baraldi A, Comelli G, Groppi G, Llorca J (2010) Appl Catal A Gen 390:1
Colussi S, Trovarelli A, Groppi G, Llorca J (2007) Catal Commun 8:1263
Farrauto RJ, Hobson MC, Kennelly T, Waterman EM (1992) Appl Catal A Gen 81:227
Vicario M, Llorca J, Boaro M, de Leitenburg C, Trovarelli A (2009) J Rare Earths 27:196
Pappacena A, Porreca P, Boaro M, de Leitenburg C, Trovarelli A (2012) Int J Hydrogen Energy 37:1698
Cao Y, Casenas B, Pan WP (2006) Energy Fuels 20:1845
Rodriguez NM, Oh SG, DallaBetta RA, Baker RTK (1995) J Catal 157:676
Lyubovsky M, Pfefferle L, Datye A, Bravo J, Nelson T (1999) J Catal 187:275
Wolf MM, Zhu HY, Green WH, Jackson GS (2003) Appl Catal A Gen 244:323
Hanchen M, Stiel A, Jovanovic ZR, Steinfeld A (2012) Ind Eng Chem Res 51:7013
Salomonsson P, Johansson S, Kasemo B (1995) Catal Lett 33:1
Farrauto RJ, Lampert JK, Hobson MC, Waterman EM (1995) Appl Catal B Environ 6:263
Thevenin PO, Alcalde A, Pettersson LJ, Jaras SG, Fierro JLG (2003) J Catal 215:78
Colussi S, Trovarelli A, Cristiani C, Lietti L, Groppi G (2012) Catal Today 180:124
Voogt EH, Mens AJM, Gijzeman OLJ, Geus JW (1996) Surf Sci 350:21
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Colussi, S., Amoroso, F., Katta, L. et al. The Effect of Ceria on the Dynamics of CuO–Cu2O Redox Transformation: CuO–Cu2O Hysteresis on Ceria. Catal Lett 144, 1023–1030 (2014). https://doi.org/10.1007/s10562-014-1237-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10562-014-1237-1