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Oxidative Dehydrogenation of Ethane to Ethylene with Carbon dioxide over Cr–Ce/SBA-15 Catalysts

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Abstract

Chromium oxide supported on SBA-15 was modified with Ce species by an incipient method. The effect of Ce on the activity of Cr/SBA-15 catalyst in the dehydrogenation of ethane with CO2 was investigated. The activity is enhanced for Ce modified Cr/SBA-15 catalyst for the dehydrogenation of ethane with CO2. The cycle between Cr6+ and Cr3+ species can be carried out viaing the dehydrogenation of ethane and oxidation of CO2 processes.

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Acknowledgements

Financial funds from the National Natural Science Foundation of China (Project Nos. 20473009) and the National Basic Research Program of China (Project No. 2005CB221405) are gratefully acknowledged.

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Authors and Affiliations

  1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, 15 Beisanhuan Dong Road, P.O. Box 35, Beijing, 100029, China

    Xuejun Shi, Shengfu Ji & Kai Wang

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  1. Xuejun Shi
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  2. Shengfu Ji
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  3. Kai Wang
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Correspondence to Shengfu Ji.

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Shi, X., Ji, S. & Wang, K. Oxidative Dehydrogenation of Ethane to Ethylene with Carbon dioxide over Cr–Ce/SBA-15 Catalysts. Catal Lett 125, 331–339 (2008). https://doi.org/10.1007/s10562-008-9569-3

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  • DOI: https://doi.org/10.1007/s10562-008-9569-3

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